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2. Synthesis and catalytic activity of unimolecular dendritic reverse micelles with 'internal' functional groups

Author

Piotti, Marcelo E., Rivera, Felix, Jr., Bond, Risha, Hawker, Craig J., and Frechet, Jean M.J.

Subjects
Micelles -- Research, Organic compounds -- Synthesis, Chemistry
Abstract

The synthesis of unnimolecular reverse micellar dendrimers that combine a unique polar interior with activating functional groups and a nonpolar corona that resembles the reaction solvent is presented. It involves the tetradecyl-substituted benzyl bromide as the terminal unit and the methyl ester functionalized diphenol as the repeat unit. The dendrimers are designed to catalyze reactions that have a nascent positive charge developed during the transition state.

Published
1999

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