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The EU Regulation No 517/2014 is going to phase-out most of the refrigerants commonly used in refrigeration and air conditioning systems (R134a, R404A and R410A) because of their extended use and their high GWP values. There are very different options to replace them; however, no refrigerant has yet imposed. In this paper we review and analyze the different mixtures proposed by the AHRI as alternative refrigerants to those employed currently. These mixtures are composed by HFC refrigerants: R32, R125, R152a and R134a; and HFO refrigerants: R1234yf and R1234ze(E). It is concluded, from the theoretical analysis, that most of the new HFO/HFC mixtures perform under the HFC analyzed (although some experimental studies show the contrary) and, in most cases, do not meet the GWP restrictions approved by the European normative. Furthermore, some of the mixtures proposed would have problems due to their flammability. [ABSTRACT FROM AUTHOR]

• Existing regulations do not limit GWP of refrigerants used for ULT applications. • Very low operating temperatures limit the possible low GWP candidates. • Cascade and auto-cascade refrigeration systems seem promising with ejector. • Compared to other hydrocarbons, flammability of R170 and R1150 is not widely studied. • R1132a is a promising candidate but requires further study. Several environmental protection policies have been enforced restricting working fluids with high global warming potential (GWP) values used in many types of refrigeration and heat pump systems. However, ultralow-temperature (ULT) refrigeration has not been included, which commonly uses refrigerants with very high GWP values (such as R23 and R508B). Therefore, publicly available research programs seeking low GWP alternative refrigerants do not cover this application and the transition to more environmentally friendly fluids is slowed down. This work presents a comprehensive review that summarizes and discusses the available studies about ULT refrigeration systems. The current status of the technology, system architectures and refrigerants are analyzed. Moreover, the transition towards low GWP refrigerants is proposed, presenting the most promising low GWP alternatives. The most commonly used architectures for ULT refrigeration are the two-stage cascade and auto-cascade, in which the use of ejector has recently been considered in research papers. R170 and R1150 are the available natural refrigerants suitable for ULT, but they have not yet been included in many flammability and risk assessment studies. The A2 hydrofluoroolefin R1132a has been recently proposed as a blend component to avoid problems of stability. However, more information is still necessary to start with simulation and experimental studies. R41 could be an alternative due to its low GWP and suitable normal boiling point, but it has not been thoroughly investigated yet. Overall, there is a gap in the literature in terms of developing alternative refrigerants for ULT refrigeration. This study aims at shedding light on this gap to direct future research in this field towards reliable, environmentally friendly and marketable alternative refrigerants. [ABSTRACT FROM AUTHOR]

Abstract High-temperature heat pumps (HTHPs) based on vapour compression can be used for industrial low-grade waste heat valorisation, which can aid in mitigating climate change. Currently, the performance of HTHPs operating at high-temperatures lifts is limited; therefore, advanced configurations become an opportunity for their utilisation. This paper presents an HTHP cascade with configurations of internal heat exchangers (IHXs) that uses low GWP refrigerants in both high-stage (HS) (HCFO-1233zd(E), HFO-1336mzz(Z), HCFO-1224yd(Z), and pentane) and low-stage (LS) (HFO-1234yf, HFO-1234ze(E), butane, isobutane, and propane) cycles. Prior to the analysis and presentation of results, an optimisation of the operating conditions is performed based on intermediate temperature and IHX effectiveness in both stage cycles. Results indicate that butane and isobutane appear to be the most convenient working LS fluids from the point of view of coefficient of performance (COP). The highest system performance is obtained using pentane and HFO-1336mzz(Z) in the HS cycle. Compared to third-generation refrigerants (HFC-245fa/HFC-134a), a slight COP improvement is obtained using HCFO-1233zd(E), and HCFO-1224yd(Z). A comparable or even lower volumetric flow rate at the HS compression suction is also observed. The use of pentane/butane achieved maximum COP (3.15), which is a 13% improvement compared to COP obtained when HFC-245fa/HFC-134a is employed. Highlights • A high-temperature heat pump cascade with the IHXs is proposed and optimised. • Synthetic and natural refrigerants with low GWPs are proposed for both stages. • The higher effectiveness of both IHXs in similar proportions increases total COP. • Pentane/butane presents maximum COP and minimum HCFO-1224yd(Z)/HFO-1234yf. • A few refrigerant pairs are comparable with HFC-245fa/HFC-134a in the stages of V ˙ s u c . [ABSTRACT FROM AUTHOR]