1. Synthesis of Novel Exocyclic Allenes with a Norbornene Fragment
- Author
-
I. M. Sakhautdinov, A. F. Mukhamet’yanova, M. S. Yunusov, and T. R. Nugumanov
- Subjects
chemistry.chemical_classification ,010405 organic chemistry ,Fragment (computer graphics) ,Stereochemistry ,Organic Chemistry ,Cumulene ,Arndt–Eistert reaction ,01 natural sciences ,0104 chemical sciences ,Amino acid ,chemistry.chemical_compound ,chemistry ,Group (periodic table) ,Norbornene - Abstract
N-Substituted amino acids with a norbornene fragment were synthesized by the direct fusion of amino acids with endic anhydride at 150°C. The synthesized compounds were used for one-pot synthesis of novel stable allenes with an exocyclic cumulene group derived from l-phenyl-3-(triphenylphosphoranylidene)-pyrrolidine-2,5-dione has been carried out.
- Published
- 2019