29 results on '"Pakawanit, Phakkhananan"'
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2. Effect of gold nanoparticles on lead zinc niobate–barium titanate structure by X-ray absorption spectroscopy.
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Pakawanit, Phakkhananan, Yimnirun, Rattikorn, Laosiritaworn, Yongyut, and Kanchiang, Kanokwan
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GOLD nanoparticles , *LEAD compounds , *BARIUM titanate , *X-ray absorption , *SINTERING - Abstract
The 0.93PZN-0.07BT ceramics containing 0.5 wt% AuNPs sintering was carried out for 3 – 5 h at various temperatures ranging from 1100 to 1150°C. The effect of AuNPs on 0.93PZN-0.07BT local structure and dielectric properties were investigated. The AuK-edge XANES spectrum indicated that AuNPs are not substituted into 0.93PZN-0.07BT structure. The dielectric constants and dielectric loss of 0.93PZN-0.07BT ceramics containing 0.5 wt% AuNPs after sintering at 1050°C for 3–5 h are higher and lower than that of 0.93PZN-0.07BT ceramics without AuNPs after sintering at 1100°C for 3–5 h, respectively, which can be described by assuming the connectivity series between the ceramics and the metal phases. In addition, Curie temperature shifting of 0.93PZN-0.07BT ceramics containing 0.5 wt% AuNPs due to the higher degree of chemical heterogeneity caused by the AuNPs addition. Therefore, the including of AuNPs into 0.93PZN-0.07BT ceramics can be improving dielectric properties with lower temperature and shorter time in sintering process. [ABSTRACT FROM PUBLISHER]
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- 2017
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3. Silk Fibroin/Amino Acid Hybrid Organic Piezoelectric-Triboelectric Nanogenerator.
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Suktep, Natdanai, Pongampai, Satana, Pakawanit, Phakkhananan, Noisak, Jitrawan, Bongkarn, Theerachai, Charoonsuk, Thitirat, and Vittayakorn, Naratip
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SILK fibroin , *ORGANIC acids , *ATTENUATED total reflectance , *NANOGENERATORS , *WEARABLE technology , *AMINO acids , *SCANNING electron microscopes - Abstract
Triboelectric nanogenerators (TENG) with great performance and biodegradability are desired for the expansion of novel medical devices and wearable electronics. The present study aims at the preparation of natural silk in the form of silk fibroin (SF) film for utilization in TENG and further improving its output efficiency by embedding organic-piezoelectric gamma-glycine (γ-gly) amino acid to be a hybrid-organic piezoelectric/triboelectric nanogenerator (HO-P/TENG). The attenuated total reflectance infrared spectroscopy (ATR-IR) results demonstrated the N-H, C = O, and C-N bonding for SF and SF/γ-gly, confirming its dominant effect with a strong electron-donating tendency from those amino groups. The scanning electron microscope (SEM) and synchrotron radiation X-ray tomographic microscopy (SR-XTM) images show good dispersibility of incorporated γ-gly on the surface and also inside the SF matrix relating to its content to improve the electrical performance homogeneously. By fabricating the device in the vertical contact-separation mode, the present SF/γ-gly HO-P/TENG at 15 wt% provides the maximum output voltage (VOC) and current (ISC) of 81 V and 121 μA with a maximum output power (Pmax) of 205 μW at the external load resistance of 5 MΩ. This SF-based HO-P/TENG has the advantage of being cost-effective with simple fabrication, demonstrating great promise for practical uses. [ABSTRACT FROM AUTHOR]
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- 2023
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4. Simple Method for Enhancing Performance of the Bacterial Cellulose-Based Triboelectric Nanogenerator by Adding Conductive Interlayer.
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Sriphan, Saichon, Pharino, Utchawadee, Pakawanit, Phakkhananan, Bongkarn, Theerachai, Vittayakorn, Wanwilai, and Vittayakorn, Naratip
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SURFACE charges , *SUSTAINABILITY , *HARVESTING , *CELLULOSE , *NANOSTRUCTURED materials - Abstract
Surface charge density is a key factor that greatly enhances the performance of a natural-based triboelectric nanogenerator (TENG), which is essential for future sustainable sensing and harvesting devices. This work introduced a conductive interlayer between a main frictional layer and electrode. This approach can suppress the charge recombination rate and improve the amount of charges produced during the triboelectrification process. Bacterial cellulose (BC) film was selected as a main frictional layer for the TENG. A conductive nanomaterial, i.e. silver flake, was incorporated into the BC film as an intermediate layer for enhancing TENG performance. As firstly reported, the maximum electrical outputs for the multi-layer BC structure could be found when using silver flake/BC composite (ratio 1:5) as an intermediate layer, which has 122 V and 8.2 µA of output voltage and current, respectively. This is higher than the output voltage and current of a single layer BC TENG by approximately 3 and 8 times, respectively. The maximum output power of ∼440 µW is achieved by connecting with a load resistor of ∼10 MΩ. This demonstrates an efficient strategy for designing a high performance energy harvester by adding an intermediate layer for the target of practical purposes in sustainable systems. [ABSTRACT FROM AUTHOR]
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- 2023
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5. Synthesis and cytotoxicity study of magnesium ferrite-gold core-shell nanoparticles.
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Nonkumwong, Jeeranan, Pakawanit, Phakkhananan, Wipatanawin, Angkana, Jantaratana, Pongsakorn, Ananta, Supon, and Srisombat, Laongnuan
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CELL-mediated cytotoxicity , *MAGNESIUM , *NANOMEDICINE , *ENERGY dispersive X-ray spectroscopy , *GOLD nanoparticles - Abstract
In this work, the core-magnesium ferrite (MgFe 2 O 4 ) nanoparticles were prepared by hydrothermal technique. Completed gold (Au) shell coating on the surfaces of MgFe 2 O 4 nanoparticles was obtained by varying core/shell ratios via a reduction method. Phase identification, morphological evolution, optical properties, magnetic properties and cytotoxicity to mammalian cells of these MgFe 2 O 4 core coated with Au nanoparticles were examined by using a combination of X-ray diffraction, scanning electron microscopy, transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy, UV–visible spectroscopy (UV–vis), vibrating sample magnetometry and resazurin microplate assay techniques. In general, TEM images revealed different sizes of the core-shell nanoparticles generated from various core/shell ratios and confirmed the completed Au shell coating on MgFe 2 O 4 core nanoparticles via suitable core/shell ratio with particle size less than 100 nm. The core-shell nanoparticle size and the quality of coating influence the optical properties of the products. The UV–vis spectra of complete coated MgFe 2 O 4 -Au core-shell nanoparticles exhibit the absorption bands in the near-Infrared (NIR) region indicating high potential for therapeutic applications. Based on the magnetic property measurement, it was found that the obtained MgFe 2 O 4 -Au core-shell nanoparticles still exhibit superparamagnetism with lower saturation magnetization value, compared with MgFe 2 O 4 core. Both of MgFe 2 O 4 and MgFe 2 O 4 -Au core-shell also showed in vitro non-cytotoxicity to mouse areola fibroblast (L-929) cell line. [ABSTRACT FROM AUTHOR]
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- 2016
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6. Anatomical and molecular insights into the antennal gland of the giant freshwater prawn <italic>Macrobrachium rosenbergii</italic>.
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Kruangkum, Thanapong, Jaiboon, Kornchanok, Pakawanit, Phakkhananan, Saetan, Jirawat, Pudgerd, Arnon, Wannapaiboon, Suttipong, Chotwiwatthanakun, Charoonroj, Cummins, Scott F., Sobhon, Prasert, and Vanichviriyakit, Rapeepun
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In this study, the complex organization of the AnG in the giant freshwater prawn
Macrobrachium rosenbergii was revealed using various techniques, including conventional histology, histochemistry, scanning electron microscopy, and X-ray tomography. The results showed the diversity of cells in the AnG and the detailed organization of the labyrinth’s tubule into four radiated areas from the central to peripheral zones. The study also demonstrated the expression of some vertebrate kidney-associated homolog genes,aquaporin (AQP ),solute carrier family 22 (SLC-22 ),nephrin , anduromodulin , in the AnG by qPCR. The result of in situ hybridization further showed the localization ofSLC-22 andAQP transcript in the bladder and labyrinth’s epithelium, specifically in regions 2, 3, and 4. Additionally, the study revealed neuropeptide expressions in the AnG by qPCR and in situ hybridization, i.e.,crustacean hyperglycemic hormone (CHH ) andmolt inhibiting hormone (MIH ), implying that the AnG may have a role in hormone production. Moreover, male and female prawns exhibited different levels ofAQP ,SLC-22 ,nephrin , andCHH expressions during the premolt and intermolt stages, suggesting a crucial role relevant to the molting stages. In conclusion, this study clarified the complex structure of the AnG inM. rosenbergii and demonstrated for the first time the expression of vertebrate kidney-associated genes and the possible endocrine role of the AnG. Further investigation is needed to clarify the role of these genes, particularly during ecdysis. The implications of these findings could significantly advance our understanding of the AnG in decapod crustaceans. [ABSTRACT FROM AUTHOR]- Published
- 2024
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7. In-situ observation of structural and chemical transitions in B4C based layered systems.
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Morawe, Christian, Pakawanit, Phakkhananan, Supruangnet, Ratchadaporn, Chanlek, Narong, Kaewsuwan, Dechmongkhon, Peffen, Jean-Christophe, and Labouré, Sylvain
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ENERGY dispersive X-ray spectroscopy , *DC sputtering , *X-ray optics , *X-ray spectra , *MAGNETRON sputtering - Abstract
• Boron depletion in B 4 C based thin layered systems was investigated. • Pt/B 4 C was studied with in-situ X-ray reflectivity during annealing in air. • The study was complemented by depth-resolved XPS, EDX, and TEM. • An interplay of reactive B 4 C, catalytic Pt, and protective C was observed. • The method is a convenient tool to optimize multilayer fabrication strategies. In the context of multilayer based X-ray optics developments, thin layered systems of C/[Pt/B 4 C] multilayers and C/Pt/B 4 C/Cr stacks with variable cap layer thicknesses were deposited on Si wafers using DC magnetron sputtering. The samples were studied with in-situ X-ray reflectivity techniques during annealing in air up to temperatures of 300 °C. Simulated X-ray spectra of B 4 C/Cr reveal a considerable thickness loss of the B 4 C layer at elevated temperatures. The effect is amplified and accelerated when a thin Pt top layer is added but attenuated and slowed down by an additional C cap layer. Energy dispersive X-ray spectroscopy data indicate the overall depletion of B in samples after the annealing process. In-depth studies using X-ray photoelectron spectroscopy techniques show clear evidence of chemical modifications in the original B 4 C layer and confirm the structural modifications derived from the X-ray reflectivity data. This study demonstrates the catalyzing role of Pt in the degradation of B 4 C based layered structures in air and the potential protective function of C cap layers. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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8. Highly Flexible Tribovoltaic Nanogenerator Based‐on P‐N Junction Interface: Comparative Study on Output Dependency Dominated by Photovoltaic Effect in Freestanding‐Mode.
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Sriphan, Saichon, Worathat, Supakarn, Pharino, Utchawadee, Chanlek, Narong, Pakawanit, Phakkhananan, Choodam, Kanokwan, Kanjanaboos, Pongsakorn, Maluangnont, Tosapol, and Vittayakorn, Naratip
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PHOTOVOLTAIC effect , *TRIBOELECTRICITY , *ENERGY harvesting , *FLEXIBLE electronics , *NANOGENERATORS , *COMPARATIVE studies , *SEMICONDUCTORS , *ELECTRIC charge - Abstract
The emergence of tribovoltaic nanogenerators (TVNGs) paves the way for developing a new kind of semiconductor‐based energy harvester that overcomes the restriction of low output current in a conventional approach. The traditional TVNG generally depends on the frictional pair between two rigid semiconductors (or metal‐semiconductor), limiting the practicability of flexible and portable electronics. Recent developments require the fundamental understanding of charge generation in diverse operating modes and structures. Here, a flexible TVNG based on the p‐Cu2O/n‐g‐C3N4 interface is presented. Operating in a freestanding mode, the proposed TVNG can generate a stable signal in any optical conditions including UV illumination, dark, and ambient. Under UV illumination, the electrical outputs of the TVNG reach 0.43 V and 2.1 µA cm−2, which are significantly larger than those obtained from dark and ambient conditions. The results demonstrate the coupling effect of three phenomena: tribovoltaic, photovoltaic, and triboelectric effects, and the unique mechanism to the observed signal is proposed. Additionally, the TVNG shows the practical feasibility of energy harvesting with capacitor charging and charge‐boosting circuits. This study showcases the unique concept with potential for developing a novel flexible nanogenerator in many aspects, including material, structure, and fundamental mechanism. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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9. Electrical performance enhancement of a triboelectric nanogenerator based on epoxy resin/BaTiO3 by Al nanopowder addition for low power electronic devices.
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Amorntep, Narong, Namvong, Ariya, Wongsinlatam, Wullapa, Remsungnen, Tawun, Siritaratiwat, Apirat, Srichan, Chavis, Sriphan, Saichon, Pakawanit, Phakkhananan, Ariyarit, Atthaporn, Supasai, Wisut, Jutong, Nuttachai, Narkglom, Sorawit, and Surawanitkun, Chayada
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ELECTRONIC equipment , *RENEWABLE energy sources , *ENERGY dispersive X-ray spectroscopy , *EPOXY resins , *POWDERS , *INTELLIGENT sensors , *ELECTRON energy loss spectroscopy , *SMART materials - Abstract
Triboelectric nanogenerators (TENGs) are crucial for applications such as smart sensors and bio-electronics. In the current work, we aimed for improved performance of TENGs with incorporation of BaTiO3 powder, which is known for its strong ferroelectric properties, combining it with epoxy resin to improve the flexibility of our devices. We observed that our TENGs can operate for over 24 000 cycles with no degradation of function. Additionally, we improved the electrical performance of the TENGs by incorporating various aluminum concentrations that change the electronic properties in the form of mixed epoxy resin, BaTiO3, and Al nanopowders. To identify the optimum conditions for the best performance, we analyzed the electrical characteristics and material properties by employing scanning electron microscopy, energy dispersive x-ray spectroscopy, and x-ray diffractometry characterization techniques. Our findings suggest that this innovative combination of materials and optimization techniques can significantly improve the performance of TENGs, making them ideal for practical applications in various fields, such as low-power electronics, environmental monitoring and healthcare. Moreover, these enhanced TENGs can serve as sustainable and dependable energy sources for various applications. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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10. Structural, optical, and electrical properties of cellulose/titanate nanosheets composite with enhanced protection against gamma irradiation.
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Maluangnont, Tosapol, Kwamman, Tanagorn, Pulphol, Phieraya, Pongampai, Satana, Charoonsuk, Thitirat, Pakawanit, Phakkhananan, Seriwattanachai, Chaowaphat, Kanjanaboos, Pongsakorn, and Vittayakorn, Naratip
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TITANATES , *NANOSTRUCTURED materials , *CELLULOSE , *ATOMIC force microscopy , *SYNCHROTRON radiation , *CORPORATE bonds - Abstract
Two-dimensional (2D) materials have emerged as a promising functional filler in nanocomposites due to their unique anisotropy and resilience to harsh conditions. We report herein the use of Ti 0.91 O 2 nanosheets as a protective component against γ -irradiation to cellulose paper. The titanate nanosheets were prepared via a sequence of solid-state synthesis of lepidocrocite-type Cs 0.7 Ti 1.825 O 4 , proton exchange to H 0.7 Ti 1.825 O 4 ·H 2 O, and exfoliation with tetrabutylammonium hydroxide. The nanosheets were incorporated into the commercial cellulose filter paper by a simple dip coating up to 0.6 mg cm−2, equivalent to 10 wt% TiO 2. The nanosheets distribution was demonstrated by energy dispersive X-ray (EDX) mapping, synchrotron radiation X-ray tomographic microscopy (SRXTM), and atomic force microscopy (AFM). It is found that γ -irradiation (up to 50 kGy) destroyed the cellulose I β crystallinity of uncoated paper, but this is less pronounced in the cellulose/titanate nanosheets composite. This was also confirmed by the lack of a 235 nm-absorption characteristics of irradiation-induced decomposition product(s) in nanosheets-containing papers, which also exhibit UVA shielding property. The coated samples remained white while the uncoated ones were darkened with γ -irradiation. In addition, the nanosheets-coated papers showed dielectric permittivity, loss tangent, and AC conductivity which were invariant of the γ -dose, unlike those from the uncoated ones. Our work demonstrates the use of lead-free Ti 0.91 O 2 nanosheets as a γ -shielding component to slow down/prevent structural, optical, and electrical properties damages in cellulose paper, which could extend to other nature-derived materials. [Display omitted] • Simple dip coating of commercial filter paper into titanate nanosheets suspension. • Nanosheets loadings were confirmed by several techniques. • The nanosheets (0.6 mg cm−2, or 10 wt% TiO 2) prevent structural, optical, and electrical properties damages by γ -irradiation (up to 50 kGy). [ABSTRACT FROM AUTHOR]
- Published
- 2023
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11. Characterization of 0.93Pb(Zn1/3Nb2/3)O3–0.07BaTiO3 ceramics derived from a novel Zn3Nb2O8 B-site precursor
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Pakawanit, Phakkhananan, Ngamjarurojana, Athipong, Prasatkhetragarn, Anurak, and Ananta, Supon
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ZINC oxide , *BARIUM titanate , *NIOBIUM oxide , *CERAMIC metals , *PEROVSKITE , *RELAXOR ferroelectrics , *MICROFABRICATION - Abstract
Abstract: In this work, perovskite relaxor ferroelectric lead zinc niobate–barium titanate (0.93PZN–0.07BT) ceramics were fabricated by using a combination of Zn3Nb2O8 B-site precursor and reactive sintering process. The effects of sintering condition on phase formation, densification, microstructure and dielectric properties of the final products have been investigated using a combination of X-ray diffraction, Archimedes density measurement, scanning electron microscopy and dielectric measurement techniques. It is seen that pure perovskite phase of PZN-BT solid solutions can be achieved in all samples. Density and average grain size values of sintered samples increased with sintering temperatures and dwell time. With appropriate sintering at 1150°C for 5h, 0.93PZN–0.07BT ceramics exhibited a peak dielectric constant of 11,497 and dielectric loss of 0.05 at the Curie temperature of 99°C measured at 1kHz. [Copyright &y& Elsevier]
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- 2013
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12. Simple enhanced charge density of chitosan film by the embedded ion method for the flexible triboelectric nanogenerator.
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Charoonsuk, Thitirat, Supansomboon, Supitcha, Pakawanit, Phakkhananan, Vittayakorn, Wanwilai, Pongampai, Satana, Woramongkolchai, Somsak, and Vittayakorn, Naratip
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LIGHT emitting diodes , *SURFACE roughness , *BIOPOLYMERS , *CHITOSAN - Abstract
This research proposed a simple ionic embedded method to improve electrical output performance by adding surface charges of cationic chitosan (CS) biopolymer for compatible utilization of the triboelectric nanogenerator (TENG). By simply embedding cationic salts, the TENG performance was enhanced by over four times more than that with pristine CS. Moreover, by modifying roughness on the film surface, the optimized condition of R-CS/3 %CaCl 2 reached the highest V OC and I SC of ~149 V and ~15 μA, respectively, thus exceeding the output from pristine R-CS TENG by four- and three times of ⁓38 V and ⁓5.1 μA. The maximum power output of 400 μW/cm2 can be observed at the 10 MΩ external load resistance. Finally, by integrating an automatic self-charge pumping (ASCP) module, the ASCP/CS-TENG provided highly efficient V OC and I SC output power by over 1.3 times more than the R-CS/3 %CaCl 2 TENG and could light up 72 light emitting diodes (LEDs) easily. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2022
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13. Microwave absorption function on a novel one-part binary geopolymer: Influence of frequency, ageing and mix design.
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Yong-Jie, Hang, Cheng-Yong, Heah, Yun-Ming, Liew, Abdullah, Mohd Mustafa Al Bakri, Yeng-Seng, Lee, Wei-Hao, Lee, Pakawanit, Phakkhananan, Shee-Ween, Ong, Hoe-Woon, Tee, and Cheng-Hsuan, Hsu
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POLYMER-impregnated concrete , *INORGANIC polymers , *DIELECTRIC loss , *MICROWAVES , *FLY ash , *ABSORPTION , *PERMITTIVITY - Abstract
This paper presents an innovative application of a one-part geopolymer for microwave absorption. The influences of frequency, ageing time and mixing formulations on the mechanical, dielectric, and microwave-absorbing performance of the one-part binary geopolymer using fly ash and ladle furnace slag were investigated. The mixing formulations included alkali activators-to-aluminosilicate sources, sodium metasilicate-to-sodium hydroxide, and water-to-binder ratios. The results demonstrated that the dielectric constant decreased while the dielectric loss and loss tangent increased and remained constant with increasing frequency. The geopolymers have the highest dielectric values at an early age and diminish with ageing time. These resulted in the geopolymers having excellent microwave absorption (50 – 80%) at high-frequency levels and later ages. A higher water content resulted in higher porosity, reducing mechanical strength but enhancing microwave absorption. An optimal water content must be attained to achieve dual mechanical strength and microwave absorption performance. • One-part binary geopolymer based on FA and LFS was synthesized. • Geopolymers show excellent microwave absorbing performance at higher frequency. • Microwave absorption of the geopolymers improved at later age. • Porosity creates path to attenuate the microwave energy. [ABSTRACT FROM AUTHOR]
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- 2024
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14. Piezo-tribo-electric nanogenerator based on BCZT/MCNTs/PDMS piezoelectric composite for compressive energy harvesting.
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Buatip, Natthawadi, Munthala, Dhanunjaya, Amonpattaratkit, Penphitcha, Pakawanit, Phakkhananan, Hu, Xiao, Jongpinit, Watcharin, Janphuang, Pattanaphong, Wan, Chaoying, Bowen, Chris, and Pojprapai, Soodkhet
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ENERGY harvesting , *PIEZOELECTRIC composites , *TRIBOELECTRICITY , *MECHANICAL energy , *MULTIWALLED carbon nanotubes , *ELECTRICAL energy , *MECHANICAL oscillations - Abstract
• Enhancing the electrical output performance of a composite piezoelectric nanogenerator based on BCZT/MCNTs/PDMS through triboelectric hybridization. • The piezo-triboelectric nanogenerator, based on the BCZT/MCNTs/PDMS composite, demonstrated optimal electrical output performance at a 50 wt%-BCZT ratio (V OC ∼ 39.7 V, I SC ∼ 1.9 µA, peak-to-peak power of ∼ 157.7 µW, and power density of ∼ 9.85 µW/cm2) under a compressive load force of 500 N and a frequency of 1 Hz. • The piezo-triboelectric nanogenerator device exhibits promising potential for energy harvesting under high compressive loading at low frequencies. This work has developed a novel piezo-tribo-electric nanogenerator (P-TENG) that is capable of converting mechanical energy into electrical energy when operating in compressive mode. An arch-shaped P-TENG device was formed using an optimal piezoelectric polymer composite, which was fabricated using a polydimethylsiloxane (PDMS) matrix that was modified with piezoelectric (Ba 0.85 Ca 0.15) (Ti 0.90 Zr 0.10)O 3 (BCZT) ceramic particles and electrically conductive multi-walled carbon nanotubes (MCNTs). A high filler loading of BCZT (40, 50, 60 wt%) and 3 wt% of MCNTs was formed into a 0–3 connectivity composite. The P-TENG device containing 50 wt% BCZT exhibited the highest electrical output (V OC ∼ 39.7 V, I SC ∼ 1.9 µA, and maximum power ∼ 157.7 µW), compared to the other composites, when subjected to an alternating compressive load of 500 N at a 1 Hz frequency. This research provides new composite formulations for elastomeric-based energy generators that are responsive to low frequency mechanical oscillations. [Display omitted] [ABSTRACT FROM AUTHOR]
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- 2024
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15. Improvements of Flexural Properties and Thermal Performance in Thin Geopolymer Based on Fly Ash and Ladle Furnace Slag Using Borax Decahydrates.
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Yong-Sing, Ng, Yun-Ming, Liew, Cheng-Yong, Heah, Abdullah, Mohd Mustafa Al Bakri, Pakawanit, Phakkhananan, Vizureanu, Petrica, Khalid, Mohd Suhaimi, Hui-Teng, Ng, Yong-Jie, Hang, Nabiałek, Marcin, Pietrusiewicz, Paweł, Garus, Sebastian, Sochacki, Wojciech, and Śliwa, Agata
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FLY ash , *THERMAL properties , *BORAX , *GLASS transition temperature , *SLAG - Abstract
This paper elucidates the influence of borax decahydrate addition on the flexural and thermal properties of 10 mm thin fly ash/ladle furnace slag (FAS) geopolymers. The borax decahydrate (2, 4, 6, and 8 wt.%) was incorporated to produce FAB geopolymers. Heat treatment was applied with temperature ranges of 300 °C, 600 °C, 900 °C, 1000 °C and 1100 °C. Unexposed FAB geopolymers experienced a drop in strength due to a looser matrix with higher porosity. However, borax decahydrate inclusion significantly enhanced the flexural performance of thin geopolymers after heating. FAB2 and FAB8 geopolymers reported higher flexural strength of 26.5 MPa and 47.8 MPa, respectively, at 1000 °C as compared to FAS geopolymers (24.1 MPa at 1100 °C). The molten B2O3 provided an adhesive medium to assemble the aluminosilicates, improving the interparticle connectivity which led to a drastic strength increment. Moreover, the borax addition reduced the glass transition temperature, forming more refractory crystalline phases at lower temperatures. This induced a significant strength increment in FAB geopolymers with a factor of 3.6 for FAB8 at 900 °C, and 4.0 factor for FAB2 at 1000 °C, respectively. Comparatively, FAS geopolymers only achieved 3.1 factor in strength increment at 1100 °C. This proved that borax decahydrate could be utilized in the high strength development of thin geopolymers. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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16. Thin fly ash/ ladle furnace slag geopolymer: Effect of elevated temperature exposure on flexural properties and morphological characteristics.
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Yong-Sing, Ng, Yun-Ming, Liew, Cheng-Yong, Heah, Abdullah, Mohd Mustafa Al Bakri, Pakawanit, Phakkhananan, Chan, Lynette Wei Ling, Hui-Teng, Ng, Shee-Ween, Ong, Wan-En, Ooi, and Yong-Jie, Hang
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INORGANIC polymers , *HIGH temperatures , *POROSITY , *TEMPERATURE effect , *FLY ash , *FLEXURAL strength , *POLYMER-impregnated concrete , *SLAG - Abstract
The flexural properties and thermal performance of 10 mm-thin geopolymers made from fly ash and ladle furnace slag were evaluated before and after exposure to elevated temperatures (300 °C, 600 °C, 900 °C, 1100 °C and 1150 °C). Class F fly ash was mixed with liquid sodium silicate (Na 2 SiO 3) and 12 M sodium hydroxide (NaOH) solution using aluminosilicate/activator ratio of 1:2.5 and Na 2 SiO 3 /NaOH ratio of 1:4 to synthesise thin fly ash (FA) geopolymers. 40 wt% of ladle furnace slag was partially replacing fly ash to produce fly ash/slag-based (FAS) geopolymers. Thermal treatment enhanced the flexural strength of thin geopolymers. In comparison to the unexposed specimen, the flexural strength of FA geopolymers at 1150 °C and FAS geopolymers 1100 °C was increased by 161.3% to 16.2 MPa and 208.9% to 24.1 MPa, respectively. A more uniform heating was achieved in thin geopolymers which favoured the phase transformation at high temperatures and contributed to the substantial increase in flexural strength. The joint effect of elevated temperature exposure and the incorporation of ladle furnace slag further improved the flexural strength of thin geopolymers. The calcium-rich slag refined the pore structure and increased the crystallinity of thin geopolymers which aided in high strength development. [Display omitted] • Thermal treatment enhanced the flexural strength of 10-mm thin geopolymers. • FA geopolymers increased flexural strength by 161.3% to 16.2 MPa at 1150 °C. • FAS geopolymers increased flexural strength by 208.9% to 24.1 MPa at 1100 °C. • Uniform heating was achieved in thin geopolymers, aided the phase transformation. • Ca-rich LFS refined the pore structure and increased geopolymers' crystallinity. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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17. Physico-mechanical and microstructural evolution of sintered pressed geopolymer: Dual effects of aging period and sintering temperature.
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Shee-Ween, Ong, Cheng-Yong, Heah, Yun-Ming, Liew, Li-Ngee, Ho, Wei-Hao, Lee, Mustafa Al Bakri Abdullah, Mohd, Pakawanit, Phakkhananan, Wei-Ken, Part, Yong-Jie, Hang, Jia-Ni, Lim, De-Wei, Gao, and Mei-Ju, Liu
- Abstract
Ceramics are highly valued for their exceptional thermal resistance and ability to withstand high temperatures. This study investigated the production of ceramic-like pressed geopolymer, focusing on the effects of aging period and sintering temperature. The results showed that the 7-day pressed geopolymer achieved the highest compressive (134.7 MPa) and flexural (34.9 MPa) strengths after sintering at 1000°C, with a density retention of 93.7 %, a mass loss of 7.9 %, and a thermal shrinkage of 1.4 %. Microstructural analysis at 1000°C showed a dense ceramic-like structure with nepheline formation. Phase analysis of the 7-day pressed geopolymer revealed a decrease in the amorphous phase as temperature increased, with nepheline formed at 800°C (26.0 %) and maximized at 1000°C (61.0 %). This work offers an optimal aging period and sintering temperature to maximize the mechanical strength and nepheline crystal formation, making them perfect for fire-resistant panels and precast construction products. • Pressed geopolymer was formed at various aging times and sintering temperatures. • The highest mechanical strength was achieved by the 7d pressed geopolymer at 1000°C. • The residual compressive strength at 1000°C ascends in 28d < 7d < 1d. • Gel matrix transformed into a ceramic-like structure with rising temperature. • The 7d pressed geopolymer has the most nepheline phase formation at 1000°C. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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18. Effects of parboiling and infrared radiation drying on the quality of germinated brown rice.
- Author
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Chatchavanthatri, Natthaporn, Junyusen, Tiraporn, Arjharn, Weerachai, Treeamnuk, Tawarat, Junyusen, Payungsak, and Pakawanit, Phakkhananan
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BROWN rice , *INFRARED radiation , *MAILLARD reaction , *BIOACTIVE compounds , *PHENOLS , *RICE , *OLIVE oil - Abstract
This research investigated the physicochemical properties, bioactive compounds, and microstructure of brown rice (BR) and non-parboiled and parboiled germinated brown rice (GBR and PGBR). The GBR and PGBR were treated by sun, hot-air oven, or infrared irradiation (IR) drying. The results showed that IR drying enhanced the bioactive compounds of non-parboiled GBR, including γ-aminobutyric acid, α-tocopherol, and total phenolic compounds, while γ-oryzanol and antioxidant activity were comparable to BR. Meanwhile, IR drying significantly improved the head rice yield (HRY) of PGBR while reducing fissured grains. Parboiling also affected the color values of rice grains, suggesting the diffusion of husk color into endosperm and the formation of brown polymers by the Maillard reaction. In addition, IR drying altered the internal structure of rice grains, resulting in abundant intercellular voids. Specifically, the IRdried non-parboiled GBR significantly enhanced essential bioactive compounds and improved HRY while maintaining the color of standard BR. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
19. Acid-resistance of one-part geopolymers: Sodium aluminate and carbonate as alternative activators to conventional sodium metasilicate and hydroxide.
- Author
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Wan-En, Ooi, Yun-Ming, Liew, Cheng-Yong, Heah, Abdullah, Mohd Mustafa Al Bakri, Li Ngee, Ho, Pakawanit, Phakkhananan, Wei Ken, Part, Khalid, Mohd Suhaimi, Md Razi, Hasniyati, Lee, Wei-Hao, Soo Jin, Tan, Shee-Ween, Ong, and Yong-Jie, Hang
- Subjects
- *
SODIUM aluminate , *SODIUM hydroxide , *ACID throwing , *SULFURIC acid , *FLY ash , *CALCITE - Abstract
[Display omitted] • The acid resistance of one-part geopolymers (OPGs) was studied. • Formation of hydrate gels during acid exposure led to a slight strength recovery. • High sorptivity made Na 2 SiO 3 and NaOH-based OPG more susceptible to acid attack. • The incorporation of NaAlO 2 and Na 2 CO 3 enhanced OPG's acid resistance. In this study, the durability of one-part geopolymers (OPGs) made from high calcium fly ash is assessed by investigating their resistance to acid attacks. The predominant use of less environmentally sustainable sodium metasilicate (Na 2 SiO 3) and sodium hydroxide (NaOH) in OPG, along with the limited understanding about the influence of solid alkali activators on OPG's acid resistance propelled the investigation and comparison of acid resistance of OPGs activated using both conventional activators and potential alternatives like sodium aluminate (NaAlO 2) and sodium carbonate (Na 2 CO 3). The OPGs developed were exposed to sulphuric acid (H 2 SO 4) solution for 28 days. The MH sample (activated with Na 2 SiO 3 and NaOH) was vulnerable to acid attack, with a 66% compressive strength drop after 5% H 2 SO 4 solution exposure, due to high sorptivity. In contrast, the MA sample (activated with Na 2 SiO 3 and NaAlO 2) demonstrated excellent acid resistance, with only a 32% strength reduction, attributed to its Al-rich hydrated gel. The MC sample (activated with Na 2 SiO 3 and Na 2 CO 3) exhibited a 41% strength reduction, where the formation of calcite reduced extensive ion exchange, gradually mitigated deterioration. The residual compressive strength of MA and MC samples increased by 7% and 9% from 7 to 28 days of immersion in 5% H 2 SO 4 solution, respectively. The NaAlO 2 and Na 2 CO 3 are potential activators for OPG, serving as alternative construction materials to OPC and traditional geopolymers in acidic environments. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
20. Enhanced adsorptive composite foams for copper (II) removal utilising bio-renewable polyisoprene-functionalised carbon derived from coconut shell waste.
- Author
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Kettum, Wachiraporn, Samart, Chanatip, Chanlek, Narong, Pakawanit, Phakkhananan, Reubroycharoen, Prasert, Guan, Guoqing, Kongparakul, Suwadee, and Kiatkamjornwong, Suda
- Subjects
- *
FOAM , *COPPER , *POLYISOPRENE , *HEVEA , *METAL ions - Abstract
A bio -renewable polyisoprene obtained from Hevea Brasiliensis was used to produce functionalised carbon composite foam as an adsorbent for heavy metal ions. Functionalised carbon materials (C-SO3H, C-COOH, or C-NH2) derived from coconut shell waste were prepared via a hydrothermal treatment. Scanning electron microscopy images showed that the functionalised carbon particles had spherical shapes with rough surfaces. X-ray photoelectron spectroscopy confirmed that the functional groups were successfully functionalised over the carbon surface. The foaming process allowed for the addition of carbon (up to seven parts per hundred of rubber) to the high ammonia natural rubber latex. The composite foams had open pore structures with good dispersion of the functionalised carbon. The foam performance on copper ion adsorption has been investigated with regard to their functional group and adsorption conditions. The carbon foams achieved maximum Cu(II) adsorption at 56.5 mg g foam - 1 for C-SO3H, 55.7 mg g foam - 1 for C-COOH, and 41.9 mg g foam - 1 for C-NH2, and the adsorption behaviour followed a pseudo-second order kinetics model. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
21. Probing local structure of pyrochlore lead zinc niobate with synchrotron x-ray absorption spectroscopy technique.
- Author
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Kanchiang, Kanokwan, Pramchu, Sittichain, Yimnirun, Rattikorn, Pakawanit, Phakkhananan, Ananta, Supon, and Laosiritaworn, Yongyut
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- *
PYROCHLORE , *NIOBATES , *X-ray absorption , *DENSITY functional theory , *PEROVSKITE , *SYNCHROTRONS - Abstract
Local structure of lead zinc niobate (PZN) ceramic, synthesized via B-site oxide precursor route in atmospheric pressure, was investigated using synchrotron x-ray absorption spectroscopy (XAS) technique. The x-ray absorption near-edge structure (XANES) simulation was first carried out. The XANES simulation results indicate that the PZN ceramic is in pyrochlore phase having Zn2+ substituted on Nb5+ site. Afterwards, the extended x-ray absorption fine structure (EXAFS) analysis was performed to extract the bond length information between Zn2+ and its neighboring atoms. From the EXAFS fitting, the bond length between Zn2+ and Pb2+ in the pyrochlore phase was found to be longer than the previously reported bond length in the perovskite phase. Further, with the radial distribution information of Zn2+'s neighboring atoms, the formation energies along the precursor-to-pyrochlore and precursor-to-perovskite reaction paths were calculated using the density functional theory (DFT). The calculated results show that the formation energy of the perovskite phase is noticeably higher than that of the pyrochlore phase, which is influenced by the presence of energetic Pb2+ lone pair, as the perovskite phase has shorter Zn2+ to Pb2+ bonding. This therefore suggests the steric hindrance of Pb2+ lone pair and the mutual interactions between Pb2+ lone pair and Zn2+ are main causes of the instability of lead zinc niobate in the perovskite structure and confirm the efficacy of XAS and DFT analysis in revealing local structural details of complex pyrochlore materials. [ABSTRACT FROM AUTHOR]
- Published
- 2013
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- View/download PDF
22. Multifunctional Nanomaterials Modification of Cellulose Paper for Efficient Triboelectric Nanogenerators.
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Sriphan, Saichon, Charoonsuk, Thitirat, Maluangnont, Tosapol, Pakawanit, Phakkhananan, Rojviriya, Catleya, and Vittayakorn, Naratip
- Subjects
- *
ENERGY harvesting , *CELLULOSE , *TRIBOELECTRICITY , *SYNCHROTRON radiation , *LIGHT emitting diodes , *X-ray photoelectron spectroscopy - Abstract
There is a need to develop inexpensive, lightweight, and flexible high‐performance triboelectric nanogenerators (TENGs) from renewable resources. Here, a multifunctional cellulose filter paper (CFP)‐based TENG consisting of dielectric Ti0.8O2 nanosheets (Ti0.8O2 NSs) and conducting Ag nanoparticles (Ag NPs) is prepared by a simple dip coating method. The incorporation of dielectric Ti0.8O2 NSs onto the CFP significantly improves charge generation, while the inclusion of Ag NPs provides an electrically conductive path for charge transportation. The presence of these fillers can be deduced from XRD, SEM, EDS, X‐ray photoelectron spectroscopy, and Raman spectroscopy. Their distribution is visualized in 3D by synchrotron radiation X‐ray tomography. The present CFP‐based TENG provides an output voltage and current density of ≈42 V and ≈1 µA cm−2, respectively with the power density of ≈25 µW cm−2. It is capable of lighting up 40 light‐emitting diode bulbs and charging a 0.22 µF capacitor to 8 V in only 5 s. The developed TENG is also capable of detecting simple human motions, i.e., finger tapping, finger rubbing, and foot trampling. This work offers a facile design of low cost yet efficient paper‐based TENG by dual modification with multifunctional nanomaterials, and also demonstrates its use as a feasible power source that not only drives small electronics, but also scavenges energy from human actions. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
23. Green development of fly ash geopolymer via casting and pressing Approaches: Strength, Morphology, efflorescence and Ecological Properties.
- Author
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Shee-Ween, Ong, Cheng-Yong, Heah, Yun-Ming, Liew, Mustafa Al Bakri Abdullah, Mohd, Li-Ngee, Ho, Pakawanit, Phakkhananan, Suhaimi Khalid, Mohd, Hazim Bin Wan Muhammad, Wan, Wan-En, Ooi, Yong-Jie, Hang, Yong-Sing, Ng, and Hui-Teng, Ng
- Subjects
- *
FLY ash , *SUSTAINABLE development , *EFFLORESCENCE , *POLYMER-impregnated concrete , *CARBON emissions , *INORGANIC polymers , *FLEXURAL strength - Abstract
[Display omitted] • A study of fly ash based pressed and cast geopolymer was proposed. • Compressive strength of pressed geopolymer nearly twice that of cast geopolymer. • Flexural strength of pressed geopolymer was 5 times higher than cast geopolymer. • The highly compacted pressed geopolymer reduced the tendency of efflorescence. • The low alkali activator of pressing method lowered EE, ECO 2 and ECI of geopolymer. The high liquid content of cast geopolymer not only limits its strength development and durability but also leads to high energy consumption and carbon dioxide (CO 2) emissions. Thus, a study of the cast and pressed geopolymer was performed. The geopolymers were cured for 1, 7 and 28 d before testing and characterizations. With the incorporation of pressure compaction, higher bulk density (2158–2227 kg/m3) was recorded for pressed geopolymer in comparison to cast geopolymer (1842–1854 kg/m3). The dense matrix in pressed geopolymer improved the inter-particle contact, increasing the 28 d degree of reaction to 39.7%, higher than that of cast geopolymer (33.0%). This feature was proved by SEM micrographs wherein the pressed geopolymer was well-compacted and denser in microstructure, with less unreacted/partially reacted fly ash and pores. The compressive and flexural strengths of pressed geopolymer reached 114.2 and 29.9 MPa after 28 d, higher than that of cast geopolymer (60.0 and 6.2 MPa, respectively). The strength reduction of pressed geopolymer (31.7%) after the accelerated efflorescence test was lower than that of cast geopolymer (60.2%). The ecological analysis inferred that pressed geopolymer was ecologically superior to the casting method in terms of embodied energy (EE) and embodied carbon dioxide emission (ECO 2), in which 50% and 59% of reductions are acquired. Besides, the embodied carbon index (ECI) of pressed geopolymer was about 21% of cast geopolymer. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
24. Contact electrification of porous PDMS-nickel ferrite composites for effective energy harvesting.
- Author
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Oh, Wonjeong, Hajra, Sugato, Divya, S., Panda, Swati, Oh, Yumi, Jaglic, Zvonko, Pakawanit, Phakkhananan, Oh, Tae Hwan, and Kim, Hoe Joon
- Subjects
- *
NICKEL ferrite , *MECHANICAL energy , *POWER electronics , *FERRITES , *ELECTRICAL energy , *POROUS materials - Abstract
• NiFe 2 O 4 is synthesized by solid state reaction and flexible PDMS-NFO composite is formed. • The PN12 device produce voltage of 60 V and current of 300 nA. • X-ray tomographic microscopy images of PDMS-NFO composite is illustrated. • Smart home-based energy harvesting in daily life is demonstrated. Energy harvesting technologies are becoming popular owing to their usage in the operation of low-power consumer electronics and as an alternative power source. Specifically, triboelectric nanogenerators (TENGs) have drawn much attention as they can efficiently scavenge waste mechanical energy into electrical output. Careful material selections can further improve the performance of TENGs. In this work, a spinel ferrite material with the chemical formula NiFe 2 O 4 (NFO abbreviated further) is synthesized using a solid-state reaction route. The structural and magnetic property of the NFO has been studied, showing the cubic symmetry and ferromagnetic nature of the sample. The 3D tomography images of the PDMS-NFO composites were carried out using X-ray tomographic microscopy. To enhance the performance of the TENGs, we adopted a porous media by evaporation of water during the curing process of PDMS-NFO composites. A single-electrode operating mode was adopted for TENG fabrication. The electrical response of the device was carried out using different wt% and frequencies. The 12 wt% of NFO in PDMS (PN12 device) delivered a voltage, current, and charge of 60 V, 300 nA, and 34 nC, respectively. The charge density of the plain and porous composite-based TENG was compared to confirm the enhancement of the charge produced on the triboelectric layers. The commercial capacitors and energy harvesting based on a smart home were demonstrated using the TENG devices. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
25. CNTs-added PMNT/PDMS flexible piezoelectric nanocomposite for energy harvesting application.
- Author
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Promsawat, Napatporn, Promsawat, Methee, Janphuang, Phatthanapong, Luo, Zhenhua, Beeby, Steve, Rojviriya, Catleya, Pakawanit, Phakkhananan, and Pojprapai, Soodkhet
- Subjects
- *
CARBON nanotubes , *ENERGY harvesting , *PIEZOELECTRIC materials - Abstract
The flexible piezoelectric nanocomposites based on lead magnesium niobate titanate [Pb(Mg1/3Nb2/3)0.65Ti0.35O3; PMNT] particles in polydimethylsiloxane (PDMS) matrix were fabricated and characterized. PMNT powders are synthesized using the columbite precursor method. PMNT/PDMS flexible nanocomposites are then prepared by spin casting technique, where a small amount of carbon nanotubes (CNTs) is added into the PMNT/PDMS composite to enhance cross-links between PMNT particles and PDMS matrix. The phase and microstructure of the nanocomposite are investigated by using X-ray diffraction and scanning electron microscope (SEM). The electromechanical behavior is evaluated by using an autonomous pneumatic actuator. The flexible composite, occupying approximately 300 mm2, is capable of generating an open-circuit voltage (Voc) of 2.83 ± 0.24 V and a short-circuit current (Isc) signal of 0.33 ± 0.01 µA across 10 Ω resistor under mechanical load of 300 N. The generated electrical charges are 29026 pC. The relative dielectric constant is measured at 10 kHz and found to be 6.76 ± 1.15. The piezoelectric PMNT/PDMS composite can potentially be used in a variety of applications such as wearable sensors, actuators, and energy harvesting for converting kinetic energy into useful electrical energy. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
- View/download PDF
26. Comparison of thermal performance between fly ash geopolymer and fly ash-ladle furnace slag geopolymer.
- Author
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Hui-Teng, Ng, Cheng-Yong, Heah, Yun-Ming, Liew, Abdullah, Mohd Mustafa Al Bakri, Pakawanit, Phakkhananan, Bayuaji, Ridho, Yong-Sing, Ng, Zulkifly, Khairunnisa Binti, Wan-En, Ooi, Yong-Jie, Hang, and Shee-Ween, Ong
- Subjects
- *
FLY ash , *POLYMER-impregnated concrete , *SLAG , *FURNACES , *COMPRESSIVE strength , *THERMAL stability - Abstract
This paper compared the thermal stability between fly ash (FA) and fly ash-ladle furnace slag (FA-LS) geopolymers. FA-LS geopolymer was prepared by mixing FA and LS (FA:LS weight ratio of 80:20) with an alkali activator. Geopolymers were aged at room temperature for 28 days before being exposed to high temperatures (200 °C – 1000 °C). Unexposed FA and FA-LS geopolymers had a compressive strength of 38.9 MPa and 40.5 MPa, respectively. The FA and FA-LS geopolymers retained 61.6% and 91.3% compressive strength, respectively, when exposed to temperatures up to 1000 °C. FA-LS geopolymers experienced smaller variation in the density (2.6 – 5.5%) and pores (17.4 – 23.0%) compared to FA geopolymers (density and porosity of 2.9 – 25.2% and 19.0 – 30.0%, respectively). The formation of crystalline peaks, densification of matrix, pores and their connectivity, cracks and dimensional changes influenced the compressive strength of exposed geopolymers. FA-LS geopolymers could be potentially applied as heat-resistance material. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
27. Influence of pore morphologies on the mechanical and tribo-electrical performance of polydimethylsiloxane sponge fabricated via commercial seasoning templates.
- Author
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Pharino, Utchawadee, Sinsanong, Yoltawan, Pongampai, Satana, Charoonsuk, Thitirat, Pakawanit, Phakkhananan, Sriphan, Saichon, Vittayakorn, Naratip, and Vittayakorn, Wanwilai
- Subjects
- *
POROSITY , *POLYDIMETHYLSILOXANE , *SYNCHROTRON radiation , *WEARABLE technology , *GEOMETRIC shapes , *X-ray microscopy - Abstract
This work demonstrated the influence of pore morphologies on the mechanical behavior and tribo-electrical performance of fabricated polydimethylsiloxane (PDMS) sponge. Commercial seasonings with different 3D geometric shapes were used as a sacrificial template to control the pore structure of the PDMS sponge. The result indicated that the softest PDMS sponge was molded by using a sodium chloride (NaCl) crystal template, as indicated by the lowest compressive modulus value. Then, P(VDF–HFP) was incorporated into PDMS prepolymer in order to enhance the charge generation characteristic of PDMS. Besides, the composite 3D structure was revealed using synchrotron radiation X-ray tomographic microscopy (SRXTM). Interpretation from the SRXTM result confirmed that the porous structure had different pore shapes, i.e. , an octahedral-like shape and a circular-like shape in a particular sponge. By pairing the composite PDMS sponge with an aluminum (Al) plate for the triboelectric nanogenerator (TENG), the maximum electrical outputs of ~29.9 V and ~0.56 μA for voltage and current, respectively, were detected with loading 50 wt% of P(VDF – HFP). The presented TENG was applied successfully for sensing basic human activities practically, which demonstrated potential applications in wearable electronics. • 3D-PDMS sponges were fabricated with various templates. • The composite P(VDF-HFP)/PDMS sponge generated a high triboelectric performance. • In single-electrode TENG mode, the V OC obtained ~40 V with the power of 25 mW. • The present TENG could sense simple human activities efficiently. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
28. Triboelectric-piezoelectric hybrid nanogenerator based on BaTiO3-Nanorods/Chitosan enhanced output performance with self-charge-pumping system.
- Author
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Pongampai, Satana, Charoonsuk, Thitirat, Pinpru, Nattapong, Pulphol, Phieraya, Vittayakorn, Wanwilai, Pakawanit, Phakkhananan, and Vittayakorn, Naratip
- Subjects
- *
ON-chip charge pumps , *TRIBOELECTRICITY , *COMPRESSIVE force , *OPEN-circuit voltage , *BIOPOLYMERS , *SHORT circuits , *POWER density - Abstract
Recent advances in achieving flexible triboelectric nanogenerators (TENGs) focus widely on utilizing and modifying abundant natural biopolymer. Boosting power generation and conversion efficiency continue to prevail. In this work, three main strategies were proposed to enhance the output performance of chitosan-based TENGs; 1) hybridization with lead-free piezoelectric nanorod, 2) introduction of a soft electrode using bacterial cellulose/carbon nanotube composite to enhance contact efficiency, and 3) enhancement of charge density of the triboelectric friction layer using a self-charge pumping (SCP) module. Under the same testing conditions of 48 ± 5% relative humidity, ~ 0.55 Hz of frequency, ~ 250 N of compressive force at 25.0 ± 0.5 °C, and the combination of 7 wt% lead-free piezoelectric BaTiO 3 nanorods (BT-NRs) in the chitosan matrix, the highest open-circuit voltage (V oc) of ~111.4 V, short circuit (I sc) of ~21.6 μA/cm2, and also output power density of 756 μW/cm2 was achieved. By using an integrated SCP module, the TENGs can provide a V oc , I sc and peak power output of 247.2 V, 36.7 μA/cm2 and 1568 μW/cm2, respectively. This electrical power output rises to over 4-fold more power enhancement than that of pristine chitosan TENGs. The TENGs demonstrate remarkable mechanical stability and reliability upon cyclical contact for up to 3000 times. This work provides a promising strategy for achieving high-output, eco-friendly triboelectric nanogenerators. By boosting the output performance via continuous charge pumping, ultrahigh effective charge density was achieved successfully in flexible chitosan/BT-NR biocomposites that can push output performance towards real applications of TENGs. Image 1 [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
29. Impairment of bone microstructure and upregulation of osteoclastogenic markers in spontaneously hypertensive rats.
- Author
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Tiyasatkulkovit, Wacharaporn, Promruk, Worachet, Rojviriya, Catleya, Pakawanit, Phakkhananan, Chaimongkolnukul, Khuanjit, Kengkoom, Kanchana, Teerapornpuntakit, Jarinthorn, Panupinthu, Nattapon, and Charoenphandhu, Narattaphol
- Subjects
- *
MICROSTRUCTURE , *OSTEOCLASTOGENESIS , *LABORATORY rats , *ALKALINE phosphatase , *BONE fractures - Abstract
Hypertension and osteoporosis are the major non-communicable diseases in the elderly worldwide. Although clinical studies reported that hypertensive patients experienced significant bone loss and likelihood of fracture, the causal relationship between hypertension and osteoporosis has been elusive due to other confounding factors associated with these diseases. In this study, spontaneously hypertensive rats (SHR) were used to address this relationship and further explored the biophysical properties and the underlying mechanisms. Long bones of the hind limbs from 18-week-old female SHR were subjected to determination of bone mineral density (BMD) and their mechanical properties. Using synchrotron radiation X-ray tomographic microscopy (SRXTM), femoral heads of SHR displayed marked increase in porosity within trabecular area together with decrease in cortical thickness. The volumetric micro-computed tomography also demonstrated significant decreases in trabecular BMD, cortical thickness and total cross-sectional area of the long bones. These changes also led to susceptibility of the long bones to fracture indicated by marked decreases in yield load, stiffness and maximum load using three-point bending tests. At the cellular mechanism, an increase in the expression of osteoclastogenic markers with decrease in the expression of alkaline phosphatase was found in primary osteoblast-enriched cultures isolated from long bones of these SHR suggesting an imbalance in bone remodeling. Taken together, defective bone mass and strength in hypertensive rats were likely due to excessive bone resorption. Development of novel therapeutic interventions that concomitantly target hypertension and osteoporosis should be helpful in reduction of unwanted outcomes, such as bone fractures, in elderly patients. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
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