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1. Copper-catalyzed allylation of α,α-difluoro-substituted organozinc reagents.

Author

Zemtsov AA, Kondratyev NS, Levin VV, Struchkova MI, and Dilman AD

Subjects
Catalysis, Hydrocarbons, Fluorinated chemistry, Molecular Structure, Allyl Compounds chemistry, Copper chemistry, Hydrocarbons, Fluorinated chemical synthesis, Organometallic Compounds chemistry, Zinc chemistry
Abstract

A method for the coupling of organozinc reagents, difluorocarbene, and allylic electrophiles is described. The reaction involves insertion of difluorocarbene into the carbon-zinc bond followed by copper-catalyzed allylic substitution.

Published
2014
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