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1. Base-free regio- and stereoselective photochemical synthesis of enol ethers from 1,3-dicarbonyl compounds.

Author

Zhu, Keyong, Yu, Wen-Jing, Zhou, Xinlong, Xu, Chaogui, Zhao, Guanzhen, Chai, Yun, Li, Shi-Jun, Xu, Yuanqing, and Li, Pan

Subjects
*ETHER synthesis, *ENOL ethers, *CYCLIC ethers, *CYCLIC compounds
Abstract

A visible light-induced kinetic controlled regioselective O-alkylation of various 1,3-dicarbonyl compounds with diazoacetates and cyclic ethers has been developed. The protocol provides a green and practical approach to highly stereoselective enol ethers under mild and base-free conditions in good to excellent yields. [ABSTRACT FROM AUTHOR]

Published
2023
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