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Composite materials based on reduced graphene oxide decorated with cuprous telluride nanoparticles (Cu 2 Te NPs@rGO) were fabricated using a facilitated two-step method. A back-contact layer was formed using a spin-coating method for cadmium telluride (CdTe) solar cells. This research is aimed to improve the photovoltaic performance of a device containing Cu 2 Te NPs@rGO/Au back contacts. Cu 2 Te NPs, as the active copper diffusion source, dope and passivate the interfaces and grain boundaries of CdTe to form the p+-layer, which can reduce the recombination centers and back-contact barrier height. Simultaneously, the reduced graphene oxide (rGO), as a buffer and carrier transport layer, prevents excessive copper diffusion during the annealing process and improves the hole collection capacity. The p-type layer formed by the rGO contact with the Au film enhances hole transport and facilitates a low-resistance contact formation, forming a quasi-ohmic contact, and increases the open-circuit voltage and short-circuit current density. Cu 2 Te NPs@rGO/Au back contacts significantly improved the photovoltaic performance (E ff : 16.5%, V oc : 830 mV, J sc : 27.13 mA/cm2, fill factor: 73.3%, area: 0.24 cm2). The composites retain properties of Cu 2 Te NPs and rGO. Their multifunctional properties reveal the potential of Cu 2 Te NPs@rGO as the back contact and broaden the application of graphene-based composites in photovoltaic devices. Additionaly, the preparation of graphene-based composites and their application as back contact is simple and convenient. • The Cu 2 Te NPs@rGO composites is synthesized by a facilitated two-step method. • The Cu 2 Te NPs@rGO composites is firstly used as the back contact for CdTe solar cells. • Cu 2 Te NPs can effectively dope the CdTe layer, and rGO/Au can reduce the barrier height. • A quasi-ohmic contact is formed by the Cu 2 Te NPs@rGO composites. • A significant enhanced performance (e.g., Eff: 16.5%, V oc : 830 mV, J sc : 27.13 mA/cm2, FF: 73.3%, area: 0.24 cm2) is achieved for CdTe solar cells. [ABSTRACT FROM AUTHOR]

Ohmic back contact is one of the keys to fabricate high efficient CdTe solar cells, as it can improve fill factor FF and open-circuit voltage V oc. In this work, antimony-containing reduced graphene oxide (RGO) was prepared and used as a back contact for CdTe thin film solar cells, in which antimony is an effective dopant for CdTe and RGO acts as a hole transport layer and diffusion barrier of antimony in the solar cells. Post deposition annealing was performed to activate the back contact layer and passivate the interface defect states. Electrical performance and apparent quantum efficiency characterization were performed to investigate device performance of CdTe solar cells with antimony-containing RGO back contacts. The results indicate that, the introduction of extrinsic doping near the CdTe back surface serves to reduce the back contact depletion width and enhance the built-in potential to enable the tunnelling of majority carrier holes through the barrier, and the RGO is beneficial for the formation of Ohmic back contact on CdTe. [ABSTRACT FROM AUTHOR]