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1. An Efficient and Convenient Approach for Synthesizing Iodohydrin and Iodoether from Aromatic Alkenes Using Hg(BF4)2.SiO2 and I2.

Author

Hosseinzadeh, Nouraddin, Mousavi, Seyyed Rasul, Ahmadi, Yavar, Batooei, Nasim, Sotoudehnia Korrani, Zahra, and Mahdavi, Mohammad

Subjects
ALKENES, TETRAFLUOROBORATES, MERCURY, ISOBUTANOL, METHANOL, ALCOHOL
Abstract

A new and simple method for synthesizing iodohydrins and iodoethers from aromatic alkenes is described. Iodohydrins and iodoether derivatives were prepared in excellent yield using Mercury(II) tetrafluoroborate (Hg(BF4)2.SiO2)/I2 in aqueous THF or alcohols (methanol, iso-propanol and tert-butanol). The reactions take place at room temperature, short reaction times, and high regioselectivity, following Markovnikov fashion. [ABSTRACT FROM AUTHOR]

Published
2022
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3. An Efficient and Convenient Approach for Synthesizing Iodohydrin and Iodoether from Aromatic Alkenes Using Hg(BF4)2.SiO2 and I2.

Author

Hosseinzadeh, Nouraddin, Mousavi, Seyyed Rasul, Ahmadi, Yavar, Batooei, Nasim, Sotoudehnia Korrani, Zahra, and Mahdavi, Mohammad

Subjects
*ALKENES, *TETRAFLUOROBORATES, *MERCURY, *ISOBUTANOL, *METHANOL, *ALCOHOL
Abstract

A new and simple method for synthesizing iodohydrins and iodoethers from aromatic alkenes is described. Iodohydrins and iodoether derivatives were prepared in excellent yield using Mercury(II) tetrafluoroborate (Hg(BF4)2.SiO2)/I2 in aqueous THF or alcohols (methanol, iso-propanol and tert-butanol). The reactions take place at room temperature, short reaction times, and high regioselectivity, following Markovnikov fashion. [ABSTRACT FROM AUTHOR]

Published
2022
Full Text
View/download PDF

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