1. Alkynylation of C.
- Author
-
Mukherjee, Satobhisha, Garza‐Sanchez, R. Aleyda, Tlahuext‐Aca, Adrian, and Glorius, Frank
- Subjects
- *
CARBONYL compounds , *ALKYLATION , *PHOTOCATALYSIS , *OXIDATION-reduction reaction , *CARBON-hydrogen bonds , *YNAMIDES - Abstract
The development of new hydrogen-atom transfer (HAT) strategies within the framework of photoredox catalysis is highly appealing for its power to activate a desired C−H bond in the substrate leading to its selective functionalization. Reported here is the first photoredox-mediated hydrogen-atom transfer method for the efficient synthesis of ynones, ynamides, and ynoates with high regio- and chemoselectivity by direct functionalization of C [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF