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We study the effect of the addition of p- or n-type doping gases, trimethylboron (TMB) or phosphine, respectively, on cluster formation in the SiH4/H2 plasma used for the deposition of hydrogenated polymorphous silicon thin films. The formation of clusters is monitored using time-resolved measurements of the second harmonic of the radio frequency current J2. We show that the addition of PH3 does not change the cluster formation, while the addition of a small amount of trimethylboron strongly affects its charging behavior, preventing to some extent its agglomeration. The most ordered pm-Si:H thin films are obtained under conditions from which not only clusters but also larger silicon agglomerates are formed in the plasma and contribute to the deposition. The inhibiting role of TMB on the agglomeration and powder formation is evidenced by the smoothness of p-type films at high rates, as deduced from the sample surface topography obtained by atomic force microscopy measurements. [ABSTRACT FROM AUTHOR]

The nanometer-scale (medium range) structural order in hydrogenated polymorphous silicon films is analyzed using fluctuation electron microscopy. The polymorphous growth regime occurs under relatively high gas pressure during plasma-enhanced chemical vapor deposition, such that small aggregates and nanocrystals form in the gas phase and impinge on the film surface. All polymorphous samples appear completely amorphous in diffraction or Raman scattering analyses. In fluctuation microscopy, carried out in the transmission electron microscope, the statistical variance V in the dark field image intensity is acquired as a function of the scattering vector k at a chosen resolution Q. Theory shows that V is quantitatively related to the three- and four-body atomic correlation functions, and thus to the nanometer scale order, in the material. Unlike typical hydrogenated amorphous silicon, the variance V is a strong function of growth conditions and displays a maximum at a silane pressure of 1.4–1.8 Torr. The images also reveal the presence of a small number of unusually bright spots, roughly 5 nm in diameter, only in samples grown at 0.8 and 1.4 Torr; we interpret that these correspond to nanocrystallites. The observation of enhanced structural order as revealed by the variance V is consistent with previous, but less conclusive, analyses of hydrogenated polymorphous silicon. [ABSTRACT FROM AUTHOR]

The unique three-dimensional pore structure of KCC-1 has attracted significant attention and has proven to be different compared to other conventional mesoporous silica such as the MCM-41 family, SBA-15, or even MSN nanoparticles. In this research, we carefully examine the morphology of KCC-1 to define more appropriate nomenclature. We also propose a formation mechanism of KCC-1 based on our experimental evidence. Herein, the KCC-1 morphology was interpreted mainly on the basis of compiling all observation and information taken from SEM and TEM images. Further analysis on TEM images was carried out. The gray value intensity profile was derived from TEM images in order to determine the specific pattern of this unique morphology that is found to be clearly different from that of other types of porous spherical-like morphologies. On the basis of these results, the KCC-1 morphology would be more appropriately reclassified as bicontinuous concentric lamellar morphology. Some physical characteristics such as the origin of emulsion, electrical conductivity, and the local structure of water molecules in the KCC-1 emulsion were disclosed to reveal the formation mechanism of KCC-1. The origin of the KCC-1 emulsion was characterized by the observation of the Tyndall effect, conductometry to determine the critical micelle concentration, and Raman spectroscopy. In addition, the morphological evolution study during KCC-1 synthesis completes the portrait of the formation of mesoporous silica KCC-1. [ABSTRACT FROM AUTHOR]

Abstract: A systematic study has been done on the formation of nanoparticles in silane–methane–hydrogen plasmas and their effect on material properties. By increasing the total pressure we cover three phases of particle growth: nanocrystals nucleation and accumulation, agglomeration, and powder formation. The presence of particles in the plasma is detected from the evolution of the discharge electrical parameters such as the self-bias (V DC) on the radio-frequency electrode and the peak-to-peak RF voltage (V PP). Interestingly, optical emission spectroscopy measurements show that the presence of particles has a strong effect on the hydrogen emission bands. Indeed, while Hα emission is dominant at low pressure in a powder free discharge, the formation of particles leads to an intense H2 Fulcher α band. Moreover the ratio I Fulcher/I Hα provides a clear signature of the transition from nucleation to agglomeration regimes, thus providing an easy way of characterizing the plasma regime. The changes in the deposition regime are also reflected on the film properties, in particular their photoluminescence characteristics. [Copyright &y& Elsevier]

Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m 2 /g. Mesoporous silica KCC-1 has significantly higher number of basicity and oxygen vacancy than those of MCM-41 and SiO 2 which directly correlated with the catalytic performance of the catalyst. The activity of mesoporous silica KCC-1 in CO 2 methanation is five-fold higher than MCM-41 with the yield of CH 4 reached 38.9% at 723 K. [ABSTRACT FROM AUTHOR]

CeO 2 nanoparticles (nanoceria) were proposed as an alternative physical sunscreen agent with antioxidant properties and comparable UV absorption performance. Green synthesis of nanoceria with Ag and Ni dopants resulted in doped nanoceria with lower catalytic activity and biologically-safe characteristics. The doped nanoceria was characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), Rancimat Instrument, and UV-Vis Spectrophotometer for SPF (Sun Protection Factor) determination. XRD and TEM analysis showed that nanoceria had been successfully formed in nanoscale-sized with a change in crystallite size due to the crystal defect phenomenon caused by dopant addition. While the Rancimat test and band gap energy analysis were conducted to evaluate the oxidative stability and reactive oxygen species formation, it was confirmed that dopant addition could decrease catalytic activity of material, resulting in Ni-doped Ce with a longer incubation time (11.81 h) than Ag-doped Ce (10.58 h) and non-doped Ce (10.30 h). In-vitro SPF value was measured using the thin layer technique of sunscreen prototype with Virgin Coconut Oil (VCO)-based emulsion, which yielded 10.862 and 5.728 SPF values for 10% Ag-doped Ce and 10% Ni-doped Ce, respectively. The dopant addition of nanoceria could reduce catalytic activity and give a decent in vitro UV-shielding performance test; thus, Ag and Ni-doped nanoceria could be seen as promising candidates for alternative physical sunscreen agents.

KCC-1, a nanostructured silica material with a bicontinuous concentric lamellar (bcl) morphology, provides plenty of functional characteristics, such as an open channel structure, excellent accessibility, and a large surface area. Although bcl silica exhibits various superior properties, studies on its morphology and its application in dye-sensitized solar cells (DSSCs) are still limited. Therefore, this work aims to study the influence of the synthesis time on the morphology of bcl silica. Moreover, we used the synthesized bcl silica as internal micro-reflectors in DSSCs. The bcl silica was synthesized using the reflux method by varying synthesis times. The morphology of bcl silica was observed using FESEM and HRTEM. FESEM images show that bcl silica has bicontinuous lamellar walls arranged concentrically to form spherical particles. As the synthesis time increases, the average particle size of bcl silica increases. The quantization of bcl silica binary images shows that the average lamellar cross-sectional area ratio decreases with increasing synthesis time. The simulation of the Cahn-Hilliard's spinodal decomposition model using MATLAB also describes the lamellar cross-sectional area ratio of bcl silica. In addition, to characterize the FESEM image's texture, a Shannon entropy calculation was performed. The line and circular gray value intensity profiles of the HRTEM image show that bcl silica has a denser core than the outer part. The denser core proves that the lamellae in bcl silica are concentrically arranged towards the particle core. Furthermore, we added bcl silica to a photoanode to see the effect of bcl characteristics on the DSSC performance. The results show that the bcl silica significantly improves the light-harvesting efficiency in DSSCs due to its low refractive index and open channel structure.

TiO 2 particles with a specific morphology are essential for their accessibility and photoactivity. The present study shows that NH 4 OH-based alkaline-hydrothermal treatment affects the transformation of their particle morphology. We investigated the effect of NH 4 OH by varying the synthesis route. We observed that the TiO 2 particles with an open channel pore structure only resulted in the alkaline-hydrothermally treated and calcined samples. Based on Raman and XRD analyses, we figured out the titanate layers as an intermediate phase resulting from the alkaline-hydrothermal treatment of the amorphous particles. The hydrothermal treatment changed the particle surface morphology into a lamellar structure with a high specific surface area. These are the anatase precursors with {200} planes that transform into the anatase phase after calcination. The calcination followed by alkaline-hydrothermal treatment converted the crystallinity without significantly changing their morphology. We found that the morphology of TiO 2 particles can be modified via hydrothermal treatment using NH 4 OH as long as the particles remain uncrystallized. We suggested the modification of particle morphology through the swelling and phase segregation process by alkaline-hydrothermal treatment. All final products have been used for the photodegradation of rhodamine B. S-HT-500 and A-HT-500 show the best photocatalytic activity with their rate constants ( k ) of 47.9 and 30.9 × 10 -2 min -1 , and their surface area-normalized rate constants ( k sa ) of 6.5 and 2.6 × 10 -3 L m -2 min -1 , respectively, and have a photocatalytic efficiency of 90.93% and 67.78%, respectively, after 10 minutes of UV irradiation. This activity is approximately 3.5 times and 1.5 times higher than that of Degussa P25; 30 times and 20 times higher than that without a photocatalyst.

Poly(3,4-ethylenedioxythiophene) (PEDOT) is a prime example of conducting polymer materials for supercapacitor electrodes that offer ease of processability and sophisticated chemical stability during operation and storage in aqueous environments. Yet, continuous improvement of its electrochemical capacitance and stability upon long cycles remains a major interest in the field, such as developing PEDOT-based composites. This work evaluates the electrochemical performances of hydroxymethyl PEDOT (PEDOTOH) coupled with hydrogel additives, namely poly(ethylene oxide) (PEO), poly(acrylic acid) (PAA), and polyethyleneimine (PEI), fabricated via a single-step electrochemical polymerization method in an aqueous solution. The PEDOTOH/PEO composite exhibits the highest capacitance (195.2 F g -1 ) compared to pristine PEDOTOH (153.9 F g -1 ), PEDOTOH/PAA (129.9 F g -1 ), and PEDOTOH/PEI (142.3 F g -1 ) at a scan rate of 10 mV s -1 . The PEDOTOH/PEO electrodes were then assembled into a symmetrical supercapacitor in an agarose gel. The type of supporting electrolytes and salt concentrations were further examined to identify the optimal agarose-based gel electrolyte. The supercapacitors comprising 2 M agarose-LiClO 4 achieved a specific capacitance of 27.6 F g -1 at a current density of 2 A g -1 , a capacitance retention of ∼94% after 10,000 charge/discharge cycles at 10.6 A g -1 , delivering a maximum energy and power densities of 11.2 Wh kg -1 and 17.28 kW kg -1 , respectively. The performance of the proposed supercapacitor outperformed several reported PEDOT-based supercapacitors, including PEDOT/carbon fiber, PEDOT/CNT, and PEDOT/graphene composites. This study provides insights into the effect of incorporated hydrogel in the PEDOTOH network and the optimal conditions of agarose-based gel electrolytes for high-performance PEDOT-based supercapacitor devices., (© 2022 Wiley-VCH GmbH.)

Aurivillius phase Bi 2 LaNb 1.5 Mn 0.5 O 9 , derived from ferroelectric PbBi 2 Nb 2 O 9 by simultaneous substitution of the A -site and B -site cations, was synthesized using a molten-salt method. Here, we discuss the structure-property relationships in detail. X-ray and neutron diffraction show that Bi 2 LaNb 1.5 Mn 0.5 O 9 adopts an A 2 1 am orthorhombic crystal structure. Rietveld refinement analysis, supported by Raman spectroscopy, indicates that the Bi 3+ ions occupy the bismuth oxide blocks, La 3+ ions occupy the perovskite A -site, and Nb 5+ /Mn 3+ ions occupy the perovskite B -site. Ferroelectric ordering takes place at 535 K, which coexists with local ferromagnetic order below 65 K. The cation disorder on the B -site results in relaxor-ferroelectric behavior, and the short-range ferromagnetic order can be attributed to Mn 3+ /Mn 4+ double-exchange. Magnetodielectric coupling measured at 5 K and 100 kHz in a field of 5 T suggests the existence of intrinsic spin-lattice coupling with a magnetodielectric coefficient of 0.20%. These findings will provide significant impetus for further research into potential devices based on the magnetodielectric effect in Aurivillius materials.

The thermodynamic picture describing the formation mechanism of bicontinuous concentric lamellar ( bcl ) nanostructured silica particles, bcl silica, was investigated thoroughly. A series of classical kinetics of bcl silica by varying the synthesis time were employed to observe the morphological evolution of bcl silica. The formation mechanism of bcl silica is proposed as the hydrolysis and condensation reactions in the reverse micelle, followed by the phase segregation process. The images of the whole part and the cross-section of bcl silica reveal that bcl silica can be obtained just 30 min after the synthesis starts. The particle morphology evolves from bicontinuous lamellar ( bl ) morphology, with the absence of the dense part in the center of the particle, to bicontinuous concentric lamellar ( bcl ) morphology. The theoretical part of this study is focused on the phase segregation process of the mixture. This process is divided thermodynamically into several reversible processes based on the reduced Helmholtz free energy state function. The type of the lamellar orientation (i.e., parallel or perpendicular orientation) changed as the stacked lamellae changed in thickness and was followed by the decrease in the free energy. It was merely shown that the segregation of the thin slab of the lamellar polysiloxane stack favors the perpendicular orientation. In contrast, the thick slab of the lamellar polysiloxane stack yields a complex lamellar structure consisting of perpendicular and parallel orientations. A lamellar polymer confined between two planar substrates can experience a topological transformation into a sphere due to an unfavorable environment, i.e., high surface tension. After the topological transformation, lamellae with a perpendicular orientation form bicontinuous lamellae, whereas the complex lamellar structure transforms into a bicontinuous concentric lamellar morphology.

Disposal of palm oil mill effluent (POME), which is highly polluting from the palm oil industry, needs to be handled properly to minimize the harmful impact on the surrounding environment. Photocatalytic technology is one of the advanced technologies that can be developed due to its low operating costs, as well as being sustainable, renewable, and environmentally friendly. This paper reports on the photocatalytic degradation of palm oil mill effluent (POME) using a BiVO 4 photocatalyst under UV-visible light irradiation. BiVO 4 photocatalysts were synthesized via sol-gel method and their physical and chemical properties were characterized using several characterization tools including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), surface area analysis using the BET method, Raman spectroscopy, electron paramagnetic resonance (EPR), and UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS). The effect of calcination temperature on the properties and photocatalytic performance for POME degradation using BiVO 4 photocatalyst was also studied. XRD characterization data show a phase transformation of BiVO 4 from tetragonal to monoclinic phase at a temperature of 450 °C (BV-450). The defect site comprising of vanadium vacancy (V v ) was generated through calcination under air and maxima at the BV-450 sample and proposed as the origin of the highest reaction rate constant ( k ) of photocatalytic POME removal among various calcination temperature treatments with a k value of 1.04 × 10 -3 min -1 . These findings provide design guidelines to develop efficient BiVO 4 -based photocatalyst through defect engineering for potential scalable photocatalytic organic pollutant degradation.

It is essential to realize a Raman measurement technique without artifact or fluorescence signals for high-quality and reliable data in a valid molecular-level analysis and interpretation. This requirement applies especially to a molecule with strong fluorescence like porphyrin. Here, the surface of a gold substrate performs better as a DCDR substrate for tetraphenylporphyrin than other surfaces, such as tantalum, indium tin oxide glass, or aluminium. Polarized Raman spectra of tetraphenylporphyrin demonstrated the oriented deposition of porphyrin crystallites on the Au substrate using the drop coating technique. The emission anisotropy suggests that the deposited crystallites are arranged outward radially with the porphyrin ring orientation. The orientation is signed by the NHHN axis that is parallel to the radial vector along the X-axis. Moreover, it also demonstrates high chemical stability after preservation and repeated measurements. The Raman signal on a gold substrate is enhanced more than on other substrates beyond mere preconcentration of analytes or the coffee-ring effect only, which might be due to the contribution of the SERRS effect. This effect will be discussed based on the interactions among localized surface plasmons, vibronic transitions, and Raman active vibrational modes.

Palm oil has fulfilled most of the oil needs in the food sector in the world. However, palm oil is indicated to contain small amounts of compounds that are harmful to humans, especially to infants. These toxic contaminants are 3-monochloropropanediol (3-MCPD) esters and glycidyl esters (GE), which are formed during the deodorization of palm oil at high temperatures. This study aims to reduce the 3-MCPD ester concentration in refined, bleached, and deodorized palm oil (RBDPO) through adsorption using activated carbon. The activated carbons were treated with heat and acid-washing using HCl at various concentrations and were characterized. The treatment altered the physicochemical characteristics of the activated carbon (surface area, pore volume, pH PZC , and CEC), resulting in the enhancement of its adsorption characteristics (adsorption capacity). The activated carbon treated with 2 N HCl (AC 2 N) was chosen as the proper adsorbent, due to better surface area, better pore volume, highest CEC value, and better positive charge in RBDPO. The 3-MCPD and GE adsorption capacity of AC 2 N was 1.48 mg g -1 and 29.68 mg g -1 , respectively. The adsorption ability of pretreated activated carbon towards 3-MCPD esters was examined in a batch system at various adsorption temperatures. The 3-MCPD ester concentration in RBDPO was successfully reduced by up to 80% at 35 °C using the activated carbon treated with 2 N HCl solution. On the other hand, the activated carbon was able to reduce the other contaminant of GE in RBDPO up to 97% from the initial concentration of GE., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Polyaniline (PANI) is a conductive polymer that has been studied intensively due to its high conductivity, ease of synthesis, fascinating doping mechanism, and a broad spectrum of applications. Polyaniline doped HCl was synthesized by a common direct-oxidation method of aniline using ammonium persulfate as the oxidant in HCl solution at various temperatures. This study focused on conductivity alteration of PANI-ES (emeraldine salt) due to the interchain interaction observed at different reaction temperatures from room temperature down to -15 °C. The molecular structure of PANI-ES was determined by FTIR and Raman spectroscopy. At low reaction temperature, the electronic transport properties improve significantly as reflected by its conductivity. X-ray diffraction (XRD) analysis shows that the value d {(110)} and β play an important role in electron transport through face-to-face and side-to-side interactions, respectively. Scanning electron microscopy (SEM) analysis shows that the morphology of the synthesized PANI-ES consists of granules that are interconnected by nanofibers. Here, the correlation between electronic transport properties, structure, and morphology induced by reaction temperature was analyzed and discussed in detail. Moreover, PANI ES synthesized at 0 °C was applied as an electrocatalytic active layer in the DSSC's counter-electrode with a promising result.

Present-day science indicates that developing sensors with excellent sensitivity and selectivity for detecting early signs of diseases is highly desirable. Electrochemical sensors offer a method for detecting diseases that are simpler, faster, and more accurate than conventional laboratory analysis methods. Primarily, exploiting non-noble-metal nanomaterials with excellent conductivity and large surface area is still an area of active research due to its highly sensitive and selective catalysts for electrochemical detection in enzyme-free sensors. In this research, we successfully fabricate Metal-Organic Framework (MOF) FeBDC-derived Fe 3 O 4 for non-enzymatic electrochemical detection of glucose. FeBDC synthesis was carried out using the solvothermal method. FeCl 2 .4H 2 O and Benzene-1,4-dicarboxylic acid (H 2 BDC) are used as precursors to form FeBDC. The materials were further characterized utilizing X-ray Powder Diffraction (XRD), Scanning Electron Microscopy (SEM), and Fourier-Transform Infrared Spectroscopy (FTIR). The resulting MOF yields good crystallinity and micro-rod like morphology. Electrochemical properties were tested using Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV) with a 0.1 M of Phosphate Buffer Saline (PBS pH 7.4) solution as the supporting electrolyte. The measurement results show the reduction and oxidation peaks in the CV curve of FeBDC, as well as Fe 3 O 4 . Pyrolysis of FeBDC to Fe 3 O 4 increases the peak of oxidation and reduction currents. The Fe 3 O 4 sample obtained has a sensitivity of 4.67 µA mM -1 .cm -2 , a linear range between 0.0 to 9.0 mM, and a glucose detection limit of 15.70 µM.

Banana is very important for both food and economic securities in many tropical and subtropical countries, because of its nutritional values. However, banana fruit is a climacteric fruit which has short shelf life, so an alternative method to delay its ripening is needed. Our group has used carrageenan as an edible coating to delay banana fruit ripening. In this study, the effect of different concentrations of carrageenan and storage temperatures on Cavendish banana shelf life and fruit quality was evaluated. The fruits were treated with 0.5%, 1.0%, and 1.5% carrageenan and stored at two different temperatures, 26°C and 20°C. Carrageenan functional groups in banana peel samples as well as changes in surface structure of banana peel, color, weight loss, pulp to peel ratio, total soluble solid, and levels of MaACS1 and MaACO1 gene expression were analyzed. Result showed that the optimum condition to extend shelf life and maintain fruit quality was by treating the banana fruits with 1.5% carrageenan and storing them at a cool temperature (20°C). In addition, the result obtained from this study suggested that carrageenan can be used as edible coating to extend the shelf life of banana fruits ( Musa acuminata AAA group)., Competing Interests: The authors declare that there are no conflicts of interest regarding the publication of this paper., (Copyright © 2020 Fenny Martha Dwivany et al.)

Investigation into the solid-state transition among drug polymorphs has been more intense lately. Many factors induce the transformation of polymorphs during manufacturing processes. Efavirenz (EFV), an AIDS therapy drug, has more than 23 polymorphs, but very little information has been reported on them. This study aimed to perform a characterisation of EFV polymorph properties and to predict the kinetics and mechanism of the polymorphic transformation of EFV during manufacturing processes. The bimorphism study was conducted by Differential Scanning Calorimetry (DSC) thermal analysis. The phase transition kinetics of the polymorphs was monitored by X-ray powder diffraction and the quantification of concomitant polymorphs was examined using Rietveld refinement with MAUD ver. 2.7 as a software aid. To predict the solid-state transition, correlation coefficients of solid-state kinetic models were fitted to the experimental data. The results show that Form I and Form II of EFV were thermodynamically shown to be monotropy related. By fitting the experimental data, it was found that isothermal treatment had the best model fit with the phase boundary reaction in the two-dimensional model (G2). Accordingly, by employing mechanical treatment (grinding), it was predicted that the transition mechanism is a second-ordered reaction (R2). The activation energy of the transition during isothermal treatment calculated by the Arrhenius plot was found to be 23.051 kJ mol -1 ; the half-lif of Form II at ambient temperature was 428.05 min (~7.1 h)., (© 2020 The Author(s).)

The confinement energy of electrons in an aromatic molecule was studied by indirect and direct methods, namely, temperature-dependent photoluminescence (TDPL) spectroscopy and scanning tunneling microscopy (STM). We observed a decrease in the tetraphenylporphyrin (H 2 TPP) PL intensity with increasing temperature. The increase in temperature provides kinetic energy for the electrons to overcome the confinement energy barrier, making recombination via nonradiative pathways more favorable. The results of fitting the integrated TDPL intensity with a modified Arrhenius equation suggest two confinement energy values. We propose that these energy values are related to the size of the delocalized electron cloud along the plane and thickness of the H 2 TPP ring. These values quantitatively express an abstract form of the size of the aromatic ring system. These results are in good agreement with the topography images of single H 2 TPP molecules and monolayer H 2 TPP obtained by a direct probing method using STM. These results are also supported by the porphyrin ring orientation relative to the excited crystal face during the TDPL measurements.

One of the emerging challenges in tackling environmental issues is to treat electronic waste, with fast-growing battery waste as a notable threat to the environment. Proper recycling processes, particularly the conversion of waste to useful & value-added materials, are of great importance but not readily available. In this work, we report a facile and fast production of graphene from graphite extracted from spent Zn-C batteries. The graphene flakes are produced by electrochemically exfoliating graphite under varying DC voltages in poly(sodium 4-styrenesulfonate) (PSS) solution of different concentrations. The exfoliation takes place via the insertion of PSS into the interlayers of graphite to form C-S bonds as confirmed by FTIR and XPS studies. Under an applied voltage of 5 V and in 0.5 M PSS, high quality graphene flakes are obtained in a good yield, giving an I D / I G ratio of about 0.86 in Raman spectroscopy. The transparent conductive film prepared from the dispersion of high quality graphene flakes shows great promise due to its low sheet resistance ( R s ) of 1.1 kΩ sq -1 and high transmittance of 89%. This work illustrates an effective and low-cost method to realize large scale production of graphene from electronic waste., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)