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Observed reductions in Earth's surface temperature following explosive volcanic eruptions have been used as a proxy for geoengineering of climate by the artificial enhancement of stratospheric sulfate. Earth cools following major eruptions due to an increase in the reflection of sunlight caused by a dramatic enhancement of the stratospheric sulfate aerosol burden. Significant global cooling has been observed following the four major eruptions since 1900: Santa Mar'ıa, Mount Agung, El Chich'on and Mt. Pinatubo, leading IPCC (2007) to state "major volcanic eruptions can, thus, cause a drop in global mean surface temperature of about half a degree Celsius that can last for months and even years". We use a multiple linear regression model applied to the global surface temperature anomaly to suggest that exchange of heat between the atmosphere and ocean, driven by variations in the strength of the Atlantic Meridional Overturning Circulation (AMOC), has been a factor in the decline of global temperature following these eruptions. The veracity of this suggestion depends on whether sea surface temperature (SST) in the North Atlantic, sometimes called the Atlantic Multidecadal Oscillation, but here referred to as Atlantic Multidecadal Variability (AMV), truly represents a proxy for the strength of the AMOC. Also, precise quantification of global cooling due to volcanoes depends on how the AMV index is detrended. If the AMV index is detrended using anthropogenic radiative forcing of climate, we find that surface cooling attributed to Mt. Pinatubo, using the Hadley Centre/University of East Anglia surface temperature record, maximises at 0.14°C globally and 0.32 °C over land. These values are about a factor of 2 less than found when the AMV index is neglected in the model and quite a bit lower than the canonical 0.5 °C cooling usually attributed to Pinatubo. This result is driven by the high amplitude, low frequency component of the AMV index, demonstrating that reduced impact of volcanic cooling upon consideration of the AMV index is driven by variations in North Atlantic SST that occur over time periods much longer than those commonly associated with major volcanic eruptions. The satellite record of atmospheric temperature from 1978 to present and other century-long surface temperature records are also consistent with the suggestion that volcanic cooling may have been over estimated by about a factor of 2 due to prior neglect of ocean circulation. Our study suggests a recalibration may be needed for the proper use of Mt. Pinatubo as a proxy for geoengineering of climate. Finally, we highlight possible shortcomings in simulations of volcanic cooling by general circulation models, which are also being used to assess the impact of geoengineering of climate via stratospheric sulfate injection. [ABSTRACT FROM AUTHOR]

The article offers information on the retrieval algorithm for bromine radicals (BrO) from Scanning Imaging Absorption Spectometer for Atmospheric Chartography (SCIAMACHY) limb near-ultraviolet (UV) measurements data. It says that the retrieval algorithms show agreement with the independent observation of balloon within one standard deviation regarding retrieval noise. It states that the data shows stratospheric loading.

Key kinetic parameters governing the partitioning of chlorine species in the Antarctic polar stratosphere were retrieved from 28 days of chlorine monoxide (CIO) microwave radiometer measurements made during the late winter/early spring of 2005 at Scott Base (77.85° S, 166.75° E). During day-time the loss of the ClO dimer chlorine peroxide (ClOOCl) occurs mainly by photolysis. Some time after sunrise, a photochemical equilibrium is established and the ClO/ClOOCl partitioning is determined by the ratio of the photolysis frequency, J, and the dimer formation rate, kf. The values of J and kf from laboratory studies remain uncertain to a considerable extent, and as a complement to these ongoing studies, the goal of this work is to provide a constraint on that uncertainty based on observations of ClO profiles in the Antarctic. First an optimal estimation technique was used to derive J/kf ratios for a range of Keq values. The optimal estimation forward model was a photochemical box model that takes J, kf, and Keq as inputs, together with a priori profiles of activated chlorine (ClOx = C1O+2XC1OOC1), profiles of ozone, temperature, and pressure. JPL06 kinetics are used as a priori in the optimal estimation and for all other chemistry in the forward model. Using the more recent JPL09 kinetics results in insignificant differences in the retrieved value of J/kf. A complementary approach was used to derive the optimal kinetic parameters; the full parameter space of J, kf, Keq and ClOx was sampled to find the minimum in differences between measured and modelled ClO profiles. Furthermore, values of Keq up to 2.0 times larger than recommended by JPL06 were explored to test the sensitivity of the J/kf ratio to changes in Keq. The results show that the retrieved J/kf ratios bracket the range of 1.23 to 1.97 times the J/kf value recommended by JPL06 over the range of Keq values considered. The retrieved J/kf ratios lie in the lower half of the large uncertainty range of J/kf recommended by JPL06 and towards the upper portion of the smaller uncertainty range recommended by JPL09. [ABSTRACT FROM AUTHOR]