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The Indian Point Energy Center (IPEC) supplied approximately 25% of New York City and the surrounding area's electricity. As of April 2021, the nuclear power plant has been shut down, creating the need for other energy sources to meet the demand. This scoping analysis study examined the ability of different renewable pathways (solar photovoltaic (PV), willow biomass, onshore wind, and two combinations of these) to replicate the IPEC's electricity generation profile. Five renewable electricity generation supply profiles were developed and analyzed from monthly and seasonal perspectives. The timing and alignment of the different generation supply profiles relative to that of IPEC were analyzed. Productivity in MWh hectare−1 year−1 and economic feasibility of the renewable electricity pathway scenarios were assessed. This study identified the solar PV pathway as the most efficient in terms of electricity land productivity at 731.9 MWh hectare−1 year−1, while the willow biomass pathway was the least efficient at 15.2 MWh hectare−1 year−1. However, in terms of net electricity output to the grid, the solar PV pathway was the least productive at 137,610 MWh/year, while the onshore wind with willow biomass pathway produced the highest net output at 894,801 MWh/year. These findings are important at a time when policymakers are considering or implementing plans to phase out nuclear power in favor of renewable electricity. [ABSTRACT FROM AUTHOR]

There is a lack of economic feasibility analyses on the harvesting of forest biomass to supply low‐carbon bioenergy feedstocks using actual data on the mixed product harvest in the hardwood region of the northeast USA. This study is a techno‐economic analysis of three different scenarios (clean chips, dirty chips, or pulpwood) based on data collected from whole‐tree harvesting systems over 6 years. Each scenario had two different cases: one with costs and revenues allocated by mass (allocated system), and the other without allocation (whole system). The six cases of three scenarios tested resulted in a wide range of positive net present values (NPVs) from $1 713 000 to $819 in US dollars. Clean chip production generated substantial NPVs and dirty chips generated marginal NPVs. The minimum selling prices (MSPs) of clean chips from two cases were similar, $45.92 and $45.55 per green metric ton (Mg), with maximum hauling distances (MHDs) of 247 and 250 km (km). The MSPs for dirty chips from four cases ranged from $34.38 to $37.47 per Mg with the range of MHDs from 184 to 351 km. MSP and sensitivity analyses suggest that the selling prices and harvesting production levels of clean chips and dirty chips, and purchase prices of forestry logging equipment are the key factors that most influence the profitability of the regional forest biomass feedstock supply chain. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd [ABSTRACT FROM AUTHOR]

Reduction of (4,0)-Ru2(chp)4Cl (1) (chp = 6-chloro-2-oxypyridinate) with Zn or FeCl2 yields a series of axial ligand adducts of the Ru2(II,II) species Ru2(chp)4(L), with L = tetrahydrofuran (2), dimethyl sulfoxide (DMSO; 3), PPh3 (4), pyridine (5), or MeCN (6). Zn reduction in noncoordinating solvents such as toluene or CH2Cl2 leads to the dimeric species [Ru2(chp)4]2 (7) or [Ru2(chp)4]2(ZnCl2) (8), whereas addition of strongly σ-donating ligands such as CO causes cleavage of the Ru-Ru bond. Density functional theory (DFT) models of these complexes, the axially free species, and the axial adducts of several other potential ligands (H2O, NH3, CH2Cl2, S-bound DMSO, N2, and CO) indicate that these compounds can be divided into three distinct categories, based on their Ru-Ru bond length and electronic structure. Compounds 2, 3, 5, 6, 7, and 8, the hypothetical axially free species, and adducts of H2O and NH3 fit in Category 1 with a (δ*)²(π*)² ground state, as indicated by their electronic spectra, magnetic properties, and Ru-Ru bond distances. However, compound 4 and the CH2Cl2 adduct (Category 2) show a pseudo-Jahn-Teller distortion and spectroscopic signs of δ*/π* orbital mixing suggestive of a new electronic ground state intermediate between the (δ*)²(π*)² and (δ*)¹(π*)³ configurations. Category 3 consists of the hypothetical adducts of N2, S-bound DMSO, and CO, all of which are predicted to have a (δ*)¹(π*)³ configuration. Electronic spectra were recorded and assigned using time-dependent DFT, allowing assignment of a band in the 10 000-13 000 cm-1 range as the δ → π* transition. The axial ligand's π-acid character heavily influences the δ*−π* gap, and thereby the ground-state electronic configuration, but not the axial ligand binding strength, which is dictated more by the σ-donor character of the ligands. Thus, this work greatly expands the number of axial ligand adducts known for Ru2(II,II) complexes supported by N,O-donor ligands and provides a predictive theoretical framework for their stability and electronic structures. [ABSTRACT FROM AUTHOR]