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SmCoO3 nanofibers achieve a large NH3 yield of 14.4 mg h−1 mgcat.−1 and a high faradaic efficiency of 81.3% at −1.0 V vs. RHE in 0.1 M PBS with 0.1 M NO3−.

Forkhead box L2 (FOXL2), one member in the superfamily of forkhead transcription factors, is a core transcription factor specifically expressed in ovarian granulosa cells and is essential for the development of follicles. FOXL2 has been shown to regulate the transcription of genes encoding enzymes that synthesize steroid hormones and estrogen receptors and regulate the expression of collagen genes in granulosa cells. This study explored the effect of FOXL2 on collagen gene expression in granulosa cells by overexpressing Foxl2 in pregranulosa cells, prehierarchical follicles and preovulation follicle granulosa cells. The results showed that FOXL2 regulated the expression of several genes encoding collagens in chicken granulosa cells and that overexpression of Foxl2 significantly reduced the messenger RNA and protein levels of Col4a1 in different granulosa cells. Moreover, luciferase reporter and chromatin immunoprecipitation assays were performed to study how FOXL2 regulates the expression of collagen genes, and the results showed that FOXL2 directly regulated the expression of Col4a1 by binding to the motif of CAGCAGCACCAGCAG between -640 and -625 bp upstream of the coding region. The results indicated that FOXL2 could regulate the components of the extracellular matrix; however, the biological significance of this regulation needs further clarification.

CuO-rich CuFe2O4 nanofibers with oxygen vacancies as a NO3−RR catalyst achieve a high Faradaic efficiency of 91.08% and a large NH3 yield of 9296.21 μg h−1 cm−2 at −1.0 V vs. RHE in 0.1 M PBS with 0.1 M NO3−.

Heterogenous Cu@ZrO2 nanofibers as an efficient and durable electrocatalyst with boosted catalytic activity for ambient nitrate reduction to ammonia achieves a large NH3 yield of 15.4 mg h−1 mg−1cat. and a high faradaic efficiency of 67.6%.

In this study, we construct a Cu@ZrO