1. On-surface synthesis of metal–organic frameworks: the critical role of the reaction conditions
- Author
-
Comunidad de Madrid, Ministerio de Ciencia e Innovación (España), Ministerio de Economía y Competitividad (España), Agencia Estatal de Investigación (España), Consejo Superior de Investigaciones Científicas (España), Sánchez-Sánchez, Carlos [0000-0001-8644-3766], Martínez, José I. [0000-0002-2086-8603], Serrate Donoso, David [0000-0002-3260-9641], Vedini, Alberto [0000-0001-8880-2080], Jacobson, Peter [0000-0002-5363-3763], Grill, Leonhard [0000-0002-9247-6502], Martín-Gago, José A. [0000-0003-2663-491X], López, María Francisca [0000-0001-7894-566X], Ruiz del Árbol, Nerea, Sánchez-Sánchez, Carlos, Martínez, José I., Rodríguez, Luis, Serrate Donoso, David, Verdini, Alberto, Floreano, Luca, Jacobson, Peter, Grill, Leonhard, Martín-Gago, José A., López, María Francisca, Comunidad de Madrid, Ministerio de Ciencia e Innovación (España), Ministerio de Economía y Competitividad (España), Agencia Estatal de Investigación (España), Consejo Superior de Investigaciones Científicas (España), Sánchez-Sánchez, Carlos [0000-0001-8644-3766], Martínez, José I. [0000-0002-2086-8603], Serrate Donoso, David [0000-0002-3260-9641], Vedini, Alberto [0000-0001-8880-2080], Jacobson, Peter [0000-0002-5363-3763], Grill, Leonhard [0000-0002-9247-6502], Martín-Gago, José A. [0000-0003-2663-491X], López, María Francisca [0000-0001-7894-566X], Ruiz del Árbol, Nerea, Sánchez-Sánchez, Carlos, Martínez, José I., Rodríguez, Luis, Serrate Donoso, David, Verdini, Alberto, Floreano, Luca, Jacobson, Peter, Grill, Leonhard, Martín-Gago, José A., and López, María Francisca
- Abstract
[EN] Two different metal–organic frameworks with either a honeycomb or Kagome structure were grown on Cu(111) using para-aminophenol molecules and native surface adatoms. Although both frameworks are made up from the same chemical species, they are structurally differ- ent emphasizing the critical role being played by the reaction condi- tions during their growth. This work highlights the importance of the balance between thermodynamics and kinetics in the final structure of surface-supported metal–organic networks.
- Published
- 2023