Chemical conversions of free phytosterols during the bleaching of corn oil.

[Display omitted] • Phytosterols found in oils have health benefit, but bleaching removes them. • Higher processing times and temperatures increase free phytosterol degradation. • Air and activated clay also promote phytosterol loss. • FPs adsorbed at acidic activated sites are also degraded. • These findings may help develop healthier and more nutritious oils. Phytosterols have health benefits; however, they are partially removed during the bleaching of corn oil. We evaluated the chemical conversion of free phytosterols (FPs) during bleaching. FP degradation accelerated with increased time and temperature, following a first-order kinetic model. In the n -heptane system, air and activated clay promoted the chemical conversion of the FPs. Sterenes formation was analysed under different conditions using a zero-order kinetic model. The apparent activation energies revealed sterene formation decreasing in the following order: campesta-3,5-diene ≈ stigmasta-3,5,22-triene > stigmasta-3,5-diene. Isomers of the above were not detected, indicating that these sterenes were the only primary products of FPs. The desorption test indicated that the FP loss from corn oil was not only due to FPs being adsorbed the activated clay, but also FPs adsorbed at acidic activated sites being degraded. This study presents a vital scientific foundation for retaining FPs to develop healthier and more nutritious oils. [ABSTRACT FROM AUTHOR]