1. Layered nanocomposites by shear-flow-induced alignment of nanosheets
- Author
-
Zhao, Chuangqi, Zhang, Pengchao, Zhou, Jiajia, Qi, Shuanhu, Yamauchi, Yoshihiro, Shi, Ruirui, and Fang, Ruochen
- Subjects
Shear flow -- Influence -- Usage -- Analysis -- Mechanical properties ,Nanotechnology -- Analysis -- Usage -- Mechanical properties ,Layer structure (Solids) -- Analysis -- Usage -- Mechanical properties ,Environmental issues ,Science and technology ,Zoology and wildlife conservation - Abstract
Biological materials, such as bones, teeth and mollusc shells, are well known for their excellent strength, modulus and toughness.sup.1-3. Such properties are attributed to the elaborate layered microstructure of inorganic reinforcing nanofillers, especially two-dimensional nanosheets or nanoplatelets, within a ductile organic matrix.sup.4-6. Inspired by these biological structures, several assembly strategies--including layer-by-layer.sup.4,7,8, casting.sup.9,10, vacuum filtration.sup.11-13 and use of magnetic fields.sup.14,15--have been used to develop layered nanocomposites. However, how to produce ultrastrong layered nanocomposites in a universal, viable and scalable manner remains an open issue. Here we present a strategy to produce nanocomposites with highly ordered layered structures using shear-flow-induced alignment of two-dimensional nanosheets at an immiscible hydrogel/oil interface. For example, nanocomposites based on nanosheets of graphene oxide and clay exhibit a tensile strength of up to 1,215 [plus or minus] 80 megapascals and a Young's modulus of 198.8 [plus or minus] 6.5 gigapascals, which are 9.0 and 2.8 times higher, respectively, than those of natural nacre (mother of pearl). When nanosheets of clay are used, the toughness of the resulting nanocomposite can reach 36.7 [plus or minus] 3.0 megajoules per cubic metre, which is 20.4 times higher than that of natural nacre; meanwhile, the tensile strength is 1,195 [plus or minus] 60 megapascals. Quantitative analysis indicates that the well aligned nanosheets form a critical interphase, and this results in the observed mechanical properties. We consider that our strategy, which could be readily extended to align a variety of two-dimensional nanofillers, could be applied to a wide range of structural composites and lead to the development of high-performance composites. Layered nanocomposites fabricated using a continuous and scalable process achieve properties exceeding those of natural nacre, the result of stiffened matrix polymer chains confined between highly aligned nanosheets., Author(s): Chuangqi Zhao [sup.1] , Pengchao Zhang [sup.1] , Jiajia Zhou [sup.1] [sup.2] , Shuanhu Qi [sup.1] [sup.2] , Yoshihiro Yamauchi [sup.3] , Ruirui Shi [sup.1] , Ruochen Fang [sup.1] [...]
- Published
- 2020
- Full Text
- View/download PDF