1. Water aging effects on the flexural properties of fully biobased coir fiber composites
- Author
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Assis, Eduardo Geraldo, dos Santos, Julio Cesar, da Silva, Rodrigo Jose, de Oliveira, Livia Avila, del Pino, Gilberto Garcia, Scarpa, Fabrizio, and Panzera, Tulio Hallak
- Subjects
Castor oil -- Analysis ,Humidity -- Analysis ,Polymers -- Analysis ,Engineering and manufacturing industries ,Science and technology - Abstract
This work describes the flexural behavior of biocomposites composed of a polyurethane matrix derived from castor oil plants and coir fibers. A statistical design is performed to identify the effects of fiber alkaline treatment and aging on the flexural modulus and strength of the composites. Physical tests and failure analyses are carried out to better assess their mechanical performance. A second experiment at 100% relative humidity is performed on treated fiber composites to compare with those obtained by immersion in water. The flexural modulus of the composites is not significantly affected by the fiber alkali treatment, while the strength is reduced by 35.17% when treated fibers are considered. Increasing the exposure time of composites under both aging conditions progressively reduces their flexural properties. The aging process of biocomposites in an environment with 100% relative humidity takes twice as long to reduce to the same flexural properties as those aged in water. Highlights * Composites made with treated fibers showed higher apparent density and lower porosity. * Water aging reduces flexural modulus and strength of biobased coir composites. * The bending properties are strongly dominated by the properties of biobased polymer. * 100% relative humidity takes twice as long to reduce to the flexural properties as those aged in water. * Untreated coir fibers achieve superior bending properties under moisture aging. KEYWORDS aging process, alkaline treatment, biobased polyurethane, coir fiber, flexural properties, 1 | INTRODUCTION In recent years, the increase in nondegradable waste accumulated in landfills, mainly polymeric materials derived from petroleum, has generated considerable environmental problems. (1) For this reason, the [...]
- Published
- 2023
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