235 results on '"Rauchfuss, Thomas B."'
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2. Crystal Structure of the [FeFe]-Hydrogenase Maturase HydE Bound to Complex‑B
3. Radical SAM Enzyme HydE Generates Adenosylated Fe(I) Intermediates En Route to the [FeFe]-Hydrogenase Catalytic H‑Cluster
4. Homoleptic Rhodium Pyridine Complexes for Catalytic Hydrogen Oxidation
5. Vibrational Perturbation of the [FeFe] Hydrogenase H-Cluster Revealed by 13C2H-ADT Labeling
6. Structural chemistry of 'Defect' cyanometalate boxes: {Cs subset [CpCo(CN)3] (sub 4) [Cp*Ru] (sub 3)} and {M subset [Cp*Rh(CN)3] (sub 4) [Cp*Ru] (sub 3)} (M = NH4, Cs)
7. Synthetic and structural studies on [Fe2(SR)(Sub 2)(CN)(Sub x)(CO)(Sub 6-x)](Super x-) as active site models for Fe-only hydrogenases
8. The N-H...S hydrogen bond in (TACN)2Fe2S6 and in model systems involving the Persulfido moiety: An ab initio and DFT study
9. Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates
10. Binding of alkenes to ReS4-
11. Alkali metal-templated assembly of cyanometalate 'boxes' (NEt4)3(M(Cp*Rh(CN)3)4(Mo(CO)3)4) (M = K, Cs). Selective binding of Cs+
12. Studies on the electroactive heterocycles C(sub6)S(sub8)(super0/2-) and C(sub6)S(sub6)O(sub2)(super0/2-) and related metal complexes
13. Functionalization of Cp4Fe4(CO)4: contrasts and comparisons with ferrocene
14. Homoleptic Rhodium Pyridine Complexes for Catalytic Hydrogen Oxidation.
15. Mobile metal-metal bonds: studies on mixed valence Ir3 and Ir4 clusters
16. Arene vs thiophene reduction in the system (C6R6)Ru(C4R4S)2+ and the protonation of eta4-thiophene ligands
17. Base hydrolysis of coordinated thiophene in (C5R5)Rh(C4Me4S)2+: nucleophilic attack at divalent sulfur and the reversible cleavage of C-S bonds
18. Redistribution of reduced thiophene ligands in the conversion of (C5R5)Rh(eta4-C4Me4S) to ((C5R5)Rh)3(eta4,eta1-C4Me4S)2
19. Vibrational Perturbation of the [FeFe] Hydrogenase H‑Cluster Revealed by 13C2H‑ADT Labeling.
20. Reaction Coordinate Leading to H2Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory
21. Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory
22. Role of the azadithiolate cofactor in models for [FeFe]-hydrogenase: novel structures and catalytic implications
23. Iron acyl thiolato carbonyls: structural models for the active site of the [Fe]-hydrogenase (Hmd)
24. Hydride-containing models for the active site of the nickel-iron hydrogenases
25. Nickel-iron dithiolato hydrides relevant to the [NiFe]-hydrogenase active site
26. Proton-assisted activation of dihydrogen: mechanistic aspects of proton-catalyzed addition of [H.sub.2] to Ru and Ir amido complexes
27. Aza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases
28. Redox-switched oxidation of dihydrogen using a non-innocent ligand
29. Homogeneous catalytic reduction of dioxygen using transfer hydrogenation catalysts
30. Redox-switched complexation/decomplexation of [K.sup.+] and [Cs.sup.+] by molecular cyanometalate boxes
31. Proton-induced Lewis acidity of unsaturated iridium amides
32. Diferrous cyanides as models for the Fe-only hydrogenases
33. Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy
34. [Fe2(SR)(sub 2)(mu-CO)(CNMe)(sub 6)](super 2+) and analogues: A new class of diiron dithiolates as structural models for the H(sub ox)(super Air) state of the Fe-only hydrogenase
35. Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates
36. Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides
37. Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory.
38. Spectroscopic Investigations of [FeFe] Hydrogenase Maturated with [57Fe2(adt)(CN)2(CO)4]2–
39. Characterization of a diferrous terminal hydride mechanistically relevant to the Fe-only hydrogenases
40. Dihydrogen activation by a diruthenium analogue of the Fe-only hydrogenase active site
41. Iron carbonyl sulfides, formaldehydes, and amines condense to give the proposed azadithiolate cofactor of the Fe-only hydrogenases
42. Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate
43. Heterolytic and homolytic activation of dihydrogen at an unusual iridium (II) sulfide
44. The influence of cyanide on the carbonylation of iron(II): synthesis of Fe-SR-CN-CO centers related to the hydrogenase active sites
45. Protonation of Nickel–Iron Hydrogenase Models Proceeds after Isomerization at Nickel
46. New Reactions of Terminal Hydrides on a Diiron Dithiolate
47. First generation analogues of the binuclear site in the Fe-only hydrogenases: Fe2(mu-SR)2(CO)4(CN)2(super 2-)
48. Synthesis, structure, and reactivity of a remarkable iron sulfide: (TACN)2Fe2S6
49. Solvatothermal routes to poly(carbon monosulfide)s using kinetically stabilized precursors
50. Addition of alkynes and alkenes to ReS4-: reactivity akin to OsO4
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