1. Ga-doping effects on electrical and luminescent properties of ZnO:(La,Eu)OF red phosphor thin films.
- Author
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Fujihara, Shinobu, Suzuki, Akira, and KIMURA, Toshio
- Subjects
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THIN films , *PHOSPHORS , *ZINC oxide , *LOW temperatures - Abstract
Red thin-film phosphors were fabricated based on a ZnO:(La,Eu)OF nanocomposite structure where (La,Eu)OF nanoparticles were dispersed in a ZnO film matrix. The films were deposited on glass substrates by a sol-gel method at a low temperature of 600 °C using trifluoroacetic acid as a fluorine source. Doping gallium into the films suppressed the grain growth of ZnO, increased the optical band gap, and decreased electrical resistivity, which indicates that Ga[SUP3+] was selectively incorporated into the ZnO lattice. Eu[SUP3+] was practically doped in the LaOF lattice. As a result, strong red emissions due to the [SUP5]D[SUB0] → [SUP7]F[SUB2] transition of Eu[SUP3+] were observed in both photo- (PL) and cathodoluminescence (CL) measurements. The efficiency of ultraviolet light excitation at 274 nm was promoted by the charge transfer from O[SUP2-] to Eu[SUP3+] in PL. Ga doping was found to increase the CL intensity of the film, which was attributed to suppression of charge accumulation on the films. [ABSTRACT FROM AUTHOR]
- Published
- 2003
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