Search

Your search keyword '"Popov, Anatolli F."' showing total 1 results
Start Over Author "Popov, Anatolli F."
1 results on '"Popov, Anatolli F."'

1. Bis(dialkylamide)hydrogen dibromobromate precursors of hypobromite ion in reactions with nerve and blister agent simulants

Author

Simanenko, Yuri S., Savelova, Vera A., Prokop'eva, Tatyana M., Mikhailov, Vasily A., Turovskaya, Marya K., Karpichev, Eugen A., Popov, Anatolli F., Gillitt, Nicholas D., and Bunton, Clifford A.

Subjects
Oxidation-reduction reaction -- Analysis, Organosulfur compounds -- Chemical properties, Phosphorylation -- Analysis, Biological sciences, Chemistry
Abstract

Bis(dialkylamide)hydrogen dibromobromate is used as a source of BrO(super -), and is shown that rates of dephosphorylation are similar with BrO(super -) generated from these complexes or from Br2-H2O. Reactions of 4-nitrophenyl tosylate, with BrO(super -) are rapid with 0.1 M BrO(super -), under conditions in which oxidations of organic sulfides are too fast to be followed by conventional methods.

Published
2004

Catalog

Books, media, physical & digital resources
See catalog results