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Highlights • Crystallization of magnetic particles from Na 2 O-SrO-Fe 2 O 3 -B 2 O 3 glasses is studied. • Increase of sodium oxide content leads to decrease of crystallization temperatures. • Crystallization of 4 nm maghemite nanoparticles is observed at low temperatures. • Hexaferrite morphology and properties are determined by annealing temperatures. Abstract Magnetic glass-ceramics with composition n Na 2 O-9SrO-6Fe 2 O 3 -8B 2 O 3 (n = 1 and 4) were prepared by fast quenching of the molten oxide mixtures and subsequent thermal treatment of the obtained glasses at 450–950 °C. The samples were investigated by differential thermal analysis, x-ray powder diffraction, electron microscopy, and SQIUD magnetometry. Increasing of the sodium oxide content leads to a significant decrease of the glass transition, devitrification, and melting temperatures. Just above the glass transition temperature (525 °C for n = 1 and 430 °C for n = 4) superparamagnetic γ-Fe 2 O 3 nanoparticles precipitate, which, at elevating annealing temperature, are substituted by thin hexaferrite nanoplatelets with coercivities of 2000–4000 Oe; the annealing at higher temperatures results in crystallization of the submicron hexaferrite particles with a coercivity of up to 6000 Oe. Thus the glass-ceramics are highly applicable sources of non-sintered nanoparticles with various morphologies and magnetic properties. [ABSTRACT FROM AUTHOR]