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1. Pyrazine-bridged polymetallic copper–iridium clusters

2. Deciphering complexity in Pd–catalyzed cross-couplings

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3. Levoglucosenone-derived synthesis of bio-based solvents and polyesters

4. Fine-tuning the efficiency of para-hydrogen-induced hyperpolarization by rational N-heterocyclic carbene design

5. Splay Nematic Phase

7. Halogen-bonded liquid-crystalline complexes formed from 4-alkoxyphenylpyridines with iodine and with interhalogens

8. Hydrogen-bonded liquid crystals formed from 4-alkoxystilbazoles and chlorophenols

11. Indole-ynones as Privileged Substrates for Radical Dearomatizing Spirocyclization Cascades

12. Crystal and molecular structure of series of triphilic ionic liquid-crystalline materials based on the 1,2,4-triazolium cation

13. Synthesis of medium-ring lactams and macrocyclic peptide mimetics via conjugate addition/ring expansion cascade reactions

16. Ir I (η 4 -diene) precatalyst activation by strong bases: formation of an anionic Ir III tetrahydride

17. Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalytic Species for Suzuki–Miyaura Couplings (X = P, As)

18. Radical–anion coupling through reagent design: hydroxylation of aryl halides†

19. The liquid-crystalline and luminescence properties of polycatenar diphenylpyridine complexes of Palladium(II)

20. Reactivity of a Dinuclear PdI Complex [Pd2(μ-PPh2)(μ2-OAc)(PPh3)2] with PPh3: Implications for Cross-Coupling Catalysis Using the Ubiquitous Pd(OAc)2/nPPh3 Catalyst System

21. Synthesis, characterization, electrochemistry, antioxidant, and toxicological studies of Co(II), Ni(II) and Ag(I) complexes of mefenamic acid/tolfenamic acid bearing metronidazole

22. Synthesis of macrocyclic and medium-sized ring thiolactones via the ring expansion of lactams

23. Synthesis, mesomorphism, photophysics and device performance of liquid-crystalline pincer complexes of gold(<scp>iii</scp>)

24. Insights into the Composition and Structural Chemistry of Gallium(I) Triflate

26. Synthesis of medium-ring lactams and macrocyclic peptide mimetics

27. Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex

28. Optimisation of pyruvate hyperpolarisation using SABRE by tuning the active magnetisation transfer catalyst† †Electronic supplementary information (ESI) available. CCDC 1957542–1957543. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9cy02498k

29. Catalytic Activation of Unstrained, Nonactivated Ketones Mediated by Platinum(II): Multiple C–C Bond Cleavage and CO Extrusion

30. Probing the Hydrogenation of Vinyl Sulfoxides Using para-Hydrogen

31. Synthesis of Oxazolidinones by using Carbon Dioxide as a C 1 Building Block and an Aluminium‐Based Catalyst

32. A Dichotomy in Cross-Coupling Site Selectivity in a Dihalogenated Heteroarene: Influence of Mononuclear Pd, Pd Clusters, and Pd Nanoparticles—the Case for Exploiting Pd Catalyst Speciation

33. Synthesis of macrocyclic and medium-sized ring thiolactones

34. Structural analysis of five-coordinate aluminium(salen) complexes and its relationship to their catalytic activity

35. Liquid-crystalline TADF materials based on substituted carbazoles and terephthalonitrile

36. Biocatalytic Aromaticity-Breaking Epoxidation of Naphthalene and Nucleophilic Ring-Opening Reactions

37. Electrocatalytic Proton Reduction by a Cobalt(III) Hydride Complex with Phosphinopyridine PN Ligands

38. Reversible Hyperpolarization of Ketoisocaproate Using Sulfoxide-containing Polarization Transfer Catalysts

39. Metal- and Halide-Free Catalyst for the Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide

40. Ionic N-phenylpyridinium tetracatenar mesogens: competing driving forces in mesophase formation and unprecedented difference in phase stabilisation within a homologous series

41. The ubiquitous cross-coupling catalyst system ‘Pd(OAc)2’/2PPh3 forms a unique dinuclear PdI complex: an important entry point into catalytically competent cyclic Pd3 clusters

42. Using coligands to gain mechanistic insight into iridium complexes hyperpolarized with para-hydrogen

43. The critical role played by water in controlling Pd catalyst speciation in arylcyanation reactions

44. Unprecedented reductive cyclisation of salophen ligands to tetrahydroquinoxalines during metal complex formation

45. Sequential X-ray-Induced Single-Crystal to Single-Crystal Transformation followed by Topotactic Reduction in a Potassium Crown Ether Complex of Tetrachloroaurate(III)

46. Iridium α -Carboxyimine Complexes Hyperpolarized with para -Hydrogen Exist in Nuclear Singlet States before Conversion into Iridium Carbonates

47. Crystallographic evidence of synthesized Ni(II) fluoride complex: Solubilization interaction of fluoride complex in anionic micellar media by conductometric and spectroscopic techniques

48. Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: fluoride ligands vs. other halides

49. 1,2,4-Triazolium ions as flexible scaffolds for the construction of polyphilic ionic liquid crystals

50. Spectroscopic and conductometric study of interaction of anionic surfactants with [Co(phen) 3 ]F 2 ·2H 2 O complex