Brewers' spent grain extract as antioxidants in starch‐based active biopolymers.

Summary: Brewer's spent grain (BSG) is a by‐product of the brewery and represents a sustainable alternative for application in starch‐based active materials. This study aimed to develop starch/poly(vinyl alcohol) films containing BSG extract, with focus on the influence of BSG on the mechanical, structural, and barrier properties of the films. The antioxidant potentials of the extract and the films were proved by ABTS●+ (IC50 = 2.0 ± 0.6 μg mL−1) and DPPH● (IC50 = 196.05 ± 018.66 μg mL−1) assays. The addition of BSG extract did not have a significant impact on the mechanical performance and weight loss in water of the materials. The incorporation of the extract resulted in a rough surface, without pores and/or cracks. Controlled release of phenolic compounds was observed for BSG3 (3 g.100 g−1 of BSG extract) (163.3 ± 20.9 mgGAE.mL−1) and BSG5 (5 g.100 g−1 of BSG extract) (165.7 ± 23.6 mgGAE.mL−1) over a 4 h period. Therefore, this study shows the potential of BSG as an organic source of antioxidants for active biopolymers. [ABSTRACT FROM AUTHOR]