1. Gallium Plasmonic Nanoantennas Unveiling Multiple Kinetics of Hydrogen Sensing, Storage, and Spillover
- Author
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Maria Losurdo, Maria M. Giangregorio, Alexandra Suvorova, Sergey Rubanov, Yael Gutiérrez, April S. Brown, Fernando Moreno, and Universidad de Cantabria
- Subjects
Materials science ,Hydrogen ,chemistry.chemical_element ,Nanoparticle ,Gallium ,02 engineering and technology ,010402 general chemistry ,7. Clean energy ,01 natural sciences ,Hydrogen storage ,Adsorption ,Metal hydrides ,General Materials Science ,Photocatalysis ,Plasmon ,business.industry ,Mechanical Engineering ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,chemistry ,Mechanics of Materials ,Plasmonics ,Optoelectronics ,Oxygen reverse spillover ,Hydrogen spillover ,0210 nano-technology ,business ,Optical hydrogen sensing ,Localized surface plasmon - Abstract
Hydrogen is the key element to accomplish a carbon-free based economy. Here, the first evidence of plasmonic gallium (Ga) nanoantennas is provided as nanoreactors supported on sapphire (α-Al2O3) acting as direct plasmon-enhanced photocatalyst for hydrogen sensing, storage, and spillover. The role of plasmon-catalyzed electron transfer between hydrogen and plasmonic Ga nanoparticle in the activation of those processes is highlighted, as opposed to conventional refractive index-change-based sensing. This study reveals that, while temperature selectively operates those various processes, longitudinal (LO-LSPR) and transverse (TO-LSPR) localized surface plasmon resonances of supported Ga nanoparticles open selectivity of localized reaction pathways at specific sites corresponding to the electromagnetic hot-spots. Specifically, the TO-LSPR couples light into the surface dissociative adsorption of hydrogen and formation of hydrides, whereas the LO-LSPR activates heterogeneous reactions at the interface with the support, that is, hydrogen spillover into α-Al2O3 and reverse-oxygen spillover from α-Al2O3. This Ga-based plasmon-catalytic platform expands the application of supported plasmon-catalysis to hydrogen technologies, including reversible fast hydrogen sensing in a timescale of a few seconds with a limit of detection as low as 5 ppm and in a broad temperature range from room-temperature up to 600 °C while remaining stable and reusable over an extended period of time. The authors thank all of the students and colleagues in their groups who were actively involved with nanoparticles research. M.L., Y.G., and F.M. have received funding from the European Union's Horizon 2020 Research and Innovation Program under Grant Agreement No. 899598—PHEMTRONICS. F.M. acknowledges MINECO (Spanish Ministry of Economy and Competitiveness, project PGC2018-096649-B-100).
- Published
- 2021