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Oil sands are a prominent unconventional source of petroleum. Total organic carbon measurements via an aircraft campaign (Spring-Summer 2018) revealed emissions above Canadian oil sands exceeding reported values by 1900-6300%. The “missing” compounds were predominantly intermediate- and semi-volatile organic compounds, which are prolific precursors to secondary organic aerosol formation. Here we use a novel combination of aircraft-based measurements (including total carbon emissions measurements) and offline analytical instrumentation to characterize the mixtures of organic carbon and their volatility distributions above oil sands facilities. These airborne, real-time observations are supplemented by laboratory experiments identifying substantial, unintended emissions from waste management practices, emphasizing the importance of accurate facility-wide emissions monitoring and total carbon measurements to detect potentially vast missing emissions across sources.Detailed chemical speciation confirms these observations near both surface mining and in-situ facilities were oil sands-derived, with facility-wide emissions around 1% of extracted petroleum—a comparable loss rate to natural gas extraction. Total emissions, spanning extraction through waste processing, were equivalent to total Canadian anthropogenic emissions from all sources. These results demonstrate that the full air quality and environmental impacts of oil sands operations cannot be captured without complete coverage of a wider volatility range of emissions.

Wildfire impacts on air quality and climate are expected to be exacerbated by climate change with the most pronounced impacts in the boreal biome. Despite the large geographic coverage, there is a lack of information on boreal forest wildfire emissions, particularly for organic compounds, which are critical inputs for air quality model predictions of downwind impacts. In this study, airborne measurements of 250 compounds from 15 instruments, including 228 non-methane organics compounds (NMOG), were used to provide the most detailed characterization, to date, of boreal forest wildfire emissions. Highly speciated measurements showed a large diversity of chemical classes highlighting the complexity of emissions. Using measurements of the total NMOG carbon (NMOGT), the ΣNMOG was found to be 46.2 % of NMOGT, of which, the intermediate- and semi-volatile organic compounds (I/SVOCs) were estimated to account for 7.4 %. These estimates of I/SVOC emission factors expand the volatility range of NMOG typically reported. Despite extensive speciation, a substantial portion of NMOGT remained unidentified (46.4 %), with expected contributions from more highly-functionalized VOCs and I/SVOCs. The emission factors derived in this study improve wildfire chemical speciation profiles and are especially relevant for air quality modelling of boreal forest wildfires. These aircraft-derived emission estimates were further linked with those derived from satellite observations demonstrating their combined value in assessing variability in modelled emissions. These results contribute to the verification and improvement of models that are essential for reliable predictions of near-source and downwind pollution resulting from boreal forest wildfires.