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1. Role of secondary structure in the asymmetric acylation reaction catalyzed by peptides based on chiral C(super alpha)-tetrasubstituted alpha-amino acids

Author

Formaggio, Fernando, Kaptein, Bernard, Barazza, Alessandra, Brazola, Elena, Bertocco, Andrea, Pengo, Paolo, Toniolo, Claudio, Pasquato, Lucia, Broxterman, Quirinus B., and Scrimin, Paolo

Subjects
Catalysts -- Usage, Peptides -- Research, Peptides -- Chemical properties, Chemistry, Organic -- Research, Biological sciences, Chemistry
Abstract

A set of analogues and dipeptide amides characterized by chiral C(super alpha)-tetrasubstituted alpha-amino acids of varied bulkiness and optical configurations are examined. Results confirm the close relationship between the beta-hairpin 3D-structure and the catalytic activity of the peptides.

Published
2004

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