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Start Over Author "Guerra, Antonio C.O." Topic nucleophilic reactions -- research
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1. Rearrangement, nucleophilic substitution, and halogen switch reactions of alkyl halides over NaY zeolite: formation of the bicyclobutonium cation inside the zeolite cavity

Author

Franco, Marcelo, Rosenbach, Nilton, Jr., Ferreira, Glaucio B., Guerra, Antonio C.O., Kover, W. Bruce, Turci, Cassia C., and Mota, Claudio J.A.

Subjects
Zeolites -- Research, Zeolites -- Chemical properties, Nucleophilic reactions -- Research, Halides -- Research, Halides -- Chemical properties, Chemistry
Abstract

The rearrangement and nucleophilic substitution of cyclo-propylcarbinyl and cyclobutyl halides over NaY zeolite has succeeded in the formation of [C.sub.4][H.sub.7.sup.} cations as discrete intermediates inside the zeolite cavity. The results have shown that zeolites have acted as solid solvents, thus permitting ionization and solvation of ionic species.

Published
2008

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