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International audience; The classical Kuiper Belt Object (KBO) Arrokoth was surveyed by the New Horizons spacecraft on 1st January 2019, revealing a small bilobed object with a red surface, whose spectral slope lies in the average of the whole KBOs population. This red color has been assigned to reddish organic materials, either inherited from the protosolar disk during accretion, or formed through radiolytic processes in the surface due to exposure to solar or interstellar photons, Solar Wind, Solar Energetic Particles or Galactic Cosmic Rays. We report here a study investigating the radiolytic scenario, based on numerical calculations and experimental simulations run with swift heavy ions (74.8 MeV136Xe19+ and 33.06 MeV58Ni9+), and low-energy 105 keV18O6+ions on CH3OH ice, the only molecule identified at Arrokoth’s surface.

Neptune's moon Triton shares many similarities with Pluto, including volatile cycles of N2, CH4 and CO, and represents a benchmark case for the study of surface-atmosphere interactions on volatile-rich KBOs. Within the context of New Horizons observations of Pluto as well as recent Earth-based observations of Triton, we adapt a Plutonian VTM to Triton, and test its ability to simulate its volatile cycles, thereby aiding our understanding of its climate. We present VTM simulations exploring the volatile cycles on Triton over long-term and seasonal timescales for varying model parameters. We explore what scenarios and model parameters allow for a best match of the available observations. In particular, our set of observational constraints include Voyager 2 observations, ground-based NIR (0.8 to 2.4 ��m) disk-integrated spectra and the evolution of surface pressure as retrieved from stellar occultations. Our results show that Triton's poles act as cold traps for volatile ices and favor the formation of polar caps extending to lower latitudes through glacial flow. As previously evidenced by other VTMs, North-South asymmetries in surface properties can favor the development of one cap over the other. Our best-case simulations are obtained for a global reservoir of N2 ice thicker than 200 m and a bedrock thermal inertia larger than 500 SI. The large N2 ice reservoir implies a permanent N2 southern cap extending to the equator. Our results also suggest that a small permanent polar cap exists in the northern (currently winter) hemisphere if the internal heat flux remains radiogenic (< 3 mW m-2). Finally, we provide predictions for the evolution of ice distribution, surface pressure, CO and CH4 atmospheric mixing ratios in the next decades. We also model the thermal lightcurves of Triton in 2022, which serve as predictions for future JWST observations., 69 pages, 29 figures, 3 tables. Accepted for publication in Icarus

Isotopic ratios have long been used to learn about physical processes acting over a wide range of geological environments, and in constraining the origin and/or evolution of planetary bodies. We report the spectroscopic detection of deuterium in Saturn's rings and satellites, and use these measurements to determine the (D/H) ratios in their near-surface regions. Saturn's moons, Phoebe and Iapetus, show a strong signature of CO2 and the 13C component of this molecule is detected and quantified. Large averages of spectra obtained by the Cassini Visual and Infrared Mapping Spectrometer, VIMS, were computed for the rings and icy satellites. The observed intensities of the infrared absorptions in H2O and CO2 and their isotopes were calibrated using laboratory data and radiative transfer models to derive the D/H and 13C/12C ratios. We find that the D/H in Saturn's rings and satellites is close to the Vienna Standard Mean Ocean Water (VSMOW) and bulk Earth (4% lower than VSMOW) value except for Phoebe, which is 8.3 times the VSMOW value. This is the highest value for any Solar-System surface yet measured, and suggests that Phoebe formed from material with a different D/H ratio than the other satellites in the Saturn system. Phoebe's 13C/12C ratio is also unusual: 4.7 times greater than terrestrial, and greater than values measured for the interstellar medium and the galactic center. The high 13C abundance in the CO2 suggests that Phoebe was never warm enough for the large D/H ratio in its surface to have originated by evaporative fractionation of its water ice (e.g., from heating in the inner Solar System before its eventual capture by Saturn). We also report the detection of a probable O-D stretch absorption due to OD in minerals on Phoebe at 3.62 μm. This absorption is not detected on other Saturnian satellites. Stronger signatures of bound water absorptions are found in the dark material of Iapetus and we report a new detection of bound water at 1.9 μm. The position of this absorption matches that seen in spectra of hydrated iron oxides but does not match absorptions seen in spectra of tholins. Despite the strong bound water signature in the Iapetus dark material, no 3.62 μm OD absorption is seen in the spectra, further indicating the high deuterium level on Phoebe is unusual. As such, it is likely that Phoebe originated in a colder part of the outer Solar System, relative to the prevailing temperatures at Saturn's distance from the Sun.

International audience; We have compared spectroscopic data of Sputnik Planitia on Pluto, as acquired by New Horizons’ Linear Etalon Imaging Spectral Array (LEISA) instrument, to the geomorphology as mapped by White et al. (2017) using visible and panchromatic imaging acquired by the LOng-Range Reconnaissance Imager (LORRI) and the Multi-spectral Visible Imaging Camera (MVIC). We have focused on 13 of the geologic units identified by White et al. (2017), which include the plains and mountain units contained within the Sputnik basin. We divided the map of Sputnik Planitia into 15 provinces, each containing one or more geologic units, and we use LEISA to calculate the average spectra of the units inside the 15 provinces. Hapke-based modeling was then applied to the average spectra of the units to infer their surface composition, and to determine if the composition resulting from the modeling of LEISA spectra reflects the geomorphologic analyses of LORRI data, and if areas classified as being the same geologically, but which are geographically separated, share a similar composition. We investigated the spatial distribution of the most abundant ices on Pluto’s surface - CH4, N2, CO, H2O, and a non-ice component presumed to be a macromolecular carbon-rich material, termed a tholin, that imparts a positive spectral slope in the visible spectral region and a negative spectral slope longward of ~1.1 μm. Because the exact nature of the non-ice component is still debated and because the negative spectral slope of the available tholins in the near infrared does not perfectly match the Pluto data, for spectral modeling purposes we reference it generically as the negative spectral slope endmember (NSS endmember). We created maps of variations in the integrated band depth (from LEISA data) and areal mass fraction (from the modeling) of the components. The analysis of correlations between the occurrences of the endmembers in the geologic units led to the observation of an anomalous suppression of the strong CH4 absorption bands in units with compositions that are dominated by H2O ice and the NSS endmember. Exploring the mutual variation of the CH4 and N2 integrated band depths with the abundance of crystalline H2O and NSS endmember revealed that the NSS endmember is primarily responsible for the suppression of CH4 absorptions in mountainous units located along the western edge of Sputnik Planitia. Our spectroscopic analyses have provided additional insight into the geological processes that have shaped Sputnik Planitia. A general increase in volatile abundance from the north to the south of Sputnik Planitia is observed. Such an increase first observed and interpreted by Protopapa et al., 2017 and later confirmed by climate modeling (Bertrand et al., 2018) is expressed geomorphologically in the form of preferential deposition of N2 ice in the upland and mountainous regions bordering the plains of southern Sputnik Planitia. Relatively high amounts of pure CH4 are seen at the southern Tenzing Montes, which are a natural site for CH4 deposition owing to their great elevation and the lower insolation they are presently receiving. The NSS endmember correlates the existence of tholins within certain units, mostly those coating the low-latitude mountain ranges that are co-latitudinal with the tholin-covered Cthulhu Macula. The spectral analysis has also revealed compositional differences between the handful of occurrences of northern non-cellular plains and the surrounding cellular plains, all of which are located within the portion of Sputnik Planitia that is presently experiencing net sublimation of volatiles, and which do not therefore exhibit a surface layer of bright, freshly-deposited N2 ice. The compositional differences between the cellular and non-cellular plains here hint at the effectiveness of convection in entraining and trapping tholins within the body of the cellular plains, while preventing the spread of such tholins to abutting non-cellular plains.

International audience; New Horizons' reectance spectra of the Cthulhu dark belt of Pluto were modelled with tholins. Reectance factors, phase function and optical constants of these tholins were numerically determined from tholins' reectance measurements. Tholins do not reproduce the featureless spectra of Cthulhu. These results could suggest that this region is covered with a highly porous layer of organic aerosolsPluto’s fly-by by the New Horizons spacecraft in July 2015 has revealed a dark reddish equatorial region, named Cthulhu, covered by a dark, non-icy material whose origin and composition have yet to be determined. It has been suggested that this material could form from the sedimentation of photochemical aerosols, originating from dissociation and ionisation processes in Pluto’s high atmosphere (similarly to aerosols forming Titan’s haze). This hypothesis is here further investigated by comparing New Horizons spectra collected both in the visible and the near-infrared to laboratory reflectance measurements of analogues of Pluto’s aerosols (Pluto tholins). These aerosols were synthesised in conditions mimicking Pluto’s atmosphere, and their optical and reflectance properties were determined, before being used in Hapke models. In particular, the single scattering albedo and phase function of Pluto tholins were retrieved through Hapke model inversion, performed from laboratory reflectance spectra collected under various geometries. From reconstructed reflectance spectra and direct comparison with New Horizons data, some of these tholins are shown to reproduce the photometric level (i.e. reflectance continuum) reasonably well in the near-infrared. Nevertheless, a misfit of the red visible slope still remains and tholins absorption bands present in the modelled spectra are absent in those collected by the New Horizons instruments. Several hypotheses are considered to explain the absence of these absorption features in LEISA data, namely high porosity effects or GCR irradiation. The formation of highly porous structures, which is currently our preferred scenario, could be promoted by either sublimation of ices initially mixed with the aerosols, or gentle deposition under Pluto’s weak gravity.

We discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt Object 2014 MU69 after its 4.6 Gyr residence in the EKB as a cold classical object. Considering the stability versus sublimation into vacuum for the suite of ices commonly found on comets, Centaurs, and KBOs at the average ~40K sunlit surface temperature of MU69 over Myr to Gyr, we find only 3 common ices that are truly refractory: HCN, CH3OH, and H2O (in order of increasing stability). NH3 and H2CO ices are marginally stable and may be removed by any positive temperature excursions in the EKB, as produced every 1e8 - 1e9 yrs by nearby supernovae and passing O/B stars. To date the NH team has reported the presence of abundant CH3OH and evidence for H2O on MU69s surface (Lisse et al. 2017, Grundy et al. 2020). NH3 has been searched for, but not found. We predict that future absorption feature detections will be due to an HCN or poly-H2CO based species. Consideration of the conditions present in the EKB region during the formation era of MU69 lead us to infer that it formed "in the dark", in an optically thick mid-plane, unable to see the nascent, variable, highly luminous Young Stellar Object-TTauri Sun, and that KBOs contain HCN and CH3OH ice phases in addition to the H2O ice phases found in their Short Period comet descendants. Finally, when we apply our ice thermal stability analysis to bodies/populations related to MU69, we find that methanol ice may be ubiquitous in the outer solar system; that if Pluto is not a fully differentiated body, then it must have gained its hypervolatile ices from proto-planetary disk sources in the first few Myr of the solar systems existence; and that hypervolatile rich, highly primordial comet C/2016 R2 was placed onto an Oort Cloud orbit on a similar timescale., Comment: 34 Pages, 5 Figures, 2 SOM Tables

We investigated whether ammonia-rich constituents are present on the surface of the Uranian moon Ariel by analyzing 32 near-infrared reflectance spectra collected over a wide range of sub-observer longitudes and latitudes. We measured the band areas and depths of a 2.2-{\micron} feature in these spectra, which has been attributed to ammonia-bearing species on other icy bodies. Ten spectra display prominent 2.2-{\micron} features with band areas and depths > 2{\sigma}. We determined the longitudinal distribution of the 2.2-{\micron} band, finding no statistically meaningful differences between Ariel's leading and trailing hemispheres, indicating that this band is distributed across Ariel's surface. We compared the band centers and shapes of the five Ariel spectra displaying the strongest 2.2-{\micron} bands to laboratory spectra of various ammonia-bearing and ammonium-bearing species, finding that the spectral signatures of the Ariel spectra are best matched by ammonia-hydrates and flash frozen ammonia-water solutions. Our analysis also revealed that four Ariel spectra display 2.24-{\micron} bands (> 2{\sigma} band areas and depths), with band centers and shapes that are best matched by ammonia ice. Because ammonia should be efficiently removed over short timescales by ultraviolet photons, cosmic rays, and charged particles trapped in Uranus' magnetosphere, the possible presence of this constituent supports geologic activity in the recent past, such as emplacement of ammonia-rich cryolavas and exposure of ammonia-rich deposits by tectonism, impact events, and mass wasting.

The close encounters of the Pluto–Charon system and the Kuiper Belt object Arrokoth (formerly 2014 MU69) by NASA’s New Horizons spacecraft in 2015 and 2019, respectively, have given new perspectives on the most distant planetary bodies yet explored. These bodies are key indicators of the composition, chemistry, and dynamics of the outer regions of the Solar System’s nascent environment. Pluto and Charon reveal characteristics of the largest Kuiper Belt objects formed in the dynamically evolving solar nebula inward of ~30 AU, while the much smaller Arrokoth is a largely undisturbed relic of accretion at ~45 AU. The surfaces of Pluto and Charon are covered with volatile and refractory ices and organic components, and have been shaped by geological activity. On Pluto, N2, CO and CH4 are exchanged between the atmosphere and surface as gaseous and condensed phases on diurnal, seasonal and longer timescales, while Charon’s surface is primarily inert H2O ice with an ammoniated component and a polar region colored with a macromolecular organic deposit. Arrokoth is revealed as a fused binary body in a relatively benign space environment where it originated and has remained for the age of the Solar System. Its surface is a mix of CH3OH ice, a red-orange pigment of presumed complex organic material, and possibly other undetected components.

International audience; A prominent fossa trough (Uncama Fossa) and adjacent 28-km diameter impact crater (Hardie) in Pluto’s Viking Terra, as seen in the high-resolution images from the New Horizons spacecraft, show morphological evidence of in-filling with a material of uniform texture and red-brown color. A linear fissure parallel to the trough may be the source of a fountaining event yielding a cryoclastic deposit having the same composition and color properties as is found in the trough and crater. Spectral maps of this region with the New Horizons LEISA instrument reveal the spectral signature of H2O ice in these structures and in distributed patches in the adjacent terrain in Viking Terra. A detailed statistical analysis of the spectral maps shows that the colored H2O ice filling material also carries the 2.2-μm signature of an ammoniated component that may be an ammonia hydrate (NH3⋅nH2O) or an ammoniated salt. This paper advances the view that the crater and fossa trough have been flooded by a cryolava debouched from Pluto’s interior along fault lines in the trough and in the floor of the impact crater. The now frozen cryolava consisted of liquid H2O infused with the red-brown pigment presumed to be a tholin, and one or more ammoniated compounds. Although the abundances of the pigment and ammoniated compounds entrained in, or possibly covering, the H2O ice are unknown, the strong spectral bands of the H2O ice are clearly visible. In consideration of the factors in Pluto’s space environment that are known to destroy ammonia and ammoniawater mixtures, the age of the exposure is of order

International audience; A multiwavelength regionally dependent photometric analysis of Pluto's anti-Charon-facing hemisphere using images collected by New Horizons' Multispectral Visible Imaging Camera (MVIC) reveals large variations in the absolute value and spectral slope of the single-scattering albedo. Four regions of interest are analyzed: the dark equatorial belt, Pluto's north pole, nitrogen-rich regions, and the mid-latitude terrains. Regions dominated by volatile ices such as Lowell Regio and Sputnik Planitia present single-scattering albedos of ~0.98 at 492 nm, almost neutral across MVIC's visible wavelength range (400–910 nm), indicating limited contributions from tholin materials. Pluto's dark equatorial regions, informally named Cthulhu and Krun Maculae, have single-scattering albedos of ~0.16 at 492 nm and are the reddest regions. Applying the Hapke radiative transfer model to combined MVIC and Linear Etalon Imaging Spectral Array (LEISA) spectra (400–2500 nm) of Cthulhu Macula and Lowell Regio successfully reproduces the spectral properties of these two regions of dramatically disparate coloration, composition, and morphology. Since this model uses only a single coloring agent, very similar to the Titan-like tholin of Khare et al., to account for all of Pluto's colors, this result supports the Grundy et al. conclusion that Pluto's coloration is the result of photochemical products mostly produced in the atmosphere. Although cosmic rays and extreme ultraviolet photons reach Pluto's surface where they can drive chemical processing, observations of diverse surface colors do not require different chemical products produced in different environments. We report a correction scaling factor in the LEISA radiometric calibration of 0.74 ± 0.05.

CO2 ice is present on the trailing hemisphere of Ariel but is mostly absent from its leading hemisphere. The leading/trailing hemispherical asymmetry in the distribution of CO2 ice is consistent with radiolytic production of CO2, formed by charged particle bombardment of H2O ice and carbonaceous material in Ariel’s regolith. This longitudinal distribution of CO2 on Ariel was previously characterized using 13 near-infrared reflectance spectra collected at “low” sub-observer latitudes between 30°S and 30°N. Here we investigated the distribution of CO2 ice on Ariel using 18 new spectra: 2 collected over low sub-observer latitudes, 5 collected at “mid” sub-observer latitudes (31°N–44°N), and 11 collected over “high” sub-observer latitudes (45°N–51°N). Analysis of these data indicates that CO2 ice is primarily concentrated on Ariel’s trailing hemisphere. However, CO2 ice band strengths are diminished in the spectra collected over mid and high sub-observer latitudes. This sub-observer latitudinal trend may result from radiolytic production of CO2 molecules at high latitudes and subsequent migration of this constituent to low-latitude cold traps. We detected a subtle feature near 2.13 μm in two spectra collected over high sub-observer latitudes, which might result from a “forbidden” transition mode of CO2 ice that is substantially stronger in well-mixed substrates composed of CO2 and H2O ice, consistent with regolith-mixed CO2 ice grains formed by radiolysis. Additionally, we detected a 2.35 μm feature in some low sub-observer latitude spectra, which might result from CO formed as part of a CO2 radiolytic production cycle.

Cometary bodies are acknowledged to contain some of the most pristine matter in the Solar System, including ices and minerals. Certain number of previously unidentified spectral emission features detected in comets can be explained as emission by hydrocarbon molecules enclosed in a Shpolskii matrix and forming frozen hydrocarbon particles. UV-induced photoluminescence spectra of several self-organized molecules exhibit emission lines coincident with unidentified cometary lines, and open the possibility of the presence of this complex organic as components of the pristine organic inventory of comets. Complex organic was detected also in three satellites of Saturn. We describe in this paper results of our investigation of complex organic of the small bodies and present new approaches and hypotheses.

Asteroid (16) Psyche is a unique, metal-rich object belonging to the “M” taxonomic class. It may be a remnant protoplanet that has been stripped of most silicates by a hit-and-run collision. Because Psyche offers insight into the planetary formation process, it is the target of NASA’s Psyche mission, set to launch in 2023. In order to constrain Psyche’s surface properties, we have carried out a mid-infrared (5–14 µm) spectroscopic study using data collected with the Spitzer Space Telescope’s Infrared Spectrograph. Our study includes two observations covering different rotational phases. Using thermophysical modeling, we find that Psyche’s surface is smooth and likely has a thermal inertia Γ = 5–25 J/m2/K/s1/2 and bolometric emissivity ϵ = 0.9, although a scenario with ϵ = 0.7 and thermal inertia up to 95 J/m2/K/s1/2 is possible if Psyche is somewhat larger than previously determined. The smooth surface is consistent with the presence of a metallic bedrock, which would be more ductile than silicate bedrock, and thus may not readily form boulders upon impact events. From comparisons with laboratory spectra of silicate and meteorite powders, Psyche’s 7–14 µm emissivity spectrum is consistent with the presence of fine-grained (

Bladed Terrain on Pluto consists of deposits of massive CH 4 , which are observed to occur within latitudes 30° of the equator and are found almost exclusively at the highest elevations (> 2 km above the mean radius). Our analysis indicates that these deposits of CH 4 preferentially precipitate at low latitudes where net annual solar energy input is lowest. CH 4 and N 2 will both precipitate at low elevations. However, since there is much more N 2 in the atmosphere than CH 4 , the N 2 ice will dominate at these low elevations. At high elevations the atmosphere is too warm for N 2 to precipitate so only CH 4 can do so. We conclude that following the time of massive CH 4 emplacement; there have been sufficient excursions in Pluto's climate to partially erode these deposits via sublimation into the blades we see today. Blades composed of massive CH 4 ice implies that the mechanical behavior of CH 4 can support at least several hundred meters of relief at Pluto surface conditions. Bladed Terrain deposits may be widespread in the low latitudes of the poorly seen sub-Charon hemisphere, based on spectral observations. If these locations are indeed Bladed Terrain deposits, they may mark heretofore unrecognized regions of high elevation.

Charon, the largest moon of Pluto, appeared as a fairly homogeneous, gray, icy world to New Horizons during closest approach on July 14th, 2015. Charon's sub-Pluto hemisphere was scanned by the Ralph/LEISA near-IR spectrograph providing an unprecedented opportunity to measure its surface composition. We apply a statistical clustering tool to identify spectrally distinct terrains and a radiative transfer approach to study the variations of the 2.0-µm H2O ice band. We map the distribution of the ices previously reported to be present on Charon's surface, namely H2O and the products of NH3 in H2O. We find that H2O ice is mostly in the crystalline phase, confirming previous studies. The regions with the darkest albedos show the strongest signature of amorphous-phase ice, although the crystalline component is still strong. The brighter albedo regions, often corresponding to crater ejecta blankets, are characterized by larger H2O grains, possibly an indication of a younger age. We observe two different behaviors for the two absorption bands representing NH3 in H2O. The 2.21-µm band tends to cluster more in the northern areas compared to the ∼2.01-µm band. Both bands are present in the brighter crater rays, but not all craters show both bands. The 2.21-µm band is also clearly present on the smaller moons Hydra and Nix. These results hint that different physical conditions may determine the appearance or absence of these two different forms of NH3 in H2O ice in the Pluto system. We also investigate the blue slope affecting the spectrum at wavelengths longer than ∼1.8 µm previously reported by several authors. We find that the slope is common among the objects in the Pluto system, Charon, the smaller moons Nix and Hydra, and the darkest terrains on Pluto. It also characterizes the analog ice tholin obtained from irradiation of Pluto-specific materials (a mixture of N2, CH4, and CO ices) in the laboratory. Our modeling results show that Pluto ice tholins are widespread almost uniformly on Charon suggesting a common distribution possibly part of the original reservoir of materials that made up Charon. This was irradiated over the years to yield the gray color characteristic of Charon today. On top of the ‘primordial’ Pluto ice tholin there is the redder component produced by irradiation of the CH4 provided by Pluto's atmospheric contribution as illustrated by Grundy et al. (2016a).

A near-IR absorption band at 2.2 μm linked to ammonia-containing ice has been detected on icy bodies throughout the solar system and appears in the extensive volume of data for Pluto and Charon returned by New Horizons. This band is an important clue for understanding the abundance of ammonia and ammoniated compounds on the surface of outer solar system bodies and requires new laboratory data for its full analysis. To satisfy this data need, the complex refractive index of amorphous ammonia ice was calculated from experimental infrared transmission spectra with ice deposition and measurements conducted at 40 K, a characteristic surface temperature for outer solar system bodies. The measured imaginary part of the complex refractive index and associated band strength calculations are generally larger than prior published values for amorphous ammonia ice at 30 K. The complex refractive index for amorphous ammonia at 40 K computed in the mid-infrared region (2.5–22.73 μm) will also be valuable for interpreting observations of both solar system and astrophysical sources anticipated with the Near InfraRed Spectrograph and Mid-Infrared Instrument on the James Webb Space Telescope.

New Horizon's accurate determination of the sizes and densities of Pluto and Charon now permit precise internal models of both bodies to be constructed. Assuming differentiated rock-ice structures, we find that Pluto is close to 2/3 solar-composition anhydrous rock by mass and Charon 3/5 solar-composition anhydrous rock by mass. Pluto and Charon are closer to each other in density than to other large (≳1000-km diameter) Kuiper belt bodies. Despite this, we show that neither the possible presence of an ocean under Pluto's water ice shell (and no ocean within Charon), nor enhanced porosity at depth in Charon's icy crust compared with that of Pluto, are sufficient to make Pluto and Charon's rock mass fractions match. All four small satellites (Styx, Nix, Kerberos, Hydra) appear much icier in comparison with either Pluto or Charon. In terms of a giant impact origin, both these inferences are most consistent with the relatively slow collision of partly differentiated precursor bodies (Canup, Astrophys. J. 141, 35, 2011). This is in turn consistent with dynamical conditions in the ancestral Kuiper belt, but implies that the impact precursors themselves accreted relatively late and slowly (to limit 26 Al and accretional heating). The iciness of the small satellites is not consistent with direct formation of the Pluto–Charon system from a streaming instability in the solar nebula followed by prompt collapse of gravitationally bound “pebble piles,” a proposed formation mechanism for Kuiper belt binaries (Nesvorný et al., Astron. J. 140, 785–793, 2010). Growth of Pluto-scale bodies by accretion of pebbles in the ancestral Kuiper belt is not ruled out, however, and may be needed to prevent the precursor bodies from fully differentiating, due to buried accretional heat, prior to the Charon-forming impact.

We investigate whether the surfaces of the classical moons of Uranus are compositionally stratified, with a thin veneer of mostly tiny H2O ice grains (, To be published in Icarus [2019, accepted]. 10 tables and 7 figures

International audience; On July 14, 2015, the New Horizons spacecraft made its closest approach to Pluto at about 12,000 km from its surface (Stern et al., 2015). Using the LEISA (Linear Etalon Imaging Spectral Array) near-IR imaging spectrometer we obtained two scans across the encounter hemisphere of Pluto at 6-7 km/pixel resolution. By correlating each spectrum with a crystalline H 2 O-ice model, we find several sites on Pluto's surface that exhibit the 1.5, 1.65 and 2.0 µm absorption bands characteristic of H 2 O-ice in the crystalline phase. These sites tend to be isolated and small (≲ 5000 km 2 per site). We note a distinct near-IR blue slope over the LEISA wavelength range and asymmetries in the shape of the 2.0 µm H 2 O-ice band in spectra with weak CH 4-ice bands and strong H 2 O-ice bands. These characteristics are indicative of fine-grain (grain diameters < wavelength or ∼ 1 µm) H 2 O-ice, like that seen in the spectra of Saturnian rings and satellites. However, the best-fit Hapke models require small mass fractions (≲10 −3) of fine-grained H 2 O-ice that we can exchange for other refractory materials in the models with little change in χ 2 , which may mean that the observed blue slope is possibly not due to a fine-grained material but an unidentified material with a similar spectral characteristic. We use these spectra to test for the presence of amorphous H 2 O-ice and estimate crystalline-to-amorphous H 2 O-ice fractions between 30 and 100%, depending on the location. We also see evidence for heavy hydrocarbons via strong absorption at λ > 2.3 µm. Such heavy hydrocarbons are much less volatile than N 2 , CH 4 , and CO at Pluto temperatures. We test for CH 3 OH, C 2 H 6 , C 2 H 4 , and C 3 H 8-ices because they have known optical constants and these ices are likely to arise from UV and energetic particle bombardment of the N 2 , CH 4 , CO-rich surface and atmosphere. Finally, we attempt to estimate the surface temperature using optical constants of pure CH 4 , and H 2 O-ice and best-fit Hapke models. Our standard model gives temperature estimates between 40 and 90 K, while our models including amorphous H 2 O-ice give lower temperature estimates between 30 and 65 K.

International audience; The Virgil Fossae region on Pluto exhibits three spatially coincident properties that are suggestive of recent cryovolcanic activity over an area approximately 300 by 200 km. Situated in the fossae troughs or channels and in the surrounding terrain are exposures of H2O ice in which there is entrained opaque red-colored matter of unknown composition. The H2O ice is also seen to carry spectral signatures at 1.65 and 2.2 μm of NH3 in some form, possibly as a hydrate, an ammoniated salt, or some other compound. Model calculations of NH3 destruction in H2O ice by galactic cosmic rays suggest that the maximum lifetime of NH3 in the uppermost meter of the exposed surface is ~109 years, while considerations of Lyman-α ultraviolet and solar wind charged particles suggest shorter timescales by a factor of 10 or 10000. Thus, 109 y is taken as an upper limit to the age of the emplacement event, and it could be substantially younger. The red colorant in the ammoniated H2O in Virgil Fossae and surroundings may be a macromolecular organic material (tholin) thought to give color to much of Pluto's surface, but probably different in composition and age. Owing to the limited spectral range of the New Horizons imaging spectrometer and the signal precision of the data, apart from the H2O and NH3 signatures there are no direct spectroscopic clues to the chemistry of the strongly colored deposit on Pluto. We suggest that the colored material was a component of the fluid reservoir from which the material now on the surface in this region was erupted. Although other compositions are possible, if it is indeed a complex organic material it may incorporate organics inherited from the solar nebula, further processed in a warm aqueous environment inside Pluto. A planet-scale stress pattern in Pluto's lithosphere induced by true polar wander, freezing of a putative interior ocean, and surface loading has caused fracturing in a broad arc west of Sputnik Planitia, consistent with the structure of Virgil Fossae and similar extensional features. This faulting may have facilitated the ascent of fluid in subsurface reservoirs to reach the surface as flows and as fountains of cryoclastic materials, consistent with the appearance of colored, ammoniated H2O ice deposits in and around Virgil Fossae. Models of a cryoflow emerging from sources in Virgil Fossae indicate that the lateral extent of the flow can be several km (Umurhan et al., 2019). The deposit over the full length (> 200 km) of the main trough in the Virgil Fossae complex and extending through the north rim of Elliot crater and varying in elevation over a range of ~2.5 km, suggests that it debouched from multiple sources, probably along the length of the strike direction of the normal faults defining the graben. The source or sources of the ammoniated H2O are one or more subsurface reservoirs that may or may not connect to the global ocean postulated for Pluto's interior. Alternatives to cryovolcanism in producing the observed characteristics of the region around Virgil Fossae are explored in the discussion section of the paper.

We present the case for the presence of complex organic molecules, such as amino acids and nucleobases, formed by abiotic processes on the surface and in near-subsurface regions of Pluto. Pluto's surface is tinted with a range of non-ice substances with colors ranging from light yellow to red to dark brown; the colors match those of laboratory organic residues called tholins. Tholins are broadly characterized as complex, macromolecular organic solids consisting of a network of aromatic structures connected by aliphatic bridging units (e.g., Imanaka et al., 2004; Materese et al., 2014, 2015). The synthesis of tholins in planetary atmospheres and in surface ices has been explored in numerous laboratory experiments, and both gas- and solid-phase varieties are found on Pluto. A third variety of tholins, exposed at a site of tectonic surface fracturing called Virgil Fossae, appears to have come from a reservoir in the subsurface. Eruptions of tholin-laden liquid H_2O from a subsurface aqueous repository appear to have covered portions of Virgil Fossae and its surroundings with a uniquely colored deposit (D.P. Cruikshank, personal communication) that is geographically correlated with an exposure of H_2O ice that includes spectroscopically detected NH_3 (C.M. Dalle Ore, personal communication). The subsurface organic material could have been derived from presolar or solar nebula processes, or might have formed in situ. Photolysis and radiolysis of a mixture of ices relevant to Pluto's surface composition (N_2, CH_4, CO) have produced strongly colored, complex organics with a significant aromatic content having a high degree of nitrogen substitution similar to the aromatic heterocycles pyrimidine and purine (Materese et al., 2014, 2015; Cruikshank et al., 2016). Experiments with pyrimidines and purines frozen in H_2O-NH_3ice resulted in the formation of numerous nucleobases, including the biologically relevant guanine, cytosine, adenine, uracil, and thymine (Materese et al., 2017). The red material associated with the H_2O ice may contain nucleobases resulting from energetic processing on Pluto's surface or in the interior. Some other Kuiper Belt objects also exhibit red colors similar to those found on Pluto and may therefore carry similar inventories of complex organic materials. The widespread and ubiquitous nature of similarly complex organic materials observed in a variety of astronomical settings drives the need for additional laboratory and modeling efforts to explain the origin and evolution of organic molecules. Pluto observations reveal complex organics on a small body that remains close to its place of origin in the outermost regions of the Solar System.

The initial chemical composition of a proto-planetary nebula depends upon the degree to which 1) organic and ice components form on dust grains, 2) organic and molecular species form in the gas phase, 3) organics and ices are exchanged between the gas and solid state, and 4) the precursor and newly formed (more complex) materials survive and are modified in the developing planetary system. Infrared and radio observations of star-forming regions reveal that complex chemistry occurs on icy grains, often before stars even form. Additional processing, through the proto-planetary disk (PPD) further modifies most, but not all, of the initial materials. In fact, the modern Solar System still carries a fraction of its interstellar inheritance (Alexander et al.2017). Here we focus on three examples of small bodies in our Solar System, each containing chemical and dynamical clues to its origin and evolution: the small-cold classical Kuiper Belt object (KBO) 2014 MU69, Pluto, and Saturn’s moon, Phoebe. The New Horizons flyby of 2014 MU69 has given the first view of an unaltered body composed of material originally in the solar nebula at ~45 AU. The spectrum of MU69 reveals methanol ice (not commonly found), a possible detection of water ice, and the noteworthy absence of methane ice (Stern et al. 2019). Pluto’s internal and surface inventory of volatiles and complex organics, together with active geological processes including cryo-volcanism, indicate a surprising level of activity on a body in the outermost region of the Solar System, and the fluid that emerges from subsurface reservoirs may contain material inherited from the solar nebula (Cruikshank et al.2019a,b). Meanwhile, Saturn’s captured moon, Phoebe, carries high D/H in H2O (Clark et al. 2019) and complex organics (Cruikshank et al. 2008), both consistent with its formation in, and inheritance from, the outer region of the solar nebula. Together, these objects provide windows on the origin and evolution of our Solar System and constraints to be considered in future chemical and physical models of PPDs.

We examine the H2O ice phase on the surface of Dione, one of Saturn’s icy satellites, to investigate whether it might harbor cryovolcanic activity induced by a subcrustal body of water. Several studies have searched for such a signature, as summarized in Buratti et al.; however, none has yet produced sufficient evidence to dissipate doubts. In the radiation environment characteristic of Saturn’s icy moons, the presence of crystalline H2O ice has been used as a marker of a high-temperature region. Because ion bombardment will, over time, drive crystalline ice toward an increasingly amorphous state, the current phase of the H2O ice can be used to gauge the temporal temperature evolution of the surface. We adopt a technique described by Dalle Ore et al. to map the fraction of amorphous to crystalline H2O ice on Dione’s surface, observed by the Cassini Visible and Infrared Mapping Spectrometer, and provide an ice exposure age. We focus on a region observed at high spatial resolution and centered on one of the faults of the Wispy Terrain, which is measured to be fully crystalline. By assuming an amorphous to crystalline ice fraction of 5% (i.e., 95% crystallinity), significantly higher than the actual measurement, we obtain an upper limit for the age of the fault of 152 Ma. This implies that the studied fault has been active in the last ∼100 Ma, supporting the hypothesis that Dione might still be active or was active a very short time ago, and similarly to Enceladus, might still be harboring a body of liquid water under its crust.

Planetary satellites such as the Jovian moon Europa and several Kuiper Belt objects (including Pluto) have surfaces consisting largely of H2O ice, which is brittle and behaves as a rock at the low temperatures that prevail in the outer Solar System. Several of those ice-crusted bodies show evidence of tectonic activity indicating high levels of stress. This paper reports on laboratory experiments with pure H2O ice and H2O2–doped H2O ices with H2O2 concentration levels comparable to those in the ices of Europa. Elongated rectangular ice blocks at T = −81 °C [192 K] were stressed at one end to test whether electric currents are generated and capable of flowing down the stress gradient. Pure H2O ice was found to not produce currents above the 10−10 A background level except for occasional transients in the 10−9–10−8 A range during fracture or rapid plastic deformation due to electrons, e’. By contrast, stressing H2O2-doped H2O ices consistently produced electric currents in the 10−7–10−5 A range, due to holes, h•, propagating from the stressed end to the unstressed end. The h• charge carriers are generated by the break-up of peroxy bonds of H2O2 molecules, leading to O−, equivalent to defect electrons or holes h• in the O2− matrix.

Using data from the Infrared Array Camera on the Spitzer Space Telescope, we present photometric observations of a sample of 100 trans-Neptunian objects (TNOs) beyond 2.2 μm. These observations, collected with two broadband filters centered at 3.6 and 4.5 μm, were done in order to study the surface composition of TNOs, which are too faint to obtain spectroscopic measurements. With this aim, we have developed a method for the identification of different materials that are found on the surfaces of TNOs. In our sample, we detected objects with colors that are consistent with the presence of small amounts of water, and we were able to distinguish between surfaces that are predominantly composed of complex organics and amorphous silicates. We found that 86% of our sample have characteristics that are consistent with a certain amount of water ice, and the most common composition (73% of the objects) is a mixture of water ice, amorphous silicates, and complex organics. Twenty-three percent of our sample may include other ices, such as carbon monoxide, carbon dioxide, methane, or methanol. Additionally, only small objects seem to have surfaces dominated by silicates. This method is a unique tool for the identification of complex organics and to obtain the surface composition of extremely faint objects. Furthermore, this method will be beneficial when using the James Webb Space Telescope for differentiating groups within the trans-Neptunian population.

The Saturnian satellite Tethys exhibits geological and spectral properties, whose appearance, nature and spatial distribution partly mirror those identified on the neighboring satellites Dione and Rhea or fit to the picture how spectral surface properties are expected to change from one satellite to the other within the inner Saturnian system. However, we also identified spectral variations that are unique in the Saturnian system. Whereas geologically young surface features are characterized by pure H2O-ice composition with relatively large particles, which match the particle sizes measured for fresh surface features also on Dione and Rhea, geologically old weathered regions are dominated by submicron-sized ice particles. Our investigations confirm that the Odysseus impact event did not cause the formation of Tethys' extended graben system Ithaca Chasma. On the contrary, Odysseus might be responsible for the N-S trending 'icy' bands that mark Tethys' surface in the center of its leading and trailing hemisphere.

The spectral position of the 3.6 micron continuum peak measured on Cassini-VIMS I/F spectra is used as a marker to infer the temperature of the regolith particles covering the surfaces of Saturn's icy satellites. This feature is characterizing the crystalline water ice spectrum which is the dominant compositional endmember of the satellites' surfaces. Laboratory measurements indicate that the position of the 3.6 micron peak of pure water ice is temperature-dependent, shifting towards shorter wavelengths when the sample is cooled, from about 3.65 micron at T=123 K to about 3.55 micron at T=88 K. A similar method was already applied to VIMS Saturn's rings mosaics to retrieve ring particles temperature (Filacchione et al., 2014). We report here about the daytime temperature variations observed on the icy satellites as derived from three different VIMS observation types. Temperature maps are built by mining the complete VIMS dataset collected in years 2004-2009 (pre-equinox) and in 2009-2012 (post equinox) by selecting pixels with max 150 km/pixel resolution. VIMS-derived temperature maps allow to identify thermal anomalies across the equatorial lens of Mimas and Tethys., 42 pages, 15 figures. Accepted for publication in Icarus journal on February 8th 2016

Spectroscopic investigations of primitive asteroid families constrain family evolution and composition and conditions in the solar nebula, and reveal information about past and present distributions of volatiles in the solar system. Visible and near-infrared studies of primitive asteroid families have shown spectral diversity between and within families. Here, we aim to better understand the composition and physical properties of two primitive families with vastly different ages: ancient Themis (∼2.5 Gyr) and young Veritas (∼8 Myr). We analyzed the 5 – 14 µm Spitzer Space Telescope spectra of 11 Themis-family asteroids, including eight previously studied by Licandro et al. (2012), and nine Veritas-family asteroids, for a total of 20 asteroids in our sample. We detect a broad 10-µm emission feature, attributed to fine-grained and/or porous silicate regolith, in all 11 Themis-family spectra and six of nine Veritas-family asteroids, with 10-µm spectral contrast ranging from 1% ± 0.1% to 8.5% ± 0.9%. We used thermal modeling to derive diameters, beaming parameters and albedos for our sample. Asteroids in both families have beaming parameters near unity and geometric albedos in the range 0.03 – 0.14. Spectral contrast of the 10-µm silicate emission feature is correlated with beaming parameter and rotation period in the Themis family, and may be related to near-infrared spectral slope for both families. We see no correlations of 10-µm emission with diameter or albedo for either family. Comparison with laboratory spectra of primitive meteorites suggests these asteroids are similar to meteorites with relatively low abundances of phyllosilicates. Overall, our results suggest the Themis and Veritas families are primitive asteroids with variation in composition and/or regolith properties within both families.

We investigated whether sulfur-bearing species are present on the icy Galilean moon Callisto by analyzing eight near-infrared reflectance spectra collected over a wide range of sub-observer longitudes. We measured the band areas and depths of a 4-micron feature in these spectra, which has been attributed to sulfur dioxide (SO2), as well as carbonates, in previously collected datasets of this moon. All eight spectra we collected display the 4-micron band. The four spectra collected over Callisto's leading hemisphere display significantly stronger 4-micron bands compared to the four trailing hemisphere spectra (> 3-sigma difference). We compared the central wavelength position and shape of Callisto's 4-micron band to laboratory spectra of various sulfur-bearing species and carbonates. Our comparison demonstrates that Callisto's 4-micron band has a spectral signature similar to thermally-altered sulfur, as well as a 4.025 micron feature attributed to disulfanide (HS2). Our analysis therefore supports the presence of S-bearing species on Callisto but is not consistent with the presence of SO2. The significantly stronger 4-micron band detected on Callisto's leading hemisphere could result from collisions with H2S-rich dust grains that originate on Jupiter's retrograde irregular satellites or implantation of magnetospheric S ions that originate from volcanic activity on Io. Alternatively, S-bearing species could be native to Callisto and are exposed by dust collisions and larger impacts that drive regolith overturn, primarily on its leading side.

International audience; On July 14, 2015, NASA's New Horizons spacecraft encountered the Pluto-system. Using the near-infrared spectral imager, New Horizons obtained the first spectra of Nix, Hydra, and Kerberos and detected the 1.5 and 2.0 µm bands of H 2 O-ice on all three satellites. On Nix and Hydra, New Horizons also detected bands at 1.65 and 2.21 µm that indicate crystalline H 2 O-ice and an ammoniated species, respectively. A similar band linked to NH 3-hydrate has been detected on Charon previously. However, we do not detect the 1.99 µm band of NH 3-hydrate. We consider NH 4 Cl (ammonium chloride), NH 4 NO 3 (ammonium nitrate) and (NH 4) 2 CO 3 (ammonium carbonate) as potential candidates, but lack sufficient laboratory measurements of these and other ammoniated species to make a definitive conclusion. We use the observations of Nix and Hydra to estimate the surface temperature and crystalline H 2 O-ice fraction. We find surface temperatures < 20 K ( 30% for Nix an Hydra, respectively. New Horizons observed Nix and Hydra twice, about 2-3 hours apart, or 5 and 25% of their respective rotation periods. We find no evidence for rotational differences in the disk-averaged spectra between the two observations of Nix or Hydra. We perform a pixel-by-pixel analysis of Nix's disk-resolved spectra and find that the surface is consistent with a uniform crystalline H 2 O-ice fraction, and a ∼ 50% variation in the normalized band area of the 2.21 µm band with a minimum associated with the red blotch seen in color images of Nix. Finally, we find evidence for bands on Nix and Hydra at 2.42 and possibly 2.45 µm, which we cannot identify, and, if real, do not appear to be associated with the ammoniated species. We do not detect other ices, such as CO 2 , CH 3 OH and HCN.

International audience; The data returned from NASA's New Horizons spacecraft have given us an unprecedented, detailed look at the Pluto system. New Horizons' Ralph/MVIC (Multispectral Visible Imaging Camera) is composed of 7 independent CCD arrays on a single substrate. Among these are a red channel (540-700 nm), near-infrared channel (780-975 nm), and narrow band methane channel (860-910 nm). By comparing the relative reflectance of these channels we are able to produce high-resolution methane "equivalent width" (based on the 890 nm absorption band) and spectral slope maps of Pluto's surface. From these maps we can then quantitatively study the relationships between methane distribution, redness, and other parameters like latitude and elevation. We find Pluto's surface to show a great diversity of terrains, particularly in the equatorial region between 30°N and 30°S latitude. Methane "equivalent width" also shows some dependence on elevation (while spectral slope shows very little).

The goal of this project is to study the properties of H 2 O ice in the environment of the Saturn satellites and in particular to measure the relative amounts of crystalline and amorphous H 2 O ice in and around two craters on Rhea. The craters are remnants of cataclysmic events that, by raising the local temperature, melted the ice, which subsequently crystallized. Based on laboratory experiments it is expected that, when exposed to ion bombardment at the temperatures typical of the Saturn satellites, the crystalline structure of the ice will be broken, resulting in the disordered, amorphous phase. We therefore expect the ice in and around the craters to be partially crystalline and partially amorphous. We have designed a technique that estimates the relative amounts of crystalline and amorphous H 2 O ice based on measurements of the distortion of the 2-μm spectral absorption band. The technique is best suited for planetary surfaces that are predominantly icy, but works also for surfaces slightly contaminated with other ices and non-ice components. We apply the tool to two areas around the Inktomi and the Obatala craters. The first is a young impact crater on the leading hemisphere of Rhea, the second is an older one on the trailing hemisphere. For each crater we obtain maps of the fraction of crystalline ice, which were overlain onto Imaging Science Subsystem (ISS) images of the satellite searching for correlations between crystallinity and geography. For both craters the largest fractions of crystalline ice are in the center, as would be intuitively expected since the ‘ground zero’ areas should be most affected by the effects of the impact. The overall distribution of the crystalline ice fraction maps the shape of the crater and, in the case of Inktomi, of the rays. The Inktomi crater ranges between a maximum fraction of 67% crystalline ice to a minimum of 39%. The Obatala crater varies between a maximum of 51% and a minimum of 33%. Based on simplifying assumptions and the knowledge that crystalline ice exposed to ion bombardment transforms into amorphous at a known rate, we estimate the age of the Obatala crater to be ∼450 Ma.

We present an analysis of the colors available for seven trans-neptunian objects (TNOs) and three centaurs among the reddest known, aimed at characterizing their surface chemical properties. In particular we seek to obtain evidence in support of the proposed correlation between the visible coloration of the surface of TNOs and their surface compositions (Brown, M.E., Schaller, E.L., Fraser, W.C. [2011]. Astrophys. J. 739, L60). The analysis focuses on nine available colors in the visible–near IR (0.3–4.5 μm) spectral range scaled to the V albedo to provide a proxy for the spectral shape of the objects. The colors include Spitzer IRAC data never published before, key in providing an effective constraint in the discrimination of ices contributing to the surface composition of the objects. Compositions are obtained by comparing the data to a grid of radiative transfer models convolved by the filter response functions of the colors adopted in the spectrum-proxies to match the resolution of the observations. We find evidence suggesting the presence of hydrocarbons and/or methanol on the surfaces of most objects in our sample, supporting the hypothesis by Brown et al. (Brown, M.E., Schaller, E.L., Fraser, W.C. [2011]. Astrophys. J. 739, L60) that the coloration of red TNOs could be linked to their methanol content. From our finding of methanol/hydrocarbon ices on the surfaces of the objects in our sample of very red TNOs and centaurs we infer that ultra-red objects in general might contain these ices and therefore might have formed in the outer part of the Solar System. We also deduce that the surfaces of most of the very red TNOs in our dataset are probably still quite pristine, and that their organic materials could have been produced by irradiation of the volatile ices whose traces are still present on their surface. Although our sample is small, we infer that the irradiation process is still in progress, as hinted by the centaurs’ slightly elevated organic amounts at smaller perihelion distances. However, considering the relatively similar amounts of organics found in our data at a wide variety of perihelion distances, we also infer that it could have started before Neptune’s migration. The technique used to constrain the composition described as part of this study introduces a new approach at investigating the surface chemistry of the very small and numerous objects that constitute the bulk of the TNO and centaur populations. This innovative method has the potential to provide constraints for irradiation theories and for models of dynamical and chemical evolution of the Solar System.

The surface of Pluto as it is understood on the eve of the encounter of the New Horizons spacecraft (mid-2015) consists of a spatially heterogeneous mix of solid N 2 , CH 4 , CO, C 2 H 6 , and an additional component that imparts color, and may not be an ice. The known molecular ices are detected by near-infrared spectroscopy. The N 2 ice occurs in the hexagonal crystalline β-phase, stable at T > 35.6 K. Spectroscopic evidence for wavelength shifts in the CH 4 bands attests to the complex mixing of CH 4 and N 2 in the solid state, in accordance with the phase diagram for N 2 + CH 4 . Spectra obtained at several aspects of Pluto’s surface as the planet rotates over its 6.4-day period show variability in the distribution of CH 4 and N 2 ices, with stronger CH 4 absorption bands associated with regions of higher albedo, in correlation with the visible rotational light curve. CO and N 2 ice absorptions are also strongly modulated by the rotation period; the bands are strongest on the anti-Charon hemisphere of Pluto. Longer term changes in the strengths of Pluto’s absorption bands occur as the viewing geometry changes on seasonal time-scales, although a complete cycle has not been observed. The non-ice component of Pluto’s surface may be a relatively refractory material produced by the UV and cosmic-ray irradiation of the surface ices and gases in the atmosphere, although UV does not generally penetrate the atmospheric CH 4 to interact with the surface. Laboratory simulations indicate that a rich chemistry ensues by the irradiation of mixtures of the ices known to occur on Pluto, but specific compounds have not yet been identified in spectra of the planet. Charon’s surface is characterized by spectral bands of crystalline H 2 O ice, and a band attributed to one or more hydrates of NH 3 . Amorphous H 2 O ice may also be present; the balance between the amorphization and crystallization processes on Charon remains to be clarified. The albedo of Charon and its generally spatially uniform neutral color indicate that a component, not yet identified, is mixed in some way with the H 2 O and NH 3 · n H 2 O ices. Among the many known small bodies in the transneptunian region, several share characteristics with Pluto and Charon, including the presence of CH 4 , N 2 , C 2 H 6 , H 2 O ices, as well as components that yield a wide variety of surface albedo and color. The New Horizons investigation of the Pluto–Charon system will generate new insight into the physical properties of the broader transneptunian population, and eventually to the corresponding bodies expected in the numerous planetary systems currently being discovered elsewhere in the Galaxy.

The spectral properties and thermal behavior of Saturn’s rings are determined from a dataset of ten radial mosaics acquired by Cassini–VIMS (Visual and Infrared Mapping Spectrometer) between October 29th 2004 and January 27th 2010 with phase angle ranging between 5.7° and 132.4° and elevation angles between −23.5° and 2.6°. These observations, after reduction to spectrograms, e.g. 2D arrays containing the VIS–IR (0.35–5.1 μm) spectral information versus radial distance from Saturn (from 73.500 to 141.375 km, 400 km/bin), allow us to compare the derived spectral and thermal properties of the ring particles on a common reference. Spectral properties: rings spectra are characterized by an intense reddening at visible wavelengths while they maintain a strong similarity with water ice in the infrared domain. Significant changes in VIS reddening, water ice abundance and grain sizes are observed across different radial regions resulting in correlation with optical depth and local structures. The availability of observations taken at very different phase angles allows us to examine spectrophotometric properties of the ring’s particles. When observed at high phase angles, a remarkable increase of visible reddening and water ice band depths is found, probably as a consequence of the presence of a red-colored contaminant intimately mixed within water ice grains and of multiple scattering. At low phases the analysis of the 3.2–3.6 μm range shows faint spectral signatures at 3.42–3.52 μm which are compatible with the CH 2 aliphatic stretch. The 3.29 μm PAH aromatic stretch absorption is not clearly detectable on this dataset. VIMS results indicate that ring particles contain about 90–95% water ice while the remaining 5–10% is consistent with different contaminants like amorphous carbon or tholins. However, we cannot exclude the presence of nanophase iron or hematite produced by iron oxidation in the rings tenuous oxygen atmosphere, intimately mixed with the ice grains. Greater pollution caused by meteoritic material is seen in the C ring and Cassini division while the low levels of aliphatic material observed by VIMS in the A and B rings particles are an evidence that they are pristine. Thermal properties: the ring-particles’ temperature is retrieved by fitting the spectral position of the 3.6 μm continuum peak observed on reflectance spectra: in case of pure water ice the position of the peak, as measured in laboratory, shifts towards shorter wavelengths when temperature decreases, moving from about 3.65 μm at 123 K to about 3.55 μm at 88 K. When applied to VIMS rings observations, this method allows us to infer the average temperature across ring regions sampled through 400 km-wide radial bins. Comparing VIMS temperature radial profiles with similar CIRS measurements acquired at the same time we have found a substantial agreement between the two instruments’ results across the A and B rings. In general VIMS measures higher temperatures than CIRS across C ring and Cassini division as a consequence of the lower optical depth and the resulting pollution that creates a deviation from pure water ice composition of these regions. VIMS results point out that across C ring and CD the 3.6 μm peak wavelength is always higher than across B and A rings and therefore C ring and CD are warmer than A and B rings. VIMS observations allow us to investigate also diurnal and seasonal effects: comparing antisolar and subsolar ansae observations we have measured higher temperature on the latter. As the solar elevation angle decreases to 0° (equinox), the peak’s position shifts at shorter wavelengths because ring’s particles becomes colder. Merging multi-wavelength data sets allow us to test different thermal models, combining the effects of particle albedo, regolith composition, grain size and thermal properties with the ring structures.

We present a quantitative analysis of the hydrocarbon and other organic molecular inventory as a component of the low-albedo material of Saturn’s satellite Iapetus, based on a revision of the calibration of the Cassini VIMS instrument. Our study uses hyperspectral data from a mosaic of Iapetus’ surface (Pinilla-Alonso, N., Roush, T.L., Marzo, G.A., Cruikshank, D.P., Dalle Ore, C.M. [2011]. Icarus 215, 75–82) constructed from VIMS data on a close fly-by of the satellite. We extracted 2235 individual spectra of the low-albedo regions, and with a clustering analysis tool (Dalle Ore, C.M., Cruikshank, D.P., Clark, R.N. [2012]. Icarus 221, 735–743), separated them into two spectrally distinct groups, one concentrated on the leading hemisphere of Iapetus, and the other group on the trailing. This distribution is broadly consistent with that found from Cassini ISS data analyzed by Denk et al. (Denk, T. et al. [2010]. Science 327, 435–439). We modeled the average spectra of the two geographic regions using the materials and techniques described by Clark et al. (Clark, R.N., Cruikshank, D.P., Jaumann, R., Brown, R.H., Stephan, K., Dalle Ore, C.M., Livio, K.E., Pearson, N., Curchin, J.M., Hoefen, T.M., Buratti, B.J., Filacchione, G., Baines, K.H., Nicholson, P.D. [2012]. Icarus 218, 831–860), and after dividing the Iapetus spectrum by the model for each case, we extracted the resulting spectra in the interval 2.7–4.0 μm for analysis of the organic molecular bands. The spectra reveal the C H stretching modes of aromatic hydrocarbons at ∼3.28 μm (∼3050 cm−1), plus four blended bands of aliphatic CH2 and CH3 in the range ∼3.36–3.52 μm (∼2980–2840 cm−1). In these data, the aromatic band, probably indicating the presence of polycyclic aromatic hydrocarbons (PAH), is unusually strong in comparison to the aliphatic bands, as was found for Hyperion (Dalton, J.B., Cruikshank, D.P., Clark, R.N. [2012]. Icarus 220, 752–776; Dalle Ore, C.M., Cruikshank, D.P., Clark, R.N. [2012], op. cit.) and Phoebe (Dalle Ore, C.M., Cruikshank, D.P., Clark, R.N. [2012], op. cit.). Our Gaussian decomposition of the organic band region suggests the presence of molecular bands in addition to those noted above, specifically bands attributable to cycloalkanes, olefinic compounds, CH3OH, and N-substituted PAHs, as well as possible Hn-PAHs (PAHs with excess peripheral H atoms). In a minimalist interpretation of the Gaussian band fitting, we find the ratio of aromatic CH to aliphatic CH2 + CH3 functional groups for both the leading and trailing hemispheres of Iapetus is ∼10, with no clear difference between them. In the aliphatic component of the surface material, the ratio CH2/CH3 is 4.0 on the leading hemisphere and 3.0 on the trailing; both values are higher than those found in interstellar dust and other Solar System materials and the difference between the two hemispheres may be statistically significant. The superficial layer of low-albedo material on Iapetus originated in the interior of Phoebe and is being transported to and deposited on Iapetus (and Hyperion) in the current epoch via the Phoebe dust ring (Tosi, F., Turrini, D., Coradini, A., Filacchione, G., and the VIMS Team [2010]. Mon. Not. R. Astron. Soc. 403, 1113–1130; Tamayo, D., Burns, J.A., Hamilton, D.P., Hedman, M.M. [2011]. Icarus 215, 260–278). The PAHs on Iapetus exist in a H2O-rich environment, and consequently are subject to UV destruction by hydrogenation on short time-scales. The occurrence of this material is therefore consistent with the assertion that the deposition of the PAH-bearing dust is occurring at the present time. If the organic inventory we observe represents the interior composition of Phoebe, we may be sampling the original material from a region of the solar nebula beyond Neptune where Phoebe formed prior to its capture by Saturn ( Johnson, T.V., Lunine, J.I. [2005] . Nature 435, 69–71).

The width and temperature of the active fissures on Saturn’s satellite Enceladus provide key observable constraints on physical models of these geyser-like eruptions. We analyze a sequence of high spatial resolution near-infrared spectra acquired with VIMS at 0.025 s intervals during a 74 km altitude flyover of the South Pole of Enceladus by the Cassini spacecraft on 14 April 2012 UTC. A thermal-emission spectrum covering 3- to 5-μm wavelengths was detected as the field of view crossed one of the four major fissures, Baghdad Sulcus, within 1 km of 82.36S latitude and 28.24W longitude. We interpret this spectrum as thermal emission from a linear fissure with temperature 197 ± 20 K and width 9 m. At the above wavelengths, the spectrum is dominated by the warmest temperature component. Looking downward into the fissure at only 13° from the vertical, we conclude that our results measure the temperature of the interior fissure walls (and the H 2 O vapor) at depths within 40 m of the surface.

© 2016 Elsevier Inc. We discuss two semi-independent calibration techniques used to determine the inflight radiometric calibration for the New Horizons’ Multi-spectral Visible Imaging Camera (MVIC). The first calibration technique compares the measured number of counts (DN) observed from a number of well calibrated stars to those predicted using the component-level calibration. The ratio of these values provides a multiplicative factor that allows a conversation between the preflight calibration to the more accurate inflight one, for each detector. The second calibration technique is a channel-wise relative radiometric calibration for MVIC's blue, near-infrared and methane color channels using Hubble and New Horizons observations of Charon and scaling from the red channel stellar calibration. Both calibration techniques produce very similar results (better than 7% agreement), providing strong validation for the techniques used. Since the stellar calibration described here can be performed without a color target in the field of view and covers all of MVIC's detectors, this calibration was used to provide the radiometric keyword values delivered by the New Horizons project to the Planetary Data System (PDS). These keyword values allow each observation to be converted from counts to physical units; a description of how these keyword values were generated is included. Finally, mitigation techniques adopted for the gain drift observed in the near-infrared detector and one of the panchromatic framing cameras are also discussed.

Iapetus, one of the large satellites of Saturn, has been studied over the centuries for its signature brightness contrast, light on one side and dark on the opposite. It has recently been suggested that the dark material is a combination of native and exogenous materials with distinct histories. We present an analysis of parts of the Cassini Regio, the darkest region on the leading hemisphere of Iapetus, focusing on the hydrocarbon signature with a view to detect and investigate differences in the material(s). We find variations in the hydrocarbon bands with geographic location, one type predominantly located on the leading hemisphere. A comparison with the equivalent spectral features on Phoebe and Hyperion reveals a predictable resemblance between the leading hemisphere material and Phoebe and an unexpected likeness between Hyperion’s darkest material and Iapetus’ trailing hemisphere surface. An analysis of the slope in the visible part of the spectrum is strongly affected by a rise in the continuum (∼0.35–0.65 μm) attributed to Rayleigh scattering from nano-size particles on the surface. The continuum rise varies in strength with the albedo and H 2 O ice content, and when it is properly accounted for, the overall slope in all the identified spectral units is the same over the interval 0.35–2.3 μm, independent of albedo or ice abundance. The interpretation of current and previous results offers two different scenarios illustrated by the presence of one vs. two dark materials distributed over the Iapetus surface. We describe the scenarios and their implications. The appearance of the aromatic and aliphatic absorption bands together in their measured relative strengths makes this spectral signature unique, and thus enables the comparison among the three satellites.

Compositional mapping of the surface of Hyperion using Cassini Visual and Infrared Mapping Spectrometer (VIMS) observations reveals a heterogeneous surface dominated by water ice accompanied by additional materials. Carbon dioxide, as evidenced by a prominent absorption band centered at 4.26 μm, is distributed over most of the surface, including icy regions. This does not represent exposures of pure CO2 ice, but concentrations of CO2 molecules adsorbed on other materials or complexed in H2O, perhaps as a clathrate (Cruikshank, D.P., Meyer, A.W., Brown, R.H., Clark, R.N., Jaumann, R., Stephan, K., Hibbitts, C.A., Sandford, S.A., Mastrapa, R., Filacchione, G., Dalle Ore, C.M., Nicholson, P.D., Buratti, B.J., McCord, T.B., Nelson, R.M., Dalton, J.B., Baines, K.H., Matson, D.L., The VIMS Team [2010]. Icarus 206, 561–572). Localized deposits of low-albedo material in subcircular depressions exhibit spectral absorptions indicative of C–H in aromatic (3.29 μm) and aliphatic (3.35–3.50 μm) hydrocarbons. An absorption band at 2.42 μm that is also seen on other saturnian satellites, tentatively identified as H2 (Clark, R.N. et al. [2011]. In: Proc. AAS-DPS Meeting, 43, 1563; Clark et al., in preparation, 2012) adsorbed on dark material grains, is also prominent. Our best spectral models included H2O and CO2 ice, with small amounts of nanophase Fe and Fe2O3. Weaker and more spatially scattered absorption features are also found at 4.48, 4.60, and 4.89 μm, although no clear molecular identifications have yet been made. While strongest in the low-albedo deposits, the CO2, hydrocarbon and putative H2 bands vary in strength throughout the icy regions, as do the 4.48-, 4.60- and 4.89-μm bands, suggesting that this background ice is laced with a complex mixture of non-ice compounds.

Complex organic materials may exist as haze layers in the atmosphere of Titan and as dark coloring agents on icy satellite surfaces. Laboratory measurements of optical constants of plausible complex organic materials are necessary for quantitative evaluation from remote sensing observations, and to document the existence of complex organic materials in the extraterrestrial environments. The recent Cassini VIMS and CIRS observations provide new constraints on Titan’s haze properties in the mid-infrared wavelength region. Here, we present the optical constants (2.5–25 μm) of Titan tholins generated with cold plasma irradiation of a N 2 /CH 4 (90/10) gas mixture at pressures of 0.26 mbar, 1.6 mbar, and 23 mbar. Our new optical constants of three types of Titan tholins suggest that no single Titan tholin in this study fulfills all the observational constraints of the Titan haze material. The discrepancy remains a challenge for future modeling and laboratory efforts that aim toward a better understanding of Titan’s haze material.

We present a detailed study of an Iapetus mosaic of VIMS data with high spatial resolution (0.5 × 0.5° or ∼6.4 km/pixel). The spectra were taken in August 2007 and provide the highest VIMS spatial resolution data for this object during Cassini’s primary mission. We analyze this set of data using a statistical clustering approach to reduce the analysis of a large number of data (∼10 4 spectra from 0.35 to 5.10 μm) to the study of seven representative groups accounting for 99.6% of the surface covered by the original sample. We analyze the spectral absorption bands in the spectra of the different clusters indicative of different composition over the observed surface. We find coherence between the distribution of the clusters and the geographical features on the surface. We give special attention to the study of the water ice and CO 2 bands. We find that CO 2 is widespread over the entire surface being studied, including the bright and dark areas on Iapetus’ surface, and is probably trapped at the molecular level with other materials. The strength of the CO 2 band in the areas where both, H 2 O- and carbon-bearing materials exist, gives support to the hypothesis that this volatile is formed on the surface of Iapetus as a product of irradiation of these two components. Finally, we also compare the Iapetus CO 2 with that on other satellites confirming, that there are evident differences on the center, depth and width of the band on Iapetus and Phoebe, where CO 2 has been suggested to be endogenous.

We report on thermal observations of the Pluto–Charon system acquired by the Spitzer observatory in August–September 2004. The observations, which consist of (i) photometric measurements (8 visits) with the Multiband Imaging Photometer (MIPS) at 24, 70 and 160 μm and (ii) low-resolution spectra (8 visits) over 20–37 μm with the Infrared Spectrometer (IRS), clearly exhibit the thermal lightcurve of Pluto/Charon at a variety of wavelengths. They further indicate a steady decrease of the system brightness temperature with increasing wavelength. Observations are analyzed by means of a thermophysical model, including the effects of thermal conduction and surface roughness, and using a multi-terrain description of Pluto and Charon surfaces in accordance with visible imaging and lightcurves, and visible and near-infrared spectroscopy. Three units are considered for Pluto, respectively covered by N2 ice, CH4 ice, and a tholin/H2O mix. Essential model parameters are the thermal inertia of Pluto and Charon surfaces and the spectral and bolometric emissivity of the various units. A new and improved value of Pluto’s surface thermal inertia, referring to the CH4 and tholin/H2O areas, is determined to be ΓPl = 20–30 J m−2 s−1/2 K−1 (MKS). The high-quality 24-μm lightcurve permits a precise assessment of Charon’s thermal emission, indicating a mean surface temperature of 55.4 ± 2.6 K. Although Charon is on average warmer than Pluto, it is also not in instantaneous equilibrium with solar radiation. Charon’s surface thermal inertia is in the range ΓCh = 10–150 MKS, though most model solutions point to ΓCh = 10–20 MKS. Pluto and Charon thermal inertias appear much lower than values expected for compact ices, probably resulting from high surface porosity and poor surface consolidation. Comparison between Charon’s thermal inertia and even lower values estimated for two other H2O-covered Kuiper-Belt objects suggests that a vertical gradient of conductivity exists in the upper surface of these bodies. Finally, the observations indicate that the spectral emissivity of methane ice is close to unity at 24 μm and decreases with increasing wavelength to ∼0.6 at 100 μm. Future observations of thermal lightcurves over 70–500 μm by Herschel should be very valuable to further constrain the emissivity behavior of the Pluto terrains.

International audience; We present new photometric and spectroscopic observations of the Pluto-Charon system carried out at the VLT-ESO (Chile) with two 8-meter telescopes equipped with the FORS2, ISAAC and SINFONI instruments. The spectra were obtained in the 0.6-2.45μm range with a spectral resolution from 300 to 1500. The SINFONI data were obtained using Adaptive Optics, allowing a complete separation of the two bodies. We derive both objects' magnitudes in the near infrared and convert them into albedo values. These first near infrared photometric data allow to adjust the different parts of Pluto's spectrum, provided by the three instruments. We run spectral models in order to give chemical and physical constraints on the surface of Pluto and Charon. We discuss the dilution properties of the methane ice and its implications on Pluto's surface. The heterogeneities of the pure and diluted methane ice on Pluto's surface is also investigated. The high signal-to-noise level of the data and our analyses may support the presence of ethane ice on the surface of Pluto, which is one of the main products of the methane irradiation and photolysis. The analyses of the spectra of Charon suggest that the water ice is almost completely in its crystalline form and that the ammonia compound is hydrated on the surface of this satellite.

International audience; The dwarf planet (90377) Sedna is one of the most remote solar system objects accessible to investigations. To better constrain its surface composition and to investigate the possible heterogeneity of the surface of Sedna, several observations have been carried out at ESO-VLT with the powerful spectrometer SINFONI observing simultaneously the H and K bands. The analyzed spectra (obtained in 2005, 2007, and 2008) show a non-uniform spectral signature, particularly in the K band. Spectral modeling using the Shkuratov radiative transfer code for surface scattering has been performed using the various sets of data, including previous observations at visible wavelengths and photometry at 3.6 and 4.5 mum by the Spitzer Space Telescope. The visible and near-infrared spectra can be modeled with organic materials (triton and titan tholin), serpentine, and H2O ice in fairly significant amounts, and CH4, N2, and C2H6 in varying trace amounts. One of the spectra obtained in 2005 October shows a different signature in the K band and is best modeled with CH3OH in place of CH4, with reduced amounts of serpentine and with the addition of olivine. The compositional surface heterogeneity can give input on the past history as well clues to the origin of this peculiar, distant object.

Spectra of Triton between 1.8 and 5.5 μm, obtained in 2007 May and 2009 November, have been analyzed to determine the global surface composition. The spectra were acquired with the grism and the prism of the Infrared Camera on board AKARI with spectral resolutions of 135 and 22, respectively. The data from 4 to 5 μm are shown in this Letter and compared to the spectra of N2, CO, and CO2, i.e., all the known ices on this moon that have distinct bands in this previously unexplored wavelength range. We report the detection of a 4σ absorption band at 4.76 μm (2101 cm–1), which we attribute tentatively to the presence of solid HCN. This is the sixth ice to be identified on Triton and an expected component of its surface because it is a precipitating photochemical product of Triton's thin N2 and CH4 atmosphere. It is also formed directly by irradiation of mixtures of N2 and CH4 ices. Here we consider only pure HCN, although it might be dissolved in N2 on the surface of Triton because of the evaporation and recondensation of N2 over its seasonal cycle. The AKARI spectrum of Triton also covers the wavelengths of the fundamental (1-0) band of β-phase N2 ice (4.296 μm, 2328 cm–1), which has never been detected in an astronomical body before, and whose presence is consistent with the overtone (2-0) band previously reported. Fundamental bands of CO and CO2 ices are also present.

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples. In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters. On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.

We report the detailed analysis of the spectrophotometric properties of Saturn’s icy satellites as derived by full-disk observations obtained by visual and infrared mapping spectrometer (VIMS) experiment aboard Cassini. In this paper, we have extended the coverage until the end of the Cassini’s nominal mission (June 1st 2008), while a previous paper ( Filacchione, G., and 28 colleagues [2007]. Icarus 186, 259–290 , hereby referred to as Paper I) reported the preliminary results of this study. During the four years of nominal mission, VIMS has observed the entire population of Saturn’s icy satellites allowing us to make a comparative analysis of the VIS–NIR spectral properties of the major satellites (Mimas, Enceladus, Tethys, Dione, Rhea, Hyperion, Iapetus) and irregular moons (Atlas, Prometheus, Pandora, Janus, Epimetheus, Telesto, Calypso, Phoebe). The results we discuss here are derived from the entire dataset available at June 2008 which consists of 1417 full-disk observations acquired from a variety of distances and inclinations from the equatorial plane, with different phase angles and hemispheric coverage. The most important spectrophotometric indicators (as defined in Paper I: I / F continua at 0.55 μm, 1.822 μm and 3.547 μm, visible spectral slopes, water and carbon dioxide bands depths and positions) are calculated for each observation in order to investigate the disk-integrated composition of the satellites, the distribution of water ice respect to “contaminants” abundances and typical regolith grain properties. These quantities vary from the almost pure water ice surfaces of Enceladus and Calypso to the organic and carbon dioxide rich Hyperion, Iapetus and Phoebe. Janus visible colors are intermediate between these two classes having a slightly positive spectral slope. These results could help to decipher the origins and evolutionary history of the minor moons of the Saturn’s system. We introduce a polar representation of the spectrophotometric parameters as function of the solar phase angle (along radial distance) and of the effective longitude interval illuminated by the Sun and covered by VIMS during the observation (in azimuth) to better investigate the spatial distribution of the spectrophotometric quantities across the regular satellites hemispheres. Finally, we report the observed spectral positions of the 4.26 μm band of the carbon dioxide present in the surface material of three outermost moons Hyperion, Iapetus and Phoebe.