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This study evaluated the effect of monovalent and divalent ions and the dosage of a SiO2-based nanocomposite on the thermochemical stability of HPAM polymeric solution. Chelating amine–functionalized NPs (AFNPs) were used to enhance the thermochemical stability of HPAM based on capturing monovalent/divalent ions after seven days at 70°C. Different polymer solutions prepared with calcium chloride dihydrate (CaCl2·2H2O) at 2000 mg/L and sodium chloride (NaCl) at 10000 mg/L, and two different dosages of HPAM (1000 and 2000 mg/L) were assessed in the presence and absence of AFNPs at dosages of 200, 500 and 1000 mg/L. The nanocomposite was characterized by N2 adsorption, Fourier-transformed infrared spectrophotometry (FTIR), thermogravimetric analysis (TGA), dynamic Light Scattering (DLS), and Zeta potential (ZP). Stability tests over time confirmed the positive effect of nanocomposite on increasing the thermochemical stability of polymer solutions. Results revealed that adding 0, 200, and 500 mg/L of nanocomposite to the polymeric solution at 1000 mg/L of HPAM, 10000 mg/L of NaCl, and 2000 mg/L of CaCl2·2H2O led to the viscosity reductions of 73.5%, 18%, and less than 1% after 7 days (70°C), respectively. Nanocomposite at 200 mg/L reduces the polymer degradation in the presence of the two salts evaluated separately, i.e., 20% for 10000 mg/L of NaCl and 15% for 2000 mg/L of CaCl2·2H2O. The adsorption tests on AFNPs and SiO2 NPs concluded that AFNPs had higher adsorption of cations in comparison to SiO2 NPs and that greater adsorption of cations is related to a reduction in polymer degradation.

In this study, the nutraceutical properties of ethanolic extract of Hyeronima macrocarpa fruits, immobilized on nanocellulose-based aerogels (NCAG) synthesized from the seeds were studied. Specifically, bioactives with antioxidant properties of the pulp were determined, NCAG and homologs of acetate (NCAG-A) and sulfate (NCAG-S) were obtained, and characterized from the seed, the aerogels loaded with antioxidants were studied to determine the anti-radical activity, digestion patterns, protein oxidation inhibition, and toxicological properties. The berries presented a high anthocyanin content of 1317.4 mg C3G/100 g FW and ORAC value ​​of 12,732 µmol Trolox/100 g FW, which make an important source of antioxidants. The seeds presented cellulose content of 61.4 % with a NC yield of 38.4 %. NCAG and their surface homologs were successfully synthesized and characterized by FTIR, DLS, and TEM finding the characteristic bands of the main functional groups, NC presented particle sizes ranging from 64 to 141 nm, BET analysis showed surface areas of 71.1, 102.3, and 183.5 m2/g for NCAG-A, NCAG, and NCAG-S, respectively, and pore sizes of 36–38 nm called mesopores. NCAG presented the highest capacity to trap reactive oxygen species (106.8 mg catechin Eq./g., 86.5 % OH• trapped, respectively). All samples showed the capacity to delay the oxidation of a protein system in a dose-dependent manner, with IC50 values ​​of 70 mg/L (NCAG), 176.3 mg/L (NCAG-A), and 255.6 mg/L (NCAG-S). In vitro digestion showed that NCAG-S was more efficient in delivering anthocyanins under gastric conditions (bioaccessibility of 59.3 %), and NCAG under duodenal conditions (bioaccessibility of 88.2 %). The differences found in samples for the different functional assays can be explained by the various types of interactions generated between the antioxidant molecules and aerogels, in the various media where the analyses are carried out. The results indicate nanocellulose-based aerogels, synthesized from lignocellulosic residues of H. macrocarpa seeds, proved to be porous matrices capable of carrying bioactive substances, and presented interesting properties for the delivery and conservation of antioxidant molecules such as anthocyanins and other polyphenols, achieving an in vitro protective effect against the oxidation of biomolecules.

Abstract Among the Enhanced Oil Recovery (EOR) methods, gas-based EOR methods are very popular all over the world. The gas injection has a high ability to increase microscopic sweep efficiency and can increase production efficiency well. However, it should be noted that in addition to all the advantages of these methods, they have disadvantages such as damage due to asphaltene deposition, unfavorable mobility ratio, and reduced efficiency of macroscopic displacement. In this paper, the gas injection process and its challenges were investigated. Then the overcoming methods of these challenges were investigated. To inhibit asphaltene deposition during gas injection, the use of nanoparticles was proposed, which were examined in two categories: liquid-soluble and gas-soluble, and the limitations of each were examined. Various methods were used to overcome the problem of unfavorable mobility ratio and their advantages and disadvantages were discussed. Gas-phase modification has the potential to reduce the challenges and limitations of direct gas injection and significantly increase recovery efficiency. In the first part, the introduction of gas injection and the enhanced oil recovery mechanisms during gas injection were mentioned. In the next part, the challenges of gas injection, which included unfavorable mobility ratio and asphaltene deposition, were investigated. In the third step, gas-phase mobility control methods investigate, emphasizing thickeners, thickening mechanisms, and field applications of mobility control methods. In the last part, to investigate the effect of nanoparticles on asphaltene deposition and reducing the minimum miscible pressure in two main subsets: 1- use of nanoparticles indirectly to prevent asphaltene deposition and reduce surface tension and 2- use of nanoparticles as a direct asphaltene inhibitor and Reduce MMP of the gas phase in crude oil was investigated.

The use of carriers to improve cannabidiol (CBD) bioavailability during digestion is at the forefront of research. The main objective of this research was to evaluate CBD bioactivity and develop CBD composites based on tailored carbon support to improve availability under digestive conditions. The antioxidant capacity of CBD was evaluated using spectrophotometric methods, and anti-proliferative assays were carried out using human colon carcinoma cells (SW480). Twenty-four composites of CBD + carbon supports were developed, and CBD desorption tests were carried out under simulated digestive conditions. The antioxidant capacity of CBD was comparable to and superior to Butylhydrox-ytoluene (BHT), a commercial antioxidant. CBD reflected an IC-50 of 10,000 mg/L against SW480 cancer cells. CBD in biological systems can increase the shelf life of lipid and protein foods by 7 and 470 days, respectively. Finally, acid carbons showed major CBD adsorption related to electrostatic interactions, but basic carbons showed better delivery properties related to electrostatic repulsion. A tailored composite was achieved with a CBD load of 27 mg/g with the capacity to deliver 1.1 mg, 21.8 mg, and 4 mg to the mouth, stomach, and duodenum during 18 h, respectively. This is a pioneering study since the carriers were intelligently developed to improve CBD release.

Abstract Gas injection is one of the most common enhanced oil recovery techniques in oil reservoirs. In this regard, pure gas, such as carbon dioxide (CO2), nitrogen (N2), and methane (CH4) was employed in EOR process. The performance of pure gases in EOR have been investigated numerically, but till now, numerical simulation of injection of rich gases has been scared. As rich gases are more economical and can result in acceptable oil recovery, numerical study of the performance of rich gases in EOR can be an interesting subject. Accordingly, in the present work the performance of rich gases in the gas injection process was investigated. Methane has been riched in liquefied petroleum gas (LPG), natural gas liquid (NGL), and Naphtha. Afterwards, the process of gas injection was simulated and the effect of injection fluids on the relative permeability, saturation profile of gas, and fractional flow of gas was studied. Our results showed that as naphtha is a heavier gas than the two other ones, IFT of oil-rich gas with naphtha is lower than other two systems. Based our results, gas oil ratio (GOR) and injection pressure did not affect the final performance of injection gas that has been riched in NGL and LPG. However, when GOR was 1.25 MSCF/STB, rich gas with naphtha moved with a higher speed in the domain and the relative permeability of each fluid and fractional flow of gas were affected. The same result was achieved at higher injection pressure. When injection pressure was 2000 psi, movement of gas with higher speed in the domain, alteration of relative permeability and changes in the fractional flow of gas were obvious. Therefore, based on our result, injection of naphtha with low pressure and high GOR was suggested for considered oil.

La industria petrolera mundial está llamada hoy en día a realizar operaciones carbono neutrales que permitan reducir la cantidad de emisiones de CO2 actuales. Sin embargo, existen diferentes limitaciones técnico-económicas que impiden avanzar hacia tecnologías de captura, uso y almacenamiento de carbono (CCUS por sus siglas en inglés) con niveles de desarrollo (TRL por sus siglas en inglés) altos que permitan su escalamiento bajo condiciones reales. Es así que la nanotecnología ha tomado un importante protagonismo en los últimos años en el potenciamiento de diferentes procesos CCUS. En ese documento se presenta una perspectiva acerca del rol de la nanotecnología en la descarbonización de la industria petrolera, con énfasis en posibles sinergias con la industria cementera, almacenamiento inteligente de carbono, y procesos de recobro mejorado (EOR) y aumento de productividad con CO2 y/o flue gas.

Scleroglucan (SG) is resistant to harsh reservoir conditions such as high temperature, high shear stresses, and the presence of chemical substances. However, it is susceptible to biological degradation because bacteria use SG as a source of energy and carbon. All degradation effects lead to viscosity loss of the SG solutions, affecting their performance as an enhanced oil recovery (EOR) polymer. Recent studies have shown that nanoparticles (NPs) can mitigate these degradative effects. For this reason, the EOR performance of two new nanohybrids (NH-A and NH-B) based on carboxymethyl-scleroglucan and amino-functionalized silica nanoparticles was studied. The susceptibility of these products to chemical, mechanical, and thermal degradation was evaluated following standard procedures (API RP 63), and the microbial degradation was assessed under reservoir-relevant conditions (1311 ppm and 100 °C) using a bottle test system. The results showed that the chemical reactions for the nanohybrids obtained modified the SG triple helix configuration, impacting its viscosifying power. However, the nanohybrid solutions retained their viscosity during thermal, mechanical, and chemical degradation experiments due to the formation of a tridimensional network between the nanoparticles (NPs) and the SG. Also, NH-A and NH-B solutions exhibited bacterial control because of steric hindrances caused by nanoparticle modifications to SG. This prevents extracellular glucanases from recognizing the site of catalysis, limiting free glucose availability and generating cell death due to substrate depletion. This study provides insights into the performance of these nanohybrids and promotes their application in reservoirs with harsh conditions.

Water is a vital liquid for developing biological, industrial, and social processes. However, by 2020, the availability of drinking water decreased by 20% worldwide, leaving more than 2 billion people without access to high-quality water. Thus, this work was based on freshwater production from air dehumidification using silica-based supported materials in two climate zones in Colombia to deal with this lack of water. The results showed that the material synthesized based on a hygroscopic CaCl2 salt supported on silica (SHS) has a high sorption capacity and efficiency even after ten sorption/desorption cycles. The obtained water isotherms had the same tendency for 20, 30, 40, and 60 °C, showing type II behavior based on the International Union of Pure and Applied Chemistry (IUPAC) classifications from 2015. A sorption capacity of 0.85 g⋅g−1 for a relative humidity of 84% was obtained. Based on the thermodynamic properties of sorption, the process is defined as spontaneous and exothermic. For the field tests, simple equipment was designed for water sorption/capture during the night, while the desorption/condensation process occurs during the day. The exclusive use of solar energy generated productivity above 0.6 g⋅g−1 in the environmental conditions of Santa Fe-Antioquia and the Tatacoa desert in Colombia. The relative humidity was less than 80% during the entire test. The desorption temperature was lower than 40 °C, which shows the high capacity of the SHS to produce water in semi-desert conditions at low temperatures. Thus, this SHS can produce water in challenging environments, generating a positive social impact by providing fresh water to those communities that need it most.

In this study, two new nanohybrids (NH-A and NH-B) were synthesized through carbodiimide-assisted coupling. The reaction was performed between carboxymethyl-scleroglucans (CMS-A and CMS-B) with different degrees of substitution and commercial amino-functionalized silica nanoparticles using 4-(dimethylamino)-pyridine (DMAP) and N,N′-dicyclohexylcarbodiimide (DCC) as catalysts. The morphology and properties of the nanohybrids were investigated by using transmission (TEM) and scanning electron microscopy (SEM), electron-dispersive scanning (EDS), attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FT-IR), X-ray photoelectron spectroscopy (XPS), powder X-ray diffraction (XRD), inductively coupled plasma atomic emission spectroscopy (ICP-OES), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic light scattering (DLS). The nanohybrids exhibited differences in structure due to the incorporation of polyhedral oligomeric silsesquioxane (POSS) materials. The results reveal that hybrid nanomaterials exhibit similar thermal properties but differ in morphology, chemical structure, and crystallinity properties. Finally, a viscosity study was performed on the newly obtained nanohybrid materials; viscosities of nanohybrids increased significantly in comparison to the carboxymethyl-scleroglucans, with a viscosity difference of 7.2% for NH-A and up to 32.6% for NH-B.

Biopolymers emerge as promising candidates for enhanced oil recovery (EOR) applications due to their molecular structures, which exhibit better stability than polyacrylamides under harsh conditions. Nonetheless, biopolymers are susceptible to oxidation and biological degradation. Biopolymers reinforced with nanoparticles could be a potential solution to the issue. The nanofluids’ stability and performance depend on the nanoparticles’ properties and the preparation method. The primary objective of this study was to evaluate the effect of the preparation method and the nanoparticle type (SiO2, Al2O3, and TiO2) on the viscosity and stability of the scleroglucan (SG). The thickening effect of the SG solution was improved by adding all NPs due to the formation of three-dimensional structures between the NPs and the SG chains. The stability test showed that the SG + Al2O3 and SG + TiO2 nanofluids are highly unstable, but the SG + SiO2 nanofluids are highly stable (regardless of the preparation method). According to the ANOVA results, the preparation method and standing time influence the nanofluid viscosity with a statistical significance of 95%. On the contrary, the heating temperature and NP type are insignificant. Finally, the nanofluid with the best performance was 1000 ppm of SG + 100 ppm of SiO2_120 NPs prepared by method II.

Recent research has highlighted wettability alteration as the main consequence of the different mechanisms involved in technologies such as adjusted brine composition water flooding (ABCW) and low-salinity water flooding (LSW). However, studies are still needed to give a phenomenological explanation, and the most influential components of the system (rock–oil–brine) must be clarified. This work focuses on determining the most relevant variables for the smart water effects to occur. Static (contact angles) and dynamic tests (coreflooding) were conducted. For the static tests, aged Berea slices, a specific crude oil (27° API, 10.5 cp at 60 °C), and mono and divalent inorganic salts (Na+, K+, Ca2+, and Mg2+/Cl−) were used in 3 different concentrations of 1000, 3000, and 5000 ppm (ionic strength variation between 0.015 and 0.06) to establish the wettability state by measuring the contact angles of the system. When salts containing chloride were evaluated, a decrease in oil wettability was observed at 5000 ppm. At 3000 and 1000 ppm, tendencies depended on the particular cation. Three brines were selected from the contact angle experiments to be used in coreflooding assays, considering a particular design to identify ion exchange from the rock–oil–brine system. The first assay was carried out in the absence of crude oil as a baseline to determine the ion exchange between the brine and the rock, and a second test considered crude oil to provide insight into ion exchange and its effect on displacement efficiency. Capillary electrophoresis was used in this research as a novel contribution to the systematic study of oil displacement tests, and it has proven to be a powerful tool for understanding the mechanisms involved. The results show that the variations in the concentrations detected in the displacement effluents were the product of the interactions between rock, oil, and brine since the concentrations measured in the absence of oil phase were comparable to those in the injection brine. Significant variations in the effluent ion concentrations were determined for the different brines used, and increases in the pressure differentials were observed for the KCl and CaCl2 brines. These results suggest that the oil–brine ion exchange (salting in/out) represents a relevant mechanism to explain the observed displacement efficiencies and differential pressures. The ionic enrichment of the water phase due to the salting in/out effect needs to be better understood.

The objective of this study is to evaluate the role of nanoparticles with different chemical structures in completion fluids (CF) in providing a positive dual effect for well stimulation and clay swelling damage inhibition. Six types of commercial (C) or synthesized (S) nanoparticles have been incorporated into a commercial completion fluid. Doses varied between 100 and 500 mg·L−1. CF-nanoparticles were evaluated by fluid–fluid, fluid–nanoparticle, and fluid–rock interactions. The adsorption isotherms show different degrees of affinity, which impacts on the reduction of the interfacial tension between the CF and the reservoir fluids. Fluid–fluid interactions based on interfacial tension (IFT) measurements suggest that positively charged nanoparticles exhibit high IFT reductions. Based on contact angle measurements, fluid–rock interactions suggest that ZnO-S, SiO2-C, SiO2-S, and ZrO2 can adequately promote water–wet rock surfaces compared with other nanomaterials. According to the capillary number, ZnO-S and MgO-S have a higher capacity to reduce both interfacial and surface restrictions for crude oil production, suggesting that completion fluid with nanoparticles (NanoCF) can function as a stimulation agent. The clay swelling inhibition test in the presence of ZnO-S-CTAB and MgO-S-CTAB nanoparticles showed a 28.6% decrease in plastic viscosity (PV), indicating a reduction in clay swelling. The results indicate that a high-clay environment can meet the completion fluid’s requirements. They also indicate that the degree of clay swelling inhibition of the nanoparticles depends on their chemical nature and dosage. Finally, displacement tests revealed that CF with nanoparticles increased the oil linear displacement efficiency.

This study investigated the effect of different storage temperatures (35–55 °C) on the bioactive substances and antioxidant properties of Hyeronima macrocarpa berries loaded on nanocellulose. NC was extracted from banana pseudo-stems and presented an interesting surface and porosity properties. The acidified ethanol extract showed better anthocyanin extraction (1317 mg C3G eq./100 g FW) and was used for the preparation of the powdered product, which presented an intense and uniform magenta color, with CIELAB parameters of L* = 59.16, a* = 35.61, and b* = 7.08. The powder exhibited significant stability at storage temperatures of 35 and 45 °C, in which there was no significant loss of anthocyanins or a decrease in antioxidant capacity. In addition, the color was stable for up to 4 months without adding any preservative agent. The anthocyanin-rich extract of H. macrocarpa reached an estimated shelf-life of 315 days (stored at 35 °C), as a result of the impregnation process between the extract and NC, with the ability to protect the bioactives from degradation, due to NC surface properties.

Pollution by dyes and heavy metals is one of the main concerns at the environmental level due to their toxicity and inefficient elimination by traditional water treatment. Orange peel (OP) without any treatment was applied to effectively eliminate methylene blue (MB) and cadmium ions (Cd2+) in mono- and multicomponent systems. Although the single adsorption processes for MB and Cd2+ have been investigated, the effects and mechanisms of interactions among multicomponent systems are still unclear. Batch experiments showed that in monocomponent systems, the maximum adsorption capacities were 0.7824 mmol g−1 for MB and 0.2884 mmol g−1 for Cd2+, while in multicomponent systems (Cd2+ and MB), both contaminants competed for the adsorption sites on OP. Particularly, a synergic effect was observed since the adsorption capacity of Cd2+ increased compared to the monocomponent system. Results of desorption and adsorbent reuse confirmed that the adsorbent presents good regeneration performance. The low cost of this material and its capacity for the individual or simultaneous removal of Cd2+ and MB in aqueous solutions makes it a potential adsorbent for polluted water treatment processes.

This study aims to develop and evaluate fracturing nanofluids from the laboratory to the field trial with the dual purpose of increasing heavy crude oil mobility and reducing formation damage caused by the remaining fracturing fluid (FF). Two fumed silica nanoparticles of different sizes, and alumina nanoparticles were modified on the surface through basic and acidic treatments. The nanoparticles were characterized by transmission electron microscopy, dynamic light scattering, zeta potential and total acidity. The rheological behavior of the linear gel and the heavy crude oil after adding different chemical nature nanoparticles were measured at two concentrations of 100 and 1000 mg/L. Also, the contact angle assessed the alteration of the rock wettability. The nanoparticle with better performance was the raw fumed silica of 7 nm at 1000 mg/L. These were employed to prepare a fracturing nanofluid from a commercial FF. Both fluids were evaluated through their rheological behavior as a function of time at high pressure following the API RP39 test, and spontaneous imbibition tests were carried out to assess the FF’s capacity to modify the wettability of the porous media. It was possible to conclude that the inclusion of 7 nm commercial silica nanoparticles allowed obtaining a reduction of 10 and 20% in the two breakers used in the commercial fracture fluid formulation without altering the rheological properties of the system. Displacement tests were also performed on proppant and rock samples at reservoir conditions of overburden and pore pressures of 3200 and 1200 psi, respectively, while the temperature was set at 77 °C and the flow rate at 0.3 cm3/min. According to the effective oil permeability, a decrease of 31% in the damage was obtained. Based on these results, the fracturing nanofluid was selected and used in the first worldwide field application in a Colombian oil field with a basic sediment and water (BSW%) of 100 and without oil production. After two weeks of the hydraulic fracture operation, crude oil was produced. Finally, one year after this work, crude oil viscosity and BSW% kept showing reductions near 75% and 33%, respectively; and having passed two years, the cumulative incremental oil production is around 120,000 barrels.

The objective of this study is to reduce heavy oil viscosity through the catalytic decomposition of heavy fractions by ultrasound cavitation using metal oxide nanoparticles and water as a hydrogen donor, leading to the reduction of asphaltene content through its conversion into lighter components. NiO nanoparticles were synthesized over a 7 nm silica support using the incipient wetness technique. Emulsified heavy oil (HO) with 40%v/v of water and 13°API was used to evaluate the ultrasound cavitation process over different exposure times and nanoparticle dosages. The viscosity of the emulsified HO before and after ultrasound cavitation was measured with and without nanoparticles. Significant viscosity reduction was obtained, showing best results at 90 minutes of ultrasound exposure time with a nanoparticle dosage of 2000 mg/L, leading to a viscosity reduction at 10 s-1 and 25°C, and an asphaltene content reduction of 44 and 16%, respectively.

This study focuses on evaluating the volumetric hydrogen content in the gaseous mixture released from the steam catalytic gasification of n-C7 asphaltenes and resins II at low temperatures (2, CeO2 functionalized with Ni-Pd, Fe-Pd, and Co-Pd. The catalytic capacity was measured by non-isothermal (from 100 to 600 °C) and isothermal (220 °C) thermogravimetric analyses. The samples show the main decomposition peak between 200 and 230 °C for bi-elemental nanocatalysts and 300 °C for the CeO2 support, leading to reductions up to 50% in comparison with the samples in the absence of nanoparticles. At 220 °C, the conversion of both fractions increases in the order CeO2 < Fe-Pd < Co-Pd < Ni-Pd. Hydrogen release was quantified for the isothermal tests. The hydrogen production agrees with each material’s catalytic activity for decomposing both fractions at the evaluated conditions. CeNi1Pd1 showed the highest performance among the other three samples and led to the highest hydrogen production in the effluent gas with values of ~44 vol%. When the samples were heated at higher temperatures (i.e., 230 °C), H2 production increased up to 55 vol% during catalyzed n-C7 asphaltene and resin conversion, indicating an increase of up to 70% in comparison with the non-catalyzed systems at the same temperature conditions.

This study aims to evaluate the effect of surface acidity of fumed silica nanoparticles in adsorption and subsequent thermal cracking of Colombian asphaltenes. The acidities of the surfaces were established through Temperature Programed Desorption (TPD) experiments. The adsorption equilibrium of asphaltenes was determined using a static batch method, and the data obtained was fitted using the Langmuir model, the Freundlich model and the SLE Model. Asphaltenes catalytic oxidation experiments were conducted, and it was found that this process was surface nature dependent. In all cases, the temperature of asphaltenes oxidation was reduced regarding the virgin asphaltene sample. The effective activation energies were estimated with the iso-conversional OFW method. This energy was found to be related to adsorption affinity and asphaltenes self-association on nanoparticles surface.

Factores que favorecen el fenómeno de auto-combustión del carbón depende principalmente de las propiedades intrínsecas, tales como tamaño de partícula, contenido de humedad, entre otros; el medio en el que se encuentra y cómo se almacena. De acuerdo con esto, el objetivo de este trabajo es evaluar el efecto del glicerol en la inhibición de auto-combustión del carbón como reductor de re-adsorción de agua, mediante la adición de glicerol en diferentes cantidades (4, 8, 18 y 28% en peso). El método de impregnación incipiente se utilizó para adicionar el glicerol a las cantidades deseadas. La caracterización de las muestras se realizó mediante: TGA-DTG, adsorción de nitrógeno a -196 ° C, C-H-N-O, FTIR, y SEM. El TGA de los carbone refleja cambios en las propiedades de combustión de cada muestra. El índice de ignición Di presenta su valor más bajo para la muestra con 8% en peso. El efecto del glicerol en la inhibición de la combustión espontánea del carbón está expuesto en el equilibrio de adsorción; la muestra con 8% en peso de glicerol presenta la mayor reducción de la adsorción de agua en el carbón validando la tecnología propuesta como agente inhibidor del fenómeno de auto-combustión en carbones colombianos.

The primary objective of this study is to develop a novel experimental nanofluid based on surfactant–nanoparticle–brine tuning, subsequently evaluate its performance in the laboratory under reservoir conditions, then upscale the design for a field trial of the nanotechnology-enhanced surfactant injection process. Two different mixtures of commercial anionic surfactants (SA and SB) were characterized by their critical micelle concentration (CMC), density, and Fourier transform infrared (FTIR) spectra. Two types of commercial nanoparticles (CNA and CNB) were utilized, and they were characterized by SBET, FTIR spectra, hydrodynamic mean sizes (dp50), isoelectric points (pHIEP), and functional groups. The evaluation of both surfactant–nanoparticle systems demonstrated that the best performance was obtained with a total dissolved solid (TDS) of 0.75% with the SA surfactant and the CNA nanoparticles. A nanofluid formulation with 100 mg·L−1 of CNA provided suitable interfacial tension (IFT) values between 0.18 and 0.15 mN·m−1 for a surfactant dosage range of 750–1000 mg·L−1. Results obtained from adsorption tests indicated that the surfactant adsorption on the rock would be reduced by at least 40% under static and dynamic conditions due to nanoparticle addition. Moreover, during core flooding tests, it was observed that the recovery factor was increased by 22% for the nanofluid usage in contrast with a 17% increase with only the use of the surfactant. These results are related to the estimated capillary number of 3 × 10−5, 3 × 10−4, and 5 × 10−4 for the brine, the surfactant, and the nanofluid, respectively, as well as to the reduction in the surfactant adsorption on the rock which enhances the efficiency of the process. The field trial application was performed with the same nanofluid formulation in the two different injection patterns of a Colombian oil field and represented the first application worldwide of nanoparticles/nanofluids in enhanced oil recovery (EOR) processes. The cumulative incremental oil production was nearly 30,035 Bbls for both injection patterns by May 19, 2020. The decline rate was estimated through an exponential model to be −0.104 month−1 before the intervention, to −0.016 month−1 after the nanofluid injection. The pilot was designed based on a production increment of 3.5%, which was successfully surpassed with this field test with an increment of 27.3%. This application is the first, worldwide, to demonstrate surfactant flooding assisted by nanotechnology in a chemical enhanced oil recovery (CEOR) process in a low interfacial tension region.

Fines migration is a common problem in the oil and gas industry that causes a decrease in productivity. In this sense, the main objective of this study is to develop nanocomposites based on the interaction of quaternary amine (hexadecyltrimethylammonium bromide—CTAB) and MgO to enhance the capacity of retention of fine particles in the porous medium. MgO nanoparticles were synthesized by the sol–gel method using Mg(NO3)2·6H2O as a precursor. Nanoparticles were characterized by dynamic light scattering (DLS), the point of zero charge (pHpzc), thermogravimetric analysis, and Fourier transform infrared spectroscopy (FT-IR). Different nanoparticle sizes of 11.4, 42.8, and 86.2 nm were obtained, which were used for preparing two system nanofluids. These systems were evaluated in the inhibition of fines migration: in the system I MgO nanoparticles were dispersed in a CTAB-containing aqueous solution, and system II consists of a nanocomposite of CTAB adsorbed onto MgO nanoparticles. The fines retention tests were performed using Ottawa sand 20/40 packed beds and fine particles suspensions at concentrations of 0.2% in a mass fraction in deionized water. Individual and combined effects of nanoparticles and CTAB were evaluated in different treatment dosages. The analysis of the interactions between the CTAB and the MgO nanoparticles was carried out through batch-mode adsorption and desorption tests. The best treatment in the system I was selected according to the fines retention capacity and optimized through a simplex-centroid mixture design for mass fractions from 0.0% to 2.0% of both CTAB and MgO nanoparticles. This statistical analysis shows that the optimal concentration of these components is reached for a mass fraction of 0.73% of MgO nanoparticles and 0.74% in mass fraction of CTAB, where the retention capacity of the porous medium increases from 0.02 to 0.39 mg·L−1. Based on the experimental results, the nanofluids combining both components showed higher retention of fines than the systems treated only with CTAB or with MgO nanoparticles, with efficiencies up to 400% higher in the system I and higher up to 600% in the system II. To evaluate the best performance treatment under reservoir conditions, there were developed core flooding tests at fixed overburden pressure of 34.5 MPa, pore pressure at 6.9 MPa and system temperature at 93 °C. Obtaining critical rate increases in 142.8%, and 144.4% for water and oil flow in the presence of the nanofluid. In this sense, this work offers a new alternative for the injection of nanocomposites as a treatment for the problem of fines migration to optimize the productivity of oil and gas wells.

It is possible to take advantage of shallow reservoirs (2 capture and storage in the post-combustion process. This process is called enhanced carbon capture and storage (e-CCS). In this process, it is necessary to use a nano-modifying agent to improve the chemical-physical properties of geological media, which allows the performance of CO2 selective adsorption to be enhanced. Therefore, this study presents the development and evaluation of carbon sphere molecular nano-sieves (CSMNS) from cane molasses for e-CSS. This is the first report in the scientific literature on CSMNS, due to their size and structure. In this study, sandstone was used as geological media, and was functionalized using a nanofluid, which was composed of CNMNS dispersed in deionized water. Finally, CO2 or N2 streams were used for evaluating the adsorption process at different conditions of pressure and temperature. As the main result, the nanomaterial allowed a natural selectivity towards CO2, and the sandstone enhanced the adsorption capacity by an incremental factor of 730 at reservoir conditions (50 °C and 2.5 MPa) using a nanoparticle mass fraction of 20%. These nanofluids applied to a new concept of carbon capture and storage for shallow reservoirs present a novel landscape for the control of industrial CO2 emissions.

The presence of water in coal presents a technological challenge for its industrial use in energetic processes. Therefore, this study aims to study the temperature effect on the water adsorption onto coals at 21, 30, 40 and 50°C. A Colombian bituminous coal was used as sample. The coal was characterized by nitrogen adsorption at 77 K (SBET), Scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, elemental analysis (C-H-N elemental). The results showed that the water uptake increased as the vapor pressure increased. The Talu and Meunier model [1] was used to fit the adsorption isotherms, and the mean square root error (MSRE%) was lower than 10%. Additionally, the Gibbs free energy was found to have negative values, which corroborates the spontaneous adsorption process.

Shale gas has become a major non-conventional energetical resource. La Luna Formation which is commonly considered as the main petroleum source rock, have also shown to be a major reservoir for shale gas resources. In order to understand the "real" potential of this unit and define exploration strategies, the correlation between compositional and petrophysical patterns. We have analyzed 11 shale samples from La Luna and Conejo Formation in the Middle Magdalena basin and the Eastern Cordillera in order to established its composition, total organic contents, thermal maturity, as well as its total porosity and adsorption capacity. Obtained results suggest that due to its organic content, the presence of quartz and carbonate that these shales have a good quality as a gas reservoir and may have also a moderately good behavior during fracturing.

A study about the use of silica nanoparticles in crude oils from the Castilla field and the effects on stability, drop size and emulsion viscosity was carried out. The interest in the use of this type of nanoparticles is created by the inversion effect that these produce in the W/O emulsion at high water cuts upper than 48%. The emulsion is transformed in W/O/W being the latter the least viscous due to the water is the external phase and it allows to the crude oil slides easily on any surface. In this study, two types of naturally emulsified crude oil with different water cuts and a synthetic emulsion were used. This kind of behavior created by nanoparticles over the emulsion could be an alternative solution to the viscosity, fluidity and mobility problems that affect the extraction and transportation in heavy crude oil.

During enhanced oil recovery (EOR), reservoir heterogeneities and fluids distributions promote preferential flow channels formation. Therefore, different types of gels have been proposed to improve swept efficiency on chemical flooding by plugging high permeability zones. The purpose of this article is to evaluate the effect that nanotechnology has on the inhibition of syneresis and the rheological properties of the Acrylamide Sodium Acrylate Copolymer/Chromium (III) Acetate gel system for conformance applications in mature reservoirs. Thus, a methodology is proposed in four stages: First, (I) nanoparticles synthesis, and characterization, followed by (II) bottle tests to monitor gelation kinetics and syneresis degree at 70 °C, then (III) description of the rheological evaluation on static and dynamic conditions to calculate gelation time and viscoelastic modulus (G’ and G”), and finally (IV) the displacement test with the best gel system in the presence of nanoparticles. Results showed that the best nanoparticle was the chromium oxide (Cr2O3), which represented the lesser syneresis degree and increased gelation time. Syneresis of gel samples in the presence of Cr2O3 at day 30 was under 1% for gels prepared with 4000, 6000, and 8000 mg·L−1 of polymer, and polymer to crosslinker ratio (p/c) of 40:1. Regarding SiO2, MgO, and Al2O3 nanoparticles, results show an improvement of gel strength. However, their thermal stability in terms of syneresis was lower. Displacement test in a triple parallel Slim Tube was able to recover an additional 37% of oil of the total oil present in the sandpacks, confirming the effectivity of the system when 100 mg·L−1 of Cr2O3 nanoparticles are included.

The main objective of this study is to develop a novel dual-purpose material based on carbon xerogel microspheres (CXMs) that permits the delayed release of cannabidiol (CBD) and the removal of aflatoxin. The CXMs were prepared by the sol-gel method and functionalized with phosphoric acid (CXMP) and melamine (CXMN). The support and the modified materials were characterized by scanning electronic microscopy (SEM), N2 adsorption at −196 °C, X-ray photoelectron spectroscopy (XPS), and zeta potential. For the loading of the cannabidiol (CBD) in the porous samples, batch−mode adsorption experiments at 25 °C were performed, varying the concentration of CBD. The desorption kinetics was performed at two conditions for simulating the gastric (pH of 2.1) and intestinal (pH of 7.4) conditions at 37 °C based on in vitro CBD release. Posteriorly, the samples obtained after desorption were used to study aflatoxin removal, which was evaluated through adsorption experiments at pH = 7.4 and 37 °C. The adsorption isotherms of CBD showed a type I(b) behavior, with the adsorbed uptake being higher for the support than for the modified materials with P and N. Meanwhile, the desorption kinetics of CBD at gastric conditions indicated release values lower than 8%, and the remaining amount was desorbed at pH = 7.4 in three hours until reaching 100% based on the in vitro experiments. The results for aflatoxin showed total removal in less than 30 min for all the materials evaluated. This study opens a broader landscape in which to develop dual-purpose materials for the delayed release of CBD, improving its bioavailability and allowing aflatoxin removal in gastric conditions.

The main objective of this study is to evaluate the regenerative effect of functionalized CeO2±δ nanoparticles with a mass fraction of 0.89% of NiO and 1.1% of PdO in adsorption and subsequent decomposition of n-C7 asphaltenes in steam gasification processes. During each regeneration cycle, the adsorption capacity and the catalytic activity of the nanoparticles were evaluated. To estimate the adsorption capacity of the nanoparticles, adsorption kinetics were studied at a fixed concentration of n-C7 asphaltenes of 10 mg·L−1 as well as adsorption isotherms at three different temperatures at 25 °C, 55 °C, and 75 °C. To evaluate the catalytic activity, the loss of mass of the nanoparticles was evaluated by isothermal conversions with a thermogravimetric analyzer at 230 °C, 240 °C, and 250 °C, and at non-isothermal conditions involving a heating from 100 °C to 600 °C at a 20 °C·min−1 heating rate. The asphaltenes showed a high affinity for being adsorbed over the nanoparticles surface, due to the nanoparticles-asphaltene interactions are stronger than those that occur between asphaltene-asphaltene, and this was maintained during nine evaluated regeneration cycles as observed in the Henry’s constant that increased slightly, with changes of 21%, 26% and 31% for 25 °C, 55 °C and 75 °C. Polanyi’s adsorption potential decreases by 2.6% for the same amount adsorbed from the first cycle to the ninth. In addition, the catalytic activity of the nanoparticles did not change significantly, showing that they decompose 100% of the n-C7 asphaltenes in all cycles. However, the small decrease in the adsorption capacity and catalytic activity of the nanoparticles is mainly due to the presence and change in concentration and ratio of certain elements such as oxygen, iron or others at the surface of the nanoparticle as shown by X-ray photoelectron spectroscopy (XPS) analyses. Thermodynamic parameters of adsorption such as Δ H a d s o , Δ S a d s o , and Δ G a d s o and the effective activation energy (Ea) were calculated to compare adsorptive and catalytic performance during each cycle. There is an increase of 9.3% and 2.6% in the case of entropy and enthalpy, respectively, and a decrease of 0.5%, 3.1% and 6.5% for 25 °C, 55 °C and 75 °C respectively for the Gibss free energy from cycle 1 to cycle 9. It was found that these parameters are correlated with the Ce concentration and oxidation state ratios (Ce3+/Ce4+ couple) at the surface.

Production water is the largest byproduct of the oil industry and must be treated before disposal, either by reinjection or shedding processes, with the purpose of eliminating emulsified crude oil and avoiding the operational and toxic problems associated with it. The objective of this work was to immobilize a hydrocarbon-degrading strain on activated carbons, to evaluate the biocomplex’s capacity for catalyzing hydrocarbons from Oil in Brine emulsions (O/W) simulating produced waters. Activated carbons were prepared and their chemical and porous properties were estimated by XPS, pHPZC and SEM, N2 adsorption, and mercury porosimetry. Biomaterials were synthesized and hydrocarbon removal tests were performed. The basic and neutral carbons immobilized Pseudomonas stutzeri by physisorption in the macroporous space and electrostatic interactions (108–109 UFC∙g−1), while acid materials inhibited bacterial growth. Removal of aromatic hydrocarbons was more efficient using materials (60%–93%) and biomaterials (16%–84%) than using free P. stutzeri (1%–47%), and the removal efficiencies of crude oil were 22%, 48% and 37% for P. stutzeri and two biomaterials, respectively. The presence of minor hydrocarbons only when P. stutzeri was present confirmed the biotransformation process.

Una revisión de las ventajas y las limitaciones termodinámicas presentes en el método experimental sorción isostérica (SIM) muestra que el SIM no garantiza una cantidad adsorbida constante. Las isósteras calculadas que consideran comportamiento de gas ideal muestran que en el SIM la masa de gas en el volumen muerto del sistema al incrementar la presión de equilibrio debido a los materiales desorbidos. El SIM es útil y efectivo para obtener datos termodinámicos de alta precisión para la sorción de gases en materiales micro y nanoporosos a bajas presiones y temperaturas. Por el contrario, cuando la presión y la temperatura son altas la desorción no es despreciable, por lo tanto el SIM no es aplicable. Los errores en los cálculos del calor isostérico usando SIM pueden ser reducidos usando procedimientos experimentales tradicionales como las isobaras e isotermas de adsorción para generar las isósteras a altas presiones y temperaturas. Como alternativa, correcciones por presión y temperatura, o un experimento que, después de cada incremento de temperatura permita a la dosis de gas compensar la masa desorbida, garantizaría una cantidad adsorbida constante y, por consiguiente, un comportamiento isostérico mediante medidas directas.

El equilibrio de sorción de agua a diferentes temperaturas (25, 35, 50 y 60°C) en un rango de humedad relativa, de 0.10 a 0.85, se determinó para la uchuva usando un método gravimétrico estático. El calor isostérico y la energía libre de Gibbs se calcularon desde el equilibrio de sorción. Los modelos de GAB, BET, SMITH, el modificado de Halsey, el modificado Chung-Pfost, el modificado de Oswin y el modificado de Henderson fueron probados para ajustar los datos experimentales. El modelo GAB fue el más adecuado para describir las curvas de sorción. Los valores de contenido de humedad de la monocapa para la sorción a diferentes temperaturas fueron calculados usando el modelo BET. El calor isostérico decrece con el incremento en el contenido de humedad, mientras que la energía libre de Gibbs incrementa.O equilíbrio de sorção de água em diferentes temperaturas (25, 35, 35 e 60° C) em uma faixa de umidade relativa, entre 0,10 e 0,85, foi determinada utilizando um método estático gravimétrico. Isostérico de calor e energia livre de Gibbs foram calculados a partir do equilíbrio de sorção. Os modelos de GAB, BET, SMITH, o Halsey modificado, modificado Chung-Pfost na Oswin modificado e Henderson modificado foram testados para ajuste dos dados experimentais. O modelo GAB é o mais adequado para descrever as curvas de adsorção. Os valores de umidade para a adsorção em monocamada em diferentes temperaturas foram calculadas utilizando o modelo de BET. calor isostérico diminui com o aumento da umidade, enquanto o aumento da energia livre de Gibbs.The equilibrium sorption of water at different temperatures (25, 35, 50 and 60°C) at a relative humidity range, from 0.10 to 0.85, was determined using a static gravimetric method. Isosteric heat and Gibbs free energy were calculated from the sorption equilibrium. The models of GAB, BET, SMITH, the modified Hasley, modified Chung-Pfost on the modified Oswin and Henderson was tested to fit the experimental data. The GAB model is most appropriate to describe the sorption curves. The moisture content values for the monolayer adsorption at different temperatures were calculated using the BET model. Isosteric heat decreases with increasing moisture energy increases.

El principal objetivo del estudio fue obtener la cinética y el equilibrio termodinámico de la sorcion de asfaltenos en polvo de roca obtenida de la formación Guadalupe (lavada y sin lavar), a diferentes tiempos, temperaturas y concentraciones. Sin embargo, el efecto de temperatura en el equilibrio de sorción no era significativo. Los polvos de roca fueron caracterizados por sorción de N2 a -196°C. El equilibrio de sorcion de los asfaltenos en los polvos de roca, dentro de un rango de concentraciones desde 250 hasta 1500 ppm, fue determinado usando un método estático. Las curvas de sorcion muestran un comportamiento Tipo I, según la IUPAC. El modelo de Langmuir se usó para calcular los valores del contenido de asfaltenos monocapa para la sorcion a diferentes temperaturas, mostrando un buen ajuste con respecto a los datos experimentales. La cinética de sorcion de los asfaltenos en muestras de rocas es función de la concentración y para concentraciones de 1500 ppm el equilibrio es alcanzado alrededor de 90 min. Se aplicaron los modelos cinéticos de pseudo primer orden y pseudo segundo orden a los datos experimentales para las diferentes concentraciones para las dos muestras de rocas con un mejor resultado para el modelo cinético de pseudo-primer orden. El efecto de lavado en el equilibrio no fue significativo, sin embargo la capacidad adsortiva de la roca sin lavar fue ligeramente mayor que la roca lavada con n-heptano y tolueno.

The main objective of this work is the catalyst optimization of Fe2O3-, Co3O4-, NiO- and/or PdO- (transition element oxides—TEO) functionalized CeO2 nanoparticles to maximize the conversion of asphaltenes under isothermal conditions at low temperatures ( CePd2 > CeNi0.66Pd0.66 > CeNi2 > CePd1 > CeNi1 > CeO2. It is worth mentioning that bi-elemental nanoparticles reduced the gasification temperature of asphaltenes in a larger degree than mono-elemental nanoparticles at a fixed amount of adsorbed asphaltenes of 0.02 mg·m−2, confirming the synergistic effects between Pd and Fe, Co, and Ni. Further, optimized nanoparticles (CeNi0.89Pd1.1) have the best performance by obtaining 100% asphaltenes conversion in less than 90 min at 220 °C while reducing 80% the activation energy.

The primary objective of this study is the development of nanofluids based on different diluent/dispersant ratios (DDR) for extra-heavy oil (EHO) viscosity reduction and its perdurability over time. Different diluents such as xylene, diesel, n-pentane, and n-heptane were evaluated for the formulation of the carrier fluid. Instability of asphaltenes was assessed for all diluents through colloidal instability index (CII) and Oliensis tests. Rheology measurements and hysteresis loop tests were performed using a rotational rheometer at 30 °C. The CII values for the alkanes type diluents were around 0.57, results that were corroborated with the Oliensis tests as asphaltenes precipitation was observed with the use of these diluents. This data was related to the viscosity reduction degree (VRD) reported for the different diluents. With the use of the alkanes, the VRD does not surpass the 60%, while with the use of xylene a VRD of approximately 85% was achieved. Dimethylformamide was used as a dispersant of the nanoparticles and had a similar VRD than that for xylene (87%). Subsequent experiments were performed varying the DDR (xylene/dimethylformamide) for different dosages up to 7 vol % determining that a DDR = 0.2 and a dosage of 5 vol % was appropriated for enhancing EHO VRD, obtaining a final value of 89%. Different SiO2 nanoparticles were evaluated in the viscosity reduction tests reporting the best results using 9 nm nanoparticles that were then included at 1000 mg·L−1 in the carrier fluid, increasing the VRD up to 4% and enhancing the perdurability based on the rheological hysteresis and the viscosity measurements for 30 days. Results showed a viscosity increase of 20 and 80% for the crude oil with the nanofluid and the carrier fluid after 30 days, respectively. The nanoparticles have a synergistic effect in the viscosity reduction and the inhibition of the viscoelastic network re-organization (perdurability) after treatment application which was also observed in the rheological modeling carried out with Cross and Carreau models as the reported characteristic relaxation time was increased almost a 20%. Moreover, the Vipulanandan rheological model denotes a higher maximum stress value reached by the EHO with the addition of nanofluids which is derived from the EHO internal structure rearrangement caused by the asphaltenes adsorption phenomenon.

The primary objective of this study is the synthesis of nanocapsules (NC) that allow the reduction of the adsorption process of surfactant over the porous media in enhanced oil recovery processes. Nanocapsules were synthesized through the nanoprecipitation method by encapsulating commercial surfactants Span 20 and Petro 50, and using type II resins isolated from vacuum residue as a shell. The NC were characterized using dynamic light scattering, transmission electron microscopy, Fourier transform infrared, solvency tests, softening point measurements and entrapment efficiency. The obtained NC showed spherical geometry with sizes of 71 and 120 nm for encapsulated Span 20 (NCS20), and Petro 50 surfactant (NCP50), respectively. Also, the NCS20 is composed of 90% of surfactant and 10% of type II resins, while the NCP50 material is 94% of surfactant and 6% of the shell. Nanofluids of nanocapsules dispersed in deionized water were prepared for evaluating the nanofluid—sandstone interaction from adsorption phenomena using a batch-mode method, contact angle measurements, and FTIR analysis. The results showed that NC adsorption was null at the different conditions of temperatures evaluated of 25, 50, and 70 °C, and stirring velocities up to 10,000 rpm. IFT measurements showed a reduction from 18 to 1.62 and 0.15 mN/m for the nanofluids with 10 mg/L of NCS20, and NCP50 materials, respectively. Displacements tests were conducted using a 20 °API crude oil in a quarter five-spot pattern micromodel and showed an additional oil recovery of 23% in comparison with that of waterflooding, with fewer pore volumes injected than when using a dissolved surfactant.

Este trabajo presenta la viabilidad de los sistemas de refrigeración solar por absorción usando soluciones de monometilamina - agua (MMA-A) para aplicaciones en conservación de alimentos en las regiones rurales de Colombia, sin acceso a la red de energía eléctrica. Para suplirlos requerimientos de energía térmica se propone un sistema de calentamiento de agua con energía solar usando colectores de placa y un sistema de respaldo convencional. En este trabajo se determinó el coeficiente de operación (COP) del sistema de refrigeración solar por absorción de una sola etapa en función de la temperatura en los diferentes componentes del ciclo. Los resultados indican que el sistema podría mejorarse mediante un mejor diseño en el intercambiador de calor de solución, el evaporador y el rectificador. Los resultados teóricos demuestran que el uso de la solución de MMA-A puede ser usada en sistemas de refrigeración por absorción operados con energía térmica de baja calidad, tales como la energía solar.Este trabalho apresenta a viabilidade e aplicabilidade dos sistemas de refrigeração solar por absorção usando como parelha a monometilamina - agua (MMA-W) para fins de conservação de alimentos ñas regiões rurais da Colômbia, onde não há energía disponível. Propõese um sistema de calefação solar mediante coletores solares de placa plana com um sistema convencional de aquecimento auxiliar para suprir as necessidades energéticas do refrigerador por absorção. Determinou-se o coeficiente de desempenho (COP) do sistema de refrigeração solar por absorção só de uma etapa em funçã da temperatura nos diferentes componentes do ciclo. Os resultados indicam que o sistema poderia se melhorar mediante um desenho melhorno intercambiador de calor de solução, o evaporador e o retificador os resultados teóricos demonstram que o uso da solução de MMA-W pode ser usada em sistemas de refrigeração como parelha absortiva operado pela energía térmica de baixa qualidade, como a energía solar.This work reports the applicability of monomethylamine-water solutions in a solar absorption refrigerator for food conservation purposes in the rural regions of Colombia , where no electricity is available. A solar heating system using fíat píate solar collectors with a conventional auxiliary heating system is proposed. We have determined the COP of the solar single-stage absorption refrigerator as a function of the temperature in the different components of the cycle. The results indícate the system might be improved by better design on the solution heat exchanger, the evaporator and the rectifier. The theoretical results prove that the use of MMA-W solution can be driven bylow-grade thermal energy such as solar energy.

The present work proposes for the first time a mathematical model for describing the rheological behavior of heavy and extra-heavy crude oils in the presence of nanoparticles. This model results from the combination of two existing mathematical models. The first one applies to the rheology of pseudoplastic substances, i.e., the Herschel-Bulkley model. The second one was previously developed by our research group to model the rheology of suspensions, namely the modified Pal and Rhodes model. The proposed model is applied to heavy and extra heavy crude oils in the presence of nanoparticles, considering the effects of nanoparticles concentration and surface chemical nature, temperature, and crude oil type. All the experimental data evaluated exhibited compelling goodness of fitting, and the physical parameters in the model follow correlate well with variations in viscosity. The new model is dependent of share rate and opens new possibilities for phenomenologically understanding viscosity reduction in heavy crude by adding solid nanoparticles and favoring the scale-up in enhanced oil recovery (EOR) and/or improved oil recovery (IOR) process.

Discharging water from oilfields has become one of the major environmental issues related to the oil industry. This work presents a study on the adsorption of oil onto nanoparticles of hydrophobic silica and silica nanoparticles functionalized with a petroleum vacuum residue (VR) at 2 and 4 wt% to reduce the amount of oil in oil–brine and oil–water emulsions at different pH values (5, 7 and 9). The initial concentration of crude oil in water ranged from 500 to 1500 mg/l. The change in oil concentration after adsorption was determined using a UV–VIS spectrophotometer. Experimental data on the adsorption kinetics were fitted to pseudo-first-order and pseudo-second-order models, with better results being obtained for the latter. Results of the study showed 100% oil removal for all the systems studied and a better performance was achieved for oil-saltwater emulsions than the experiments performed using oil-saltwater emulsions. In addition, the adsorption equilibrium was achieved faster for the oil–water emulsion using the salty medium. Adsorption velocity was higher for neutral and basic systems compared with acid ones, and it was improved by increasing the amount of VR on silica surface.

The aim of this article was to carry out a study of the life cycles of three products of Colombian companies; based on a logistic model of population growth as a life cycles measurement tool. We found that the products life cycles have a similar behavior to the population growth, according to an S curve. The inflection points of the curves were obtained by a nonlinear regression. These points might be used as a tool for strategic decision making in products, in terms of identifying key instants for launching technological innovations, investments and execute marketing strategies.

Abstract In this work, a study of the adsorption/desorption of n-C7 asphaltenes at low and high concentrations (100 - 30000 mg/L) was performed for which the effects of adsorbent particle size (nano and microsilica), pressure, solvent, and temperature were evaluated. Adsorption/desorption tests on different silica surfaces were performed in batch-mode using UV-vis spectrophotometry and thermogravimetric analyses. Owing to its high surface area and dispersibility, nanosilica adsorbed higher quantities of n-C7 asphaltenes than microsilica. Asphaltene desorption from nanosilica surface was significant, while the desorption from microsilica surfaces was insignificant, suggesting a higher adsorption potential for the latter. Asphaltene adsorption increased with pressure and decreased with temperature. Type of solvent plays a significant role on the asphaltene desorption. The wettability tests for virgin nanosilica and nanosilica contained adsorbed asphaltenes showed that even at high asphaltene loading, the nanoparticles maintained its water-wet nature.