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Polyethylene is the single largest volume polymer produced globally using Ziegler-type catalysts. Numerous modifications have been reported in search of a better catalyst that can control molecular weight, polydispersity, and branching. In our attempts to identify a suitable imine thiophene-ligated chromium complex, we examined 9 different titanium complexes computationally. The DFT investigations considered barriers for insertion, propagation, and termination by β-H elimination or chain transfer, and identified N-(4-methoxyphenyl)-2-phenyl-1-(thiophen-2-yl)ethan-1-imine(L9) as the most suitable ligand. Subsequently, L9 was prepared in good yield (70%) by condensing 2-phenyl-1-(thiophen-2-yl)ethan-1-one with 4-methoxyaniline. Ligand L9 was treated with early transition metal precursors (Ti, Cr, Zr) to generate a homogenous catalyst. The identity of these catalysts was unambiguously ascertained using a combination of NMR, ICP, FT-IR, UV-Vis spectroscopy, and ESI-MS. The performance of L9-ligated titanium complex [Cat.1] was examined in ethylene polymerization using MMAO as a co-catalyst. Insertion of ethylene was tracked using high-pressure NMR experiments and Cat.1 was found to be active in the polymerization. Ethylene polymerization conditions were optimized to obtain high activity and molecular weight polyethylene. The chromium complex [Cat.2] outperformed the Ti and Zr-derived catalysts with the highest TOF of 6294 mol of PE/mol of Cr/h. Cat.2 produced high molecular weight, high-density polyethylene. SYNOPSIS TOC: Rational designing and synthesis of imine thiophene-ligated Ti, Cr, and Zr-complexes and their performance in ethylene polymerization is presented. [ABSTRACT FROM AUTHOR]

The European Union (EU) regulations mandate 10% of all food packaging to be reusable by 2030. United States (U.S.) exporters of specialty crops face new challenges in ensuring microbiological food safety using reusable packaging. A novel antimicrobial formulation consisting of ammonium carboxylate salt of capric acid and L-arginine (GS-2) was recently developed as a spray coating chemical for food packaging materials. In this study, we evaluated the antimicrobial efficacy of GS-2 against microbial strains representing three foodborne bacterial pathogens (Escherichia coli O157:H7, Listeria monocytogenes, Salmonella enterica), one fungal spoilage organism (Aspergillus niger), and one surrogate viral pathogen (murine norovirus) on three reusable plastic materials (acrylonitrile butadiene styrene, high-density polyethylene, and polypropylene) and one cardboard packaging material, respectively. Different chemical concentrations, exposure times, and storage conditions were individually evaluated for the relative antimicrobial efficacies of GS-2 against these microorganisms. Our results showed that GS-2 was highly effective for inactivating bacterial pathogens on both plastic and cardboard surfaces. For instance, 3% GS-2 achieved a >5 log CFU/in2 reduction in E. coli O157:H7, L. monocytogenes, and S. enterica on tested plastic surfaces at an exposure time of 60 min. However, its efficacy against A. niger and murine norovirus was less optimal, resulting in a ≤1 log CFU/in2 reduction on all tested surfaces. Based on our study, GS-2 demonstrated a strong potential as an antibacterial coating reagent for reusable food packaging materials to minimize pathogen contamination and ensure the safety of the specialty crops. [ABSTRACT FROM AUTHOR]

High‐density polyethylene (HDPE) nanocomposites containing different optimized fractions of carbon nanofiber (CNF) at 6 wt.%, polyethylene glycol (PEG) at 4 wt.%, and copper oxide (CuO) nanorods in concentration ranges of 0.15, 0.5, and 2 wt.% were successfully melt processed using corotating twin extrusion and compression molding technique. The effect of PEG and CuO nanofiller on the HDPE matrix were studied, particularly for the percolation threshold for electrical conductivity, structural morphology, and other properties including thermal stability, thermal conductivity (TC), dielectric, and UV protection properties. It is observed that PEG acts as a good compatibilizer, facilitating better interfacial connection between CNF and HDPE matrix. The optimized composite with 0.15 wt.% CuO nanorods (H/C6/P4/Cu0.15) shows a fine morphology and strong interfacial connections between fillers and the matrix, as observed in FE‐SEM micrographs. This optimized composite exhibits improved thermal stability, higher thermal conductivity (0.0404 W.K−1.m−1), increased dielectric constant, reduced electrical volume resistivity (from 2.1 × 1015 to 2.1 × 106 Ω.cm), and lower optical band gap value (2.74 eV). Additionally, all prepared nanocomposites offer approximately 100% Ultraviolet Protection Factor (UPF) rating for UV protection. Highlights: The transformation of insulating HDPE into conducting HDPE composites.The effect of CuO nanorods was investigated in compatibilized HDPE composites.A percolation is achieved in the HDPE composite at 0.15 wt.% of CuO nanorods.PEG and CuO nanorods improved the multifunctional properties of the composite. [ABSTRACT FROM AUTHOR]

The widespread use of low-density polyethylene (LDPE) and high-density polyethylene (HDPE) plastics has resulted in a large amount of waste plastic that requires appropriate disposal or reuse. One potential solution is to use them in the modification of asphalt concrete (AC) mixtures for more sustainable highways. To study this possibility, permanent deformation and dynamic modulus (DM) of the LDPE and HDPE modified AC mixtures was investigated by conducting flow number (FN), flow time (FT) and DM tests on Superpave gyratory compacted specimens. Machine learning models; multi-layer perceptron (MLP), radial basis function neural network (RBFNN), generalized regression neural network (GRNN) and support vector machine (SVM) were used to predict the DM on the basis of frequency and temperature parameters. The model's performance was gauged by analyzing the root mean square error, mean relative error, and coefficient of determination. The study findings revealed that the LDPE and HDPE modified AC mixtures provide 2.07 times and 1.27 times better resistance to permanent deformation, respectively, than their counterpart. It was also found that the LDPE and HDPE modified AC mixtures have 2.1 times and 1.4 times higher DM values, respectively, than the Control AC mixtures. Among the machine learning models, MLP (R2 = 0.98) showed best accuracy in predicting DM and thus is recommended to be used in similar studies due to its robustness. Additionally, the feature importance analysis revealed that frequency has the highest impact on DM predictions, followed by temperature and the inclusion of the LDPE. [ABSTRACT FROM AUTHOR]

Bio‐based polymers may present a sustainable, circular way to reduce the environmental impact of plastics because they are produced from biomass that absorbs CO2 during its growth. However, sourcing (type of biomass used and cultivation location), production, and end‐of‐life affect the environmental impact of bio‐based plastics. We assessed the effect of sourcing and end‐of‐life options on the environmental impact of bio‐based high‐density polyethylene (bio‐HDPE) in 31 sourcing scenarios and five end‐of‐life options. Our study found that careful consideration of biomass sourcing (biomass type and production location) and end‐of‐life is needed to optimize the environmental impact of bio‐based plastics. If these aspects are not considered, the environmental impact of bio‐HDPE may exceed that of its petrochemical‐based counterpart. The direct availability of fermentable sugars indicated a lower environmental impact. The production location affected the resources needed for biomass cultivation and the environmental impact of processing due to the energy mix. Recently published guidelines do not allow biogenic carbon to be accounted for during the production stage, but only upon the incineration of the plastic. Our results show that this way of attributing biogenic carbon results in an apparent disadvantage for bio‐based plastics compared to petrochemical‐based plastics. Furthermore, it disadvantaged mechanical recycling of bio‐based plastics compared to incineration, a result out of line with circular economy principles. [ABSTRACT FROM AUTHOR]

It has been known that plastics with undegradability and long half‐times have caused serious environmental and ecological issues. Considering the devastating effects, the development of efficient plastic upcycling technologies with low energy consumption is absolutely imperative. Catalytic hydrogenolysis of single‐use polyethylene over Ru‐based catalysts to produce high‐quality liquid fuel has been one of the current top priority strategies, but it is restricted by some tough challenges, such as the tendency towards methanation resulting from terminal C−C cleavage. Herein, we introduced Ru nanoparticles supported on hollow ZSM‐5 zeolite (Ru/H‐ZSM‐5) for hydrocracking of high‐density polyethylene (HDPE) under mild reaction conditions. The implication of experimental results is that the 1Ru/H‐ZSM‐5 (~1 wt % Ru) acted as an effective and reusable bifunctional catalyst providing higher conversion rate (82.53 %) and liquid fuel (C5−C21) yield (62.87 %). Detailed characterization demonstrated that the optimal performance in hydrocracking of PE could be attributed to the moderate acidity and appropriate positively charged Ru species resulting from the metal‐zeolite interaction. This work proposes a promising catalyst for plastic upcycling and reveals its structure‐performance relationship, which has guiding significance for catalyst design to improve the yield of high‐value liquid fuels. [ABSTRACT FROM AUTHOR]

The waste of polymeric materials in our society is increasing year after year, generating a serious pollution problem. One way to deal with this waste problem is to recycle and reuse these materials. This process of recovery of used plastic materials aims to minimise their impact on the environment and reduce the energy consumption required for the generation of new consumer products. Recycling companies that recover these plastic materials must take into account some aspects such as transparency and colour, cleanliness, size, odour and sorting. One of the major disadvantages in accepting these recycled materials in the production processes is their odour, which in some cases causes the rejection of materials with comparable mechanical characteristics. High-density polyethylene, HDPE, is one of the polymeric wastes generated in the packaging industry. The aim of this work is to eliminate the bad odour of HDPE from waste collection plants for application in the recovery and reuse industry. HDPE supplied by a recycling company was washed, characterised and processed, and the odour was analysed by gas chromatography at each stage and by olfactory panel. In view of the results, it was observed that the washing processes managed to reduce the odour. Likewise, the processing of this waste by extrusion and injection managed to further reduce this effect, even eliminating some of the components responsible for odour by treating the samples with acetone and then extruding and injecting these samples. These results have a direct application in the packaging industry with significant shares of recycled material. [ABSTRACT FROM AUTHOR]

In this study, a small‐sized shredder machine equipped with spiral oriented double‐edged rotating and fixed blades was utilized to shred high‐density polyethylene (HDPE) waste. The performance of the shredder machine was determined based on the recycling and shredding efficiency, the percentage of retention, and the wear of its rotating and fixed blades. The wear of the blades was examined using an optical microscope, a scanning electron microscope, an energy dispersive x‐ray, and an x‐ray diffraction. High recycling (~95 %–98 %) and shredding (~66 %–70 %) efficiency, and low percentage of retention (~1.2 %–4.1 %) indicated a reliable performance of the shredder machine. The rotating blade exhibited higher wear at the back end, compared to the front end for the fixed blade. The wear of the blades was due to scratching and edge chipping. Formation of iron oxides during shredding did not cause significant changes in the hardness of the blades. Based on the evaluation, cost‐effective and time saving maintenance of the shredder blades could be achieved by gradual maintenance starting from the blade exhibited high wear. [ABSTRACT FROM AUTHOR]

To manufacture, feature and analyze the potential of materials to be used as raw material for drug delivery systems for the treatment of overactive bladder. Four distinct mixtures of oxybutynin and polymers ethylene vinyl acetate (EVA) and high-density polyethylene (PE) were prepared via compression molding and hot melt extrusion. The materials were characterized regarding their physicochemical and mechanical properties as well as drug release potential. Promising results were obtained in which the release of oxybutynin was observed for more than 250 days from both EVA and HDPE matrices. The obtained data demonstrate it is possible to manufacture HDPE- and EVA-based samples with the incorporation of oxybutynin, and the EVA samples presented an adequate release profile. The results are promising for the development of an intravesical device with drug delivery, especially because super dose risk is extinguished when considering the release from a monolithic release system. [ABSTRACT FROM AUTHOR]

The recent emphasis on nanocomposites composed of polymers and metal oxides is largely due to their significant promise as effective radiation sensors, detectors, and dosimeters for gamma rays, X-rays, and charged particles. The sensitivity of a system may be affected by various factors, including the volume of the sensitive material, the concentration of heavy metal oxide nanoparticles, the bias voltage applied, and the degree of crystallinity within the polymer matrix. Studies have shown that a pronounced degree of crystallinity in polymers can restrict the homogeneous spread of nanoparticles. This research utilized two distinct polymer matrices, namely HDPE and PC, to create a nanocomposite that incorporated bismuth oxide nanoparticles at concentrations reaching 60 wt%. FESEM images revealed that PC exhibited better dispersion up to 60 wt%, while HDPE showed agglomeration at 40 wt%. Under a defined dose rate of 42.67 mGy.min-1, and with a fixed amount of Bi2O3 nanofillers, the dosimetry response (measured as a change in electrical current) of PC was twice as pronounced compared to HDPE. Therefore, PC, as an amorphous polymer containing 50 wt% Bi2O3, may be considered a suitable candidate for dosimetry applications. [ABSTRACT FROM AUTHOR]

High-density polyethylene (HDPE)/Fe3O4 composites with Fe3O4 nanofiller contents of ω = 1, 3, and 5 vol % have been obtained by hot pressing of a homogeneous mixture of HDPE and a synthesized Fe3O4 nanopowder. The structure and thermal properties of the HDPE/Fe3O4 nanocomposites have been studied; it has been found that, with an increase in the Fe3O4 nanoparticle concentration in the polymer matrix, the morphology of the supramolecular structure of the HDPE matrix drastically changes. It has been established that, with an increase in the nanofiller concentration, the mobility of macromolecular chains in the matrix and the crystalline lamellae thickness decrease. Nanoparticles disrupt the regularity of lamellae in the crystalline phase of the polymer matrix and prevent the formation and growth of new crystalline domains in the amorphous region. [ABSTRACT FROM AUTHOR]

Heptene‐graphitic nanoplatelets (HtGNP) serve as a filler for high density polyethylene (HDPE), generated through a mechanochemical reaction involving graphite and 1‐heptene. Various analyses indicate the efficient exfoliation of graphite into HtGNP, characterized by exceptional traits. Consequently, HtGNP & HDPE_5 nanocomposites, produced via the solution process, exhibit significantly increased tensile strength and Young's modulus, boasting corresponding increases of 27.7% and 13.7% compared to pure HDPE. Thus, owing to their outstanding performance, HtGNP emerges as a promising option in the form of a novel reinforcing additive for various hydrocarbon polymers. [ABSTRACT FROM AUTHOR]

This study examines the impact of Pineapple Leaf Fiber (PALF) loading on the properties of High-Density Polyethylene (HDPE)/PALF composites successfully produced through a melt extrusion process. The melt-extruded HDPE/PALF composites were characterized by their thermal and mechanical properties and their morphologies. Subsequently, adding 5% maleic anhydride (MA) to the HDPE/PALF composite formulation led to significant improvements in the mechanical strength properties. Moreover, adding 10 wt.% PALF and 5% MA to the composites improves the crystallinity (10.38%) and Young's modulus (17.30%) properties and affects the thermal stability. The optimal formulation is achieved with 10 wt.% PALF filler incorporated into the HDPE composite. This study highlights the promising potential of HDPE/PALF composites for plastic product applications. [ABSTRACT FROM AUTHOR]

We investigate the aging behavior of High-Density Polyethylene (HDPE) pipelines, specifically comparing the Pipe Body (PB) and Butt-Fusion Welded Joint (BFWJ) under thermal oxidative and hydrothermal accelerated aging conditions. Our results indicate that the performance disparity between PB and BFWJ diminishes as aging time increases. We also find that the specimen type affects the quantity of polyethylene fibers, with hydrothermal aging significantly affecting the cohesive force among these fibers in both PB and BFWJ. These findings on differential aging processes of PB and BFWJ contribute to a deeper understanding of HDPE pipeline durability and offer practical recommendations for mitigating degradation risks associated with these disparities. This research underscores the importance of considering specific aging behaviors in the maintenance and reliability assessment of HDPE pipeline systems used in energy transport, industrial, and agricultural applications. [ABSTRACT FROM AUTHOR]

High-density polyethylene (HDPE) pipes have gradually become the first choice for gas networks because of their excellent characteristics. As the use of pipes increases, there will unavoidably be a significant amount of waste generated when the pipes cease their operation life, which, if improperly handled, might result in major environmental contamination issues. In this study, the thermal degradation of polyethylene materials is simulated for different pressures (10, 50, 100, and 150 MPa) and temperatures (2300, 2500, 2700, and 2900 K) in the framework of Reactive Force Field (ReaxFF) molecular dynamics simulation. The main gas products, density, energy, and the mean square displacement with temperature and pressure are also calculated. The findings indicate that raising the temperature leads to an increase in the production of gas products, while changing the pressure has an impact on the direction in which the products are generated; the faster the temperature drops, the less dense the air; both temperature and pressure increase impact the system's energy conversion or distribution mechanism, changing the system's potential energy as well as its total energy; the rate at which molecules diffuse increases with temperature, and decreases with pressure. The results of this investigation provide a theoretical basis for the development of the pyrolytic treatment of polyethylene waste materials. [ABSTRACT FROM AUTHOR]

This study investigates the potential for recycling fishing rope waste from the Magdalen Islands, Canada, into sustainable wall cladding panels, addressing both environmental concerns and waste management challenges. A comprehensive characterization of the fishing ropes was conducted using various analytical techniques to assess their suitability for recycling. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) identified polyethylene (PE) and isotactic polypropylene (iPP) as the main polymers present in the ropes, with a composition of approximately 25% PE and 75% PP. The effects of photodegradation were evaluated through carbonyl index analysis, differential scanning calorimetry (DSC), tensile testing, and gel permeation chromatography (GPC). The results showed reduced crystallinity, a 20% decrease in tensile strength, and lower molecular weights due to environmental exposure in comparison with unused ropes. However, melt flow rate (MFR) measurements aligned with virgin HDPE and PP values used in rope manufacturing, indicating suitable processability for recycling. Panels produced from recycled fishing ropes exhibited lower flexural and impact properties compared to commercial alternatives due to the presence of mineral contaminants and voids in the panels as revealed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). This comprehensive investigation provides valuable insights into the potential repurposing of fishing rope waste, contributing to the development of sustainable waste management strategies for coastal communities. [ABSTRACT FROM AUTHOR]

Friction stir spot welding (FSSW) is a promising technique for joining thermoplastic materials, such as high-density polyethylene (HDPE). However, there needs to be more understanding regarding the effect of welding parameters on the weld temperature of FSSW joints in HDPE. The Taguchi method is used for a FSSW of HDPE sheets in the present work. The welding parameters examined in the study include the tool number, speed, plunge depth, and dwell time. The effect of friction stir spot welding (FSSW) parameters on weld temperature was investigated using signal-to-noise ratio (S/N), an orthogonal array, and analysis of variance (ANOVA). The S/N ratio response graphs and ANOVA were used to discover the significant parameters and optimal welding parameter combination. The most important welding parameter affecting the weld pool's temperature is the tool's rotational speed, followed by dwell period. The tool rotation speed of 1400 revolutions per minute, tool penetration depth of 6.8 mm and dwell duration of 60 s are the optimal welding parameters for the temperature of weld pool. This investigation offers valuable perspectives on the FSSW process of HDPE. It can serve as a reference for determining optimal welding parameters in various industrial settings. [ABSTRACT FROM AUTHOR]

Abstract A series of high-density polyethylene and a statistical copolymer of poly(propylene-co-ethylene) blends in a wide range, namely (0, 10, 20, 30, 40, 50, 60,70, 80, 90, 100) abbreviated as HDPE/VM were systematically investigated by using a rheometer, differential scanning calorimetry (DSC) measurements, polarized optical microscopy (POM) and tensile tests. Rheometer results show that adding VM decreases dynamic viscosity, storage, and loss modulus. Han plot shows that HDPE and VM are compatible and miscible in the range from 20 to 60 VM % in the molten state. DSC results show little nucleation effect of VM on HDPE (HDPE’s melt crystallization temperature shifts 2 °C higher). Moreover, a linear composition dependence of ∆cp ∆Hc, ∆Hm shows that PE and VM are most probably compatible in the molten state in composition range from 20 to 60%. However, upon crystallization, the VM and PE domains occur distinctively. The results of the tensile tests demonstrated a decrease in elastic modulus, yield stress, and ultimate tensile strength as VM content increased. At low VM content (less than 20%), high elongation at break was detected for the blends, and very fine spherulites of HDPE were found across the sample by POM.

Abstract The widespread use of low-density polyethylene (LDPE) and high-density polyethylene (HDPE) plastics has resulted in a large amount of waste plastic that requires appropriate disposal or reuse. One potential solution is to use them in the modification of asphalt concrete (AC) mixtures for more sustainable highways. To study this possibility, permanent deformation and dynamic modulus (DM) of the LDPE and HDPE modified AC mixtures was investigated by conducting flow number (FN), flow time (FT) and DM tests on Superpave gyratory compacted specimens. Machine learning models; multi-layer perceptron (MLP), radial basis function neural network (RBFNN), generalized regression neural network (GRNN) and support vector machine (SVM) were used to predict the DM on the basis of frequency and temperature parameters. The model’s performance was gauged by analyzing the root mean square error, mean relative error, and coefficient of determination. The study findings revealed that the LDPE and HDPE modified AC mixtures provide 2.07 times and 1.27 times better resistance to permanent deformation, respectively, than their counterpart. It was also found that the LDPE and HDPE modified AC mixtures have 2.1 times and 1.4 times higher DM values, respectively, than the Control AC mixtures. Among the machine learning models, MLP (R2 = 0.98) showed best accuracy in predicting DM and thus is recommended to be used in similar studies due to its robustness. Additionally, the feature importance analysis revealed that frequency has the highest impact on DM predictions, followed by temperature and the inclusion of the LDPE.

Okra hessian cloth and Sunn hemp hessian cloth were prepared and treated with 5, 10, and 15 wt% alkali solutions for 1 h. The optimized concentration of alkali is 10 wt%. The untreated and treated hessian cloths reinforced high-density polyethylene (HDPE) composites were then prepared using the compression molding method. Alkali-treated, and 55 wt% fiber contents reinforced composites showed improved mechanical properties among 40, 45, 50, 55, 60, and 65 wt% fiber contents composites. 55 wt% fiber contents reinforced composites were then irradiated under gamma-ray at doses 2.5–7.5 kGy at the rate of 6 kGy/h. According to the X-ray diffraction analysis results, only alkali-treated Okra reinforced, and Sunn hemp-reinforced HDPE composites had higher crystallinity values than untreated and irradiated composites. Surface micrographs showed that the Okra-HDPE and Sunn hemp-HDPE had better matrix and fiber attachment. Cross-linking between the two varieties of fibers and matrix was seen using Fourier-transform infrared (FTIR) spectroscopy. Both irradiated composites exhibited greater hydrophobicity in their water intake characteristics compared to untreated and alkali-treated composites. The tensile strength (TS) value of Sunn hemp composite for 5 kGy gamma-ray irradiation dose is 68 MPa, which is 14% and 42% higher than that of treated and untreated composites, respectively. For comparison, the TS value for 5 kGy dose irradiated Okra composite is 66 MPa, which is 17% and 44% higher than that of treated and untreated composites, respectively. Young's modulus (Y) values of irradiated Okra composite and irradiated Sunn hemp composite showed higher values than that of other composites. Both irradiated composites have better thermal and structural characteristics than untreated and alkali-treated composites. [ABSTRACT FROM AUTHOR]

This work reported two types of photocatalysts in polymeric sheets derived from recycled high-density polyethylene (HDPEr): anatase TiO2 and Ag-decorated anatase TiO2 (TiO2-Ag). The Ag nanoparticles were deposited on the TiO2 nanoparticles via chemical reduction using formaldehyde as the reducing agent, although XPS analysis indicated that anatase was also reduced during Ag deposition. The sheets were prepared using two methods: extrusion and a plasma immersion process. In the first one, nanoparticles were introduced during extrusion, resulting in photocatalyst/HDPEr composites. On the other hand, the plasma method involved depositing photocatalyst nanoparticles into the polymer sheet surface through a two-step process of air plasma treatment followed by immersion in an aqueous photocatalyst suspension. The composites obtained through extrusion exhibited a higher Young's modulus compared to neat HDPEr, attributed to the reinforcing effect of the nanoparticles, which was more significant with the incorporation of TiO2 nanoparticles. Photocatalytic activity assessment revealed that sheets obtained by extrusion showed poor performance, whereas photocatalyst deposition on sheets significantly enhanced NOx photodegradation. Notably, TiO2-Ag nanoparticles exhibited superior photocatalytic activity, with the polymeric sheet containing TiO2-Ag nanoparticles on the surface achieving the highest activity (~ 23.67% NOx photodegradation). The detailed methodology and robust experimental data provided offer valuable insights into optimizing nanoparticle incorporation techniques to enhance the functional properties of recycled polymeric materials for environmental applications. Overall, although the plasma treatment did not affect the mechanical properties of the sheets significantly, it allows an outstanding advance in NOX abatement. Especially for the TiO2-Ag-modified sheets. Based on this background, this research addresses a double environmental approach by developing self-cleaning building panels from HDPEr. [ABSTRACT FROM AUTHOR]

This study investigates the potential for recycling fishing rope waste from the Magdalen Islands, Canada, into sustainable wall cladding panels, addressing both environmental concerns and waste management challenges. A comprehensive characterization of the fishing ropes was conducted using various analytical techniques to assess their suitability for recycling. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) identified polyethylene (PE) and isotactic polypropylene (iPP) as the main polymers present in the ropes, with a composition of approximately 25% PE and 75% PP. The effects of photodegradation were evaluated through carbonyl index analysis, differential scanning calorimetry (DSC), tensile testing, and gel permeation chromatography (GPC). The results showed reduced crystallinity, a 20% decrease in tensile strength, and lower molecular weights due to environmental exposure in comparison with unused ropes. However, melt flow rate (MFR) measurements aligned with virgin HDPE and PP values used in rope manufacturing, indicating suitable processability for recycling. Panels produced from recycled fishing ropes exhibited lower flexural and impact properties compared to commercial alternatives due to the presence of mineral contaminants and voids in the panels as revealed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). This comprehensive investigation provides valuable insights into the potential repurposing of fishing rope waste, contributing to the development of sustainable waste management strategies for coastal communities.

A composite of high-density polyethylene/ultra-high molecular weight polyethylene (HDPE/UHMWPE) was synthesized via a high-temperature melting process. We specifically examined the effects of annealing on the morphological and rheological properties of the composite. Using scanning electron microscopy and advanced rotational rheometry, we determined that annealing notably alters the composite’s microstructure, with a reduction in pronounced features post-treatment. Rheologically, UHMWPE content significantly enhanced mechanical properties, particularly in storage modulus (G′), loss modulus (G″), and complex viscosity (|η*|), which aligned with scaling law principles. Our findings highlight a distinct improvement in mechanical properties post-annealing, underscoring the potential of UHMWPE in enhancing polymer composite performance. The scaling laws relating G′, G″, and |η*| with UHMWPE were identified as follows: (1) pre-c e: G′ ∼ c 0.2, g″ ∼ c 0.07, |η*| ～ c0.07 and (2) post-c e: G′ ∼ c 1.20, g″ ∼ c 0.6, |η*| ∼ c 0.64, with a forward shift in c e noted after annealing. The addition of UHMWPE significantly enhanced the system’s properties, particularly after annealing. This study offers crucial insights into optimizing HDPE plastic films for enhanced durability and sustainability, ideally suiting them for eco-friendly agricultural uses.

Amid the current environmental crisis caused by plastic accumulation, one of the proposed solutions to manage this problem is using biodegradable polymers. However, the impact of adding biodegradable polymers to the well-established circular economy of recyclable polymers, such as HDPE, has not been fully considered. Therefore, there is a need to reconsider the way we consume, dispose of, and manage biodegradable polymers after use. This study evaluates the effect of varying the contents of a biodegradable polymer, taking poly(lactic acid) (PLA) as a model biodegradable polymer, on the thermal and mechanical properties of HDPE. The study highlights the importance of identifying and disposing of biodegradable polymers to avoid mixtures with HDPE, in order not to affect mechanical performance when considering reprocessing and a new life cycle of this conventional polymer. [ABSTRACT FROM AUTHOR]

In pursuit of a sustainable future, the focus on thermoplastic compounding emerges as a transformative avenue. Strategically blending and compounding thermoplastics unlock the potential for eco-friendly materials, addressing pressing environmental concerns. Polymer blending is a widely utilized technique that offers significant advantages in terms of cost-effectiveness and the development of materials with diverse properties. However, achieving compatibility between polymers remains a challenge due to their non-negligible entropy, particularly in the case of immiscible polymers like Polypropylene (PP) and High-Density Polyethylene (HDPE). The success of such systems heavily depends on optimizing factors such as additive selection, mixing methodology, composition, and processing conditions. Despite the extensive industrial usage of polymers like PP and HDPE, there is still limited understanding regarding the impact of blending these polymers, especially when graphene is introduced. This study addresses these challenges by overcoming the entropy barrier between PP and HDPE using a high shear rate thermo-kinetic mixer and employing upcycled graphene nanoplatelets (GNP) as a type of low-cost graphene material through interface engineering. The GNP content in the blends ranged from 0 to 1 wt%, and through meticulous selection of the polymer weight fraction and the use of minimal GNP content, GNP was strategically localized at the blend interface. This resulted in remarkable mechanical performance achieved through the optimized manufacturing technique. Incorporating 0.1 wt% GNP resulted in a significant 38% increase in tensile modulus, while flexural modulus and flexural strength saw respective increments of 39% and 22% compared to neat PP. Further enhancements were observed with higher GNP contents. This study illuminates the transformative potential of thermoplastic compounding as a key driver toward a sustainable future. [ABSTRACT FROM AUTHOR]

Plastic is a revolutionary material. However, pollution caused by plastic damages the environment, human health, and economy of different countries. It is important to find the new methods for recycling and reusing plastic materials. In this present study, plastic waste coming from high‐density polyethylene (HDPE) cups (called HDPEr in the following) are used together with virgin cork for production of composite materials. Different fractions of virgin cork with HDPEr are tested and allow to obtain successfully composite materials. The properties of HDPEr and composite are compared. The morphology of elaborated composite is studied by scanning electron microscope (SEM). The thermal properties are investigated by thermogravimetric analysis (TGA) analysis; the flammability study is performed using a cone calorimeter. Moreover, the mechanical properties of the samples stored under different conditions are studied by tensile strength experiments. The results show that the cork content has an effect on the mechanical and thermal properties. The feasibility of the composites based on cork and HDPEr wastes opens the way of reusing of these wastes. The formulation of HDPEr composites must be optimized by adding a flame retardant and a coupling agent. [ABSTRACT FROM AUTHOR]

High‐density polyethylene (HDPE) is one of the most used thermoplastic materials for piping applications, due to its significant advantages. The butt‐fusion process is the most used joining processes for HDPE welding. During the process, the behavior of the material changes. This behavioral change depends on the applied welding process and on the used parameters. Thermal analysis can be used as a tool to reveal and evaluate the modifications of the physical and mechanical properties. In this study, an experimental program was applied to HDPE to assess the effects of different parameters on the welding process including heating temperature, heating duration and the applied strength. Tests are performed according to a full factorial design of experiment (DOE). Mathematical models derived from experimental data are used to establish relationships between the input parameters, such as force and heating duration and the corresponding outputs such as temperature distribution during the different welding phases and the thickness of the molten polymer. The empirical models can be used to implement a control strategy for the temperature and hence quantify the thickness of the molten zone to improve the quality of the weld joint by selecting the appropriate welding conditions for the molten zone. Highlights: High‐density polyethylene piping butt‐fusion joint examination using Infrared imaging.Spatial–temporal distribution of temperature for different phases of the welding process.Mathematical Regression techniques are performed.Thickness of molten polymer is assessed.Results are useful for saving material and improvement of the process. [ABSTRACT FROM AUTHOR]

Polymer blends of poly(L-lactide)-b-poly(ethylene glycol)-b-poly(L-lactide) (PLLA-PEG-PLLA) and high-density polyethylene (HDPE) with different blend ratios were prepared by a melt blending method. The thermal, morphological, mechanical, opacity, and biodegradation properties of the PLLA-PEG-PLLA/HDPE blends were investigated and compared to the PLLA/HDPE blends. The blending of HDPE improved the crystallization ability and thermal stability of the PLLA-PEG-PLLA; however, these properties were not improved for the PLLA. The morphology of the blended films showed that the PLLA-PEG-PLLA/HDPE blends had smaller dispersed phases compared to the PLLA/HDPE blends. The PLLA-PEG-PLLA/HDPE blends exhibited higher flexibility, lower opacity, and faster biodegradation and bioerosion in soil than the PLLA/HDPE blends. Therefore, these PLLA-PEG-PLLA/HDPE blends have a good potential for use as flexible and partially biodegradable materials. [ABSTRACT FROM AUTHOR]

The co-pyrolysis of polyethylene terephthalate (PET) with low-density polyethylene (LDPE) and high-density polyethylene (HDPE) was carried out in a batch steel pyrolyzer in order to convert the PET into pyrolysis oil as its pyrolysis alone resulted in wax and gases. The study also aimed to increase the aromatic content of pyrolysis oil by the interaction of degradation fragments of linear chains of LDPE and HDPE with the benzene ring of PET during the pyrolysis. The reaction conditions were optimized for a higher yield of pyrolysis oil which were found to be 500 °C pyrolysis temperature with a heating rate of 0.5 °Cs−1, 1 h reaction time and 20 g of the initial mass of polymer mixture having 20% PET, 40% LDPE and 40% HDPE. Waste aluminium particles were applied as an economical catalyst in the process. The thermal co-pyrolysis yielded 8% pyrolysis oil, 32.3 wax, 39.7 wt% gases and 20% coke while the catalytic co-pyrolysis produced 30.2% pyrolysis oil, 4.2% wax, 53.6 wt% gases and 12% coke. The fractional distillation of catalytic oil resulted in 46% gasoline range oil, 31% kerosene range oil and 23% diesel range oil. These fractions resembled the standard fuels in terms of their fuel properties as well as FT-IR spectra. The GC-MS analysis revealed that the catalytic co-pyrolysis favoured the formation of relatively short-chain hydrocarbons with olefins and isoparaffins as major components while the thermal co-pyrolysis formed long-chain paraffins. The naphthenes and aromatics were also found in higher amounts in the catalytic oil compared with the thermal oil. [ABSTRACT FROM AUTHOR]

Untreated and alkali-treated Sunn hemp hessian cloth-reinforced high-density polyethylene (HDPE) composites were prepared by the compression molding method. The fabricated composites contained 40, 45, 50, 55, 60, and 65wt% fiber contents and were optimized. 55wt% fiber contents reinforced composites showed better mechanical properties. This composite was alkali treated and irradiated under gamma-ray at doses 2.5‒7.5 kGy at the rate of 6 kGy/h. The X-ray diffraction (XRD) result indicates that the crystallinity of the alkali-treated Sunn hemp-reinforced HDPE composites shows a higher value than those of untreated and irradiated composites. Better adhesion between fiber and matrix was observed from surface micrographs. Fourier-transform infrared (FTIR) spectroscopy reveals cross-linking between fiber and matrix. The water intake properties of irradiated composite show more hydrophobic nature than that of untreated and alkali-treated composites. The tensile strength of the gamma-ray irradiated composites are 20% and 33% greater than that of untreated and alkali-treated composites. Similar results are found for Young's modulus. At a certain dose of 5 kGy, the irradiated composites show improved thermal, mechanical, and structural properties than untreated and alkali-treated composites. [ABSTRACT FROM AUTHOR]

Chemical modification of the surface of halloysite nanotubes (HNT) by alkalization (with sodium hydroxide (NaOH)) and grafting with silanes (bis(trimethylsilyl)amine (HMDS)) was carried out. The efficiency of the alkalization and grafting process was evaluated by X–ray diffraction (XRD), Fourier–transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and the nitrogen adsorption method were used. XRD and FTIR analysis confirmed the formation of bonds of trimethylsilyl groups to the HNT surface which changed the nature of the surface from hydrophilic to hydrophobic. In addition, it was noted that grafting with silanes decreases by 7.2% the specific surface area of the halloysite compared to the alkalized material. High–density polyethylene (HDPE) composites with halloysite (HNT), alkalized halloysite (alk–HNT), and HMDS–modified halloysite (m–HNT) were processed in the molten state in a Brabender mixer chamber. On SEM/EDS micrographs of HDPE composites with silanized HNT, a change in surface characteristics from smooth to ductile was observed. Higher melting point values based on differential scanning calorimetry (DSC) analysis of HDPE composites with 5%wt silanized halloysite in comparison with HNT and alk–HNT of, respectively, 2.2% and 1.4% were found, which indicates a slight beneficial influence of the filler on the quality of ordering of the crystalline phase of the matrix. [ABSTRACT FROM AUTHOR]

This study reports the influence of fly ash on the operational, technological, and physical-mechanical properties of composites based on secondary high-density polyethylene filled with wood flour. It is shown that when calcite is replaced by fly ash in the composite, the operational and technological properties of the material are improved: water absorption, coefficient of linear thermal expansion and technological shrinkage are reduced. When using fly ash as a filler, there is also an increase in the flexural strength of the composite by 9% (from 51.3 MPa in the absence of fly ash to 55.8 MPa in the absence of calcite), but the Charpy impact toughness of samples with cut is decreased by more than 2 times (from 11.9 kJ/m² to 5.1 kJ/m², respectively). [ABSTRACT FROM AUTHOR]

This study assesses the impact of alkaline treatments and volume fractions on biocomposites composed of a high-density polyethylene (HDPE) matrix reinforced with date palm tree fibers (FPDS). Tensile tests were conducted on both untreated and NaOH-treated biocomposites. Additionally, fiber analysis was performed using scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results reveal higher strength and stiffness compared to HDPE, albeit with limited plasticity making the material brittle. The NaOH treatment enhances certain mechanical properties. Further assessments encompassed hardness, density, melt index, and Izod impact tests. Two volume fractions, 20% and 25%, of FPDS were tested. The study establishes a correlation between empirical predictions and artificial neural network (ANN) models. Notably, an ANN architecture consisting of two input factors, 10 hidden nodes, and one output provides the analysis of mechanical properties. This investigation highlights the potential of FPDS-reinforced HDPE biocomposites, emphasizing their mechanical performance under various treatments and fiber levels. [ABSTRACT FROM AUTHOR]

Worldwide, environmental groups and policymakers are focusing on waste recycling to create economic value and on the decomposition of waste by leveraging on scarce resources. This work, therefore, explores the thermal decomposition of enhanced biodegradable polymer matrices made from a mixture of discarded Phoenix dactylifera L./high-density polyethylene (PD/HDPE) using the machine learning analysis of experimental data. The experimental results of these samples were obtained via thermogravimetric (TGA) analysis under an oxidation–free environment, with heating rates of 10, 20, and 40 °C·min−1 and a degradation temperature range from 25 to 600 °C. The TGA analyses revealed the continued dependence of the actual percentage weight loss by these materials as a test function of the degradation temperature, shifting thermograms to temperature maxima consistent with increasing heating rates. Although high-density polyethylene (HDPE) materials were found to be thermally more stable than Phoenix dactylifera L. (PD) materials, PD/HDPE composite materials contained a significant amount of residual ash. Using a machine learning deep neural network approach for this process, significantly improved learning algorithms have been developed, which reduces the overall cost function (residual error) to almost zero (0.025) after just over a million iterations (epochs) and provides predictions that overlap with the experimental results ( R 2 ~ 1 ). Learning algorithms, along with optimized synaptic weights and biases, were employed to predict the behaviour of PD materials based on experimental thermograms conducted at higher degradation temperatures, typically ranging between 600 and 1000 °C. Predicted data using the enhanced learning algorithms completely overlapped the experiments ( R 2 ~ 1 ) for these higher degradation temperatures with near unity correlation if the decomposition of the materials continued until the residue was attained. With this approach, it is possible to predict and optimize the thermal characteristics of PD and HDPE with greater efficiency, which reduces the need for multiple design iterations and experimentation. [ABSTRACT FROM AUTHOR]

In the present study, electrostatic powder coating waste was recycled and employed to reinforce high‐density polyethylene. The hydrolysis method was preferred to modify the powder coating waste of various systems, and they were mixed with high‐density polyethylene at various weight ratios. The mixtures were prepared in a mechanical mixer and then in an extruder to obtain a homogeneous mixture. This homogeneous structure was pressed into molds with a plastic injection device to obtain standard tensile samples. Mechanical and thermal tests were conducted on the samples. It was determined that the tensile stress of the sample decreased with the increase in filler content. The changes in sample tensile strength were investigated after the samples were aged. Three‐point bending strength of the samples was also investigated and it was observed that they became more resistant to vertical loads as the filler content increased. The Izod impact strength of the samples differed based on the filler type and weight ratio. Furthermore, mass loss in the produced mixtures was determined with thermogravimetric analysis. The matrix and filler bonding mechanisms were observed under an electron microscope. [ABSTRACT FROM AUTHOR]

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The recycling of waste materials is a way of limiting over-consumption and optimizing the value of resources. Within the framework of a circular economy, this can be applied to post-consumer plastic wastes, but also to biobased by-products. Hence, this work deals with the design of composite materials by combining recycled high-density polyethylene (HDPE) and polypropylene (PP) coming from bottle caps and virgin cork of insufficient quality for cork stoppers. Different fractions (0, 5, 10, 15, and 20 wt%) of virgin cork were incorporated into recycled polymers (HDPEr and PPr). These composites were prepared without a coupling agent or fire retardant. The morphology and mechanical properties of the different conditionings were studied and compared. The thermal decomposition and the fire behavior of the composites were also investigated. Microscopy revealed the poor adhesion between the cork particles and polymer matrices. However, this limited interaction affected only the tensile strength of the PPr composites, while that of the HDPEr composites remained almost constant. The addition of cork was shown to reduce the time to ignition, but also to promote charring and reduce the heat released during the composite's combustion. The feasibility of composites based on cork and HDPEr/PPr waste opens the way for their reuse. [ABSTRACT FROM AUTHOR]

This paper presents a comprehensive investigation into the manufacturing of high‐performance wood‐crosslinked high‐density polyethylene composites (WxHDPEC). In particular, the effect of maleated polyethylene (MAPE) treatment and concentration (0–50 wt%) of maple wood fibers is investigated. The samples were produced via dry‐blending followed by compression molding and a set of characterization was performed including chemical, morphological, mechanical, thermal, and physical properties. The gel content was found to increase with increasing wood fiber content, while the surface modification significantly improved the tensile strength (11%), tensile modulus (298%), flexural strength (138%), and flexural modulus (81%). Thermal analyses also showed improved thermal stability and higher thermal resistance for the treated composites. Finally, the Shore D hardness increased by 11.0 (from 61.5 to 72.5) and 12.1 (from 61.5 to 73.6) points, while the Shore A hardness increased by 7.5 (from 91.5 to 99.0) and 8.1 (from 91.5 to 99.6) points for the untreated and treated composites, respectively. These improvements are attributed to effective adhesion between MAPE‐treated wood fibers and the xHDPE matrix. The findings not only advance our understanding of these complex materials but also provide alternatives for various applications from construction to automotive engineering. Highlights: High‐performance wood‐reinforced crosslinked high‐density polyethylene was produced.The effect of maleated polyethylene (MAPE) treatment and maple wood fibers was studied.Higher crosslink density in MAPE‐treated wood‐xHDPE was obtained.Wood‐crosslinked high‐density polyethylene composites have better properties. [ABSTRACT FROM AUTHOR]

Abstract The development of efficient and sustainable composites remains a primary objective of both research and industry. In this study, the use of biochar, an eco-friendly reinforcing material, in additive manufacturing (AM) is investigated. A high-density Polyethylene (HDPE) thermoplastic was used as the matrix, and the material extrusion (MEX) technique was applied for composite production. Biochar was produced from olive tree prunings via conventional pyrolysis at 500 °C. Composite samples were created using biochar loadings in the range of 2.0–10.0 wt. %. The 3D-printed samples were mechanically tested in accordance with international standards. Thermogravimetric analysis (TGA) and Raman spectroscopy were used to evaluate the thermal and structural properties of the composites. Scanning electron microscopy was used to examine the fractographic and morphological characteristics of the materials. The electrical/dielectric properties of HDPE/biochar composites were studied over a broad frequency range (10–2 Hz–4 MHz) at room temperature. Overall, a laborious effort with 12 different tests was implemented to fully characterize the developed composites and investigate the correlations between the different qualities. This investigation demonstrated that biochar in the MEX process can be a satisfactory reinforcement agent. Notably, compared to the control samples of pure HDPE, biochar increased the tensile strength by over 20% and flexural strength by 35.9% when added at a loading of 4.0 wt. %. The impact strength and microhardness were also significantly improved. Furthermore, the Direct current (DC) conductivity of insulating HDPE increased by five orders of magnitude at 8.0 wt. % of biochar content, suggesting a percolation threshold. These results highlight the potential of C-based composites for the use in additive manufacturing to further exploit their applicability by providing parts with improved mechanical performance and eco-friendly profiles. Graphical Abstract

This study proposes locally available and environment-friendly Algerian palm (Washingtonia filifera) waste fibers to develop biocomposites. Waste palm fibers (WPFs) were chosen as an effective high-intensity polyethylene (HDPE) reinforcement material to create WPF/HDPE biocomposites. WPFs were treated with sodium hydroxide (NaOH) solution to improve their adhesion to the HDPE matrix. Tensile strength and Young’s modulus were evaluated using mixes generated by the response surface methodology (RSM). Based on RSM, the central composite design was used to investigate the effect of various parameters on the tensile properties of cured WPF/HDPE biocomposites. The tensile properties of cured WPF/HDPE biocomposites were influenced by variables such as NaOH (0–3%), fiber treatment duration (0–24 h), and WPF content (0–30% (wt.)). RSM shows that tensile strength increases significantly with a NaOH concentration of 3%, a fiber treatment duration of 10.12 h, and a maximum content of 30% (wt.) in WPFs. The experimental validation reveals that these values correlate with predicted values with an error of less than 3.55%.

The common use of plastics in daily life has engendered gigantic amounts of waste plastics, which have a detrimental influence on the environment. Researchers have proposed several strategies for the recycling of waste plastics and their products. Among these, one strategy is to use them in the construction industry, particularly in asphaltic pavements. This study thus focused on the utilization of waste plastics, specifically Low-Density Polyethylene (LDPE) and High-Density Polyethylene (HDPE), as an additive in Asphalt Concrete (AC) mixes. Indirect Tensile Strength (ITS), Flow Time (FT), and Dynamic Modulus (DM) tests were used to investigate the moisture damage, permanent deformation, fatigue performance, and DM of the LDPE and HDPE modified AC mixes. According to the laboratory test results, the LDPE and HDPE modified AC mixes offer more resistance to moisture damage compared to the Control AC mixes. It was also concluded that asphalt mixes modified with the LDPE and HDPE attained 2.07 times and 1.26 times superior resistance to permanent deformation than the Control mixes. Furthermore, the LDPE and HDPE modified AC mixes outperformed the DM values of the Control mixes by 2.06 times and 1.41 times, respectively. In addition, it was determined that the LDPE and HDPE modified AC mixes exhibit 1.72 times and 1.39 times greater fatigue parameter values than their counterpart, suggesting superior fatigue resistance performance. The statistical models developed using Response Surface Methodology (RSM) revealed the highest values of the Coefficient of Determination (>0.80), adequate precision (>4.0), and lack-of-fit tests, indicating the model’s adequacy for predicting the response.

An iron-based metal–organic framework, MIL-53(Fe), was synthesized and added as a synergist to high-density polyethylene (HDPE), and its flame-retardant effect with aluminum diethyl hypophosphite (ADP) and aluminum hypophosphite (AHP) in HDPE was investigated to further improve the flame-retardant efficiency. FTIR results showed that the ADP, AHP, and MIL-53(Fe) were successfully incorporated into the HDPE. The LOI of HDPE-3 and HDPE-7 with 0.75 mass% MIL-53(Fe) was 48.9% and 34.8% higher than that of the pure sample. The combustion grades reached V-0 and V-1. HDPE/MIL-53(Fe)/ADP exhibited more superior flame-retardant properties than HDPE/MIL-53(Fe)/AHP. A synergistic effect between ADP and both AHP and MIL-53(Fe) changes the decomposition process of HDPE. In addition, the FGI value of the composites decreased after the addition of MIL-53(Fe). MIL-53(Fe) enhances the thermal stability of HDPE composites, and improves the quality of the char residue. Experimental results show that MIL-53(Fe) can be used as a flame retardant and is a novel material in polymer flame-retardant research. The new synthetic material shown here may contribute to environmental safety. [ABSTRACT FROM AUTHOR]

Prior studies into fatigue crack growth (FCG) in fibre-reinforced polymer composites have shown that the two methodologies of Simple-Scaling and the Hartman–Schijve crack growth equation, which is based on relating the FCG rate to the Schwalbe crack driving force, Δκ, were able to account for differences observed in the measured delamination growth curves. The present paper reveals that these two approaches are also able to account for differences seen in plots of the rate of crack growth, da/dt, versus the range of the imposed stress intensity factor, ΔK, associated with fatigue tests on different grades of high-density polyethylene (HDPE) polymers, before and after electron-beam irradiation, and for tests conducted at different R ratios. Also, these studies are successfully extended to consider FCG in an acrylonitrile butadiene styrene (ABS) polymer that is processed using both conventional injection moulding and additive-manufactured (AM) 3D printing. [ABSTRACT FROM AUTHOR]

Copyright of Ingeniería Solidaria is the property of Universidad Cooperativa de Colombia and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Polymer Materials Science & Engineering is the property of Sichuan University, Polymer Research Institute and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)