Search

Biochar is of great importance to realizing solid biowastes reduction and environmental remediation. Modifying biochar for better performance is also of great concern to achieve property improvement. P-doped biochar from soybean straw is prepared for multistage utilization to realize water pollutant removal and biofuel usage. The results suggest that the prepared biochar is adequate for sulfadiazine adsorption and has stable performance under coexisting ions and aquatic pH. Furthermore, the higher heating value of the biochar is close to coal and thus can be an alternative to fossil fuel. The maximum sulfadiazine adsorption amount of P-doped biochar is 252.24 mg·g- 1 , and the P-doped biochar HHV is 24 MJ·kg -1 which can be an alternative to coal. The greenhouse gas and pollutant emission potential are also considered to explore the environmental impact of P-doped biochar production and usage. Overall, the optimal ratio of soybean straw: K 3 PO 4 is 3:1., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Pine wastes, including pine needles, cones, and wood, are abundantly produced as an agroforestry by-product globally and have shown tremendous potential for biochar production. Various thermochemical conversion technologies have exhibited promising results in converting pine wastes to biochar, displaying impressive performance. Hence, this review paper aims to investigate the possibilities and recent technological advancements for synthesizing biochar from pine waste. Furthermore, it explores techniques for enhancing the properties of biochar and its integrated applications in various fields, such as soil and water remediation, carbon sequestration, battery capacitor synthesis, and bio-coal production. Finally, the paper sheds light on the limitations of current strategies, emphasizing the need for further research and study to address the challenges in pine waste-based biochar synthesis. By promoting sustainable and effective utilization of pine wastes, this review contributes to environmental conservation and resource management., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Biochar, a carbon-rich and por ous material derived from waste biomass resources, has demonstrated tremendous potential in wastewater treatment. Torrefaction technology offers a favorable low-temperature biochar production method, and torrefied biochar can be used not only as a solid biofuel but also as a pollutant adsorbent. This review compares torrefaction technology with other thermochemical processes and discusses recent advancements in torrefaction techniques. Additionally, the applications of torrefied biochar in wastewater treatment (dyes, oil spills, heavy metals, and emerging pollutants) are comprehensively explored. Many studies have shown that high productivity, high survival of oxygen-containing functional groups, low temperature, and low energy consumption of dried biochar production make it attractive as an adsorbent for wastewater treatment. Moreover, used biochar's treatment, reuse, and safe disposal are introduced, providing valuable insights and contributions to developing sustainable environmental remediation strategies by biochar., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The biorefining process of lignocellulosic biomass has recently emerged as one of the most profitable biofuel production options. However, pretreatment is required to improve the recalcitrant lignocellulose's enzymatic conversion efficiency. Among biomass pretreatment methods, the steam explosion is an eco-friendly, inexpensive, and effective approach to pretreating biomass, significantly promoting biofuel production efficiency and yield. This review paper critically presents the steam explosion's reaction mechanism and technological characteristics for lignocellulosic biomass pretreatment. Indeed, the principles of steam explosion technology for lignocellulosic biomass pretreatment were scrutinized. Moreover, the impacts of process factors on pretreatment efficiency and sugar recovery for the following biofuel production were also discussed in detail. Finally, the limitations and prospects of steam explosion pretreatment were mentioned. Generally, steam explosion technology applications could bring great potential in pretreating biomass, although deeper studies are needed to deploy this method on industrial scales., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

This study performs the comparative advantage analysis of oxidative torrefaction of corn stalks to investigate the advantages of oxidative torrefaction for biochar fuel property upgrading. The obtained results indicate that oxidative torrefaction is more efficient in realizing mass loss and energy density improvement, as well as elemental carbon accumulation and surface functional groups removal, and thus leads to a better fuel property. The maximum values of relative mass loss, higher heating value, enhancement factor, and energy yield are 3.00, 1.10, 1.03, and 0.87, respectively. The relative elemental carbon, hydrogen, and oxygen content ranges are 1.30-3.10, 1.50-3.30, and 2.00-6.80, respectively. In addition, an excellent linear distribution is obtained between the comprehensive pyrolysis index and torrefaction severity index, with elemental carbon and oxygen component variation stemming from pyrolysis performance correlating to the elemental component and valance., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, biochar produced from sunflower seeds husk was activated through ZnCl 2 to support the NiCo 2 O 4 nanoparticles (NiCo 2 O 4 @ZSF) in catalytic activation of peroxymonosulfate (PMS) toward tetracycline (TC) removal from aqueous solution. The good dispersion of NiCo 2 O 4 NPs on the ZSF surface provided sufficient active sites and abundant functional groups for the adsorption and catalytic reaction. The NiCo 2 O 4 @ZSF activating PMS showed high removal efficiency up to 99% after 30 min under optimal condition ([NiCo 2 O 4 @ZSF] = 25 mg L -1 , [PMS] = 0.04 mM, [TC] = 0.02 mM and pH = 7). The catalyst also exhibited good adsorption performance with a maximum adsorption capacity of 322.58 mg g -1 . Sulfate radicals (SO 4 •- ), superoxide radical (O 2 •-), and singlet oxygen ( 1 O 2 ) played a decisive role in the NiCo 2 O 4 @ZSF/PMS system. In conclusion, our research elucidated the production of highly efficient carbon-based catalysts for environmental remediation, and also emphasized the potential application of NiCo 2 O 4 doped biochar., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Microalgae are currently not viable as solid biofuels owing to their poor raw fuel properties. Torrefaction under oxidative media offers a cost-effective and energy-efficient process to address these drawbacks. A design of experiment was conducted using central composite design with three factors: temperature (200, 250, and 300 °C), time (10, 35, and 60 min), and O 2 concentration (3, 12, and 21 vol%). The responses were solid yield, energy yield, higher heating value, and onset temperatures at 50% and 90% carbon conversion determined from thermogravimetric analysis. Temperature and time significantly affected all responses, while O 2 concentration only affected higher heating value, energy yield and thermodegradation temperature at 90% conversion. Oxidative torrefaction of microalgae is recommended to be conducted at 200 °C, 10.6 min, 12% O 2 where the energy yield and enhancement factor are 98.73% and 1.08, respectively. It is also more reactive under an air environment compared to inert torrefaction conditions., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, Aurantiochytrium sp. CJ6 was cultivated heterotrophically on a waste resource, sorghum distillery residue (SDR) hydrolysate without adding any nitrogen sources. Mild sulfuric acid treatment released sugars that supported the growth of CJ6. Optimal operating parameters (salinity, 2.5%; pH, 7.5; with light exposure) determined using batch cultivation attained biomass concentration and astaxanthin content of 3.72 g/L and 69.32 µg/g dry cell weight (DCW), respectively. Using continuous-feeding fed-batch (CF-FB) fermentation, the biomass concentration of CJ6 increased to 6.3 g/L with biomass productivity and sugar utilization rate of 0.286 mg/L/d and 1.26 g/L/d, respectively. Meanwhile, CJ6 obtained maximum astaxanthin content (93.9 µg/g DCW) and astaxanthin concentration (0.565 mg/L) after 20-day cultivation. Thus, the CF-FB fermentation strategy seems to have a high potential for the cultivation of thraustochytrids to produce the high-value product (astaxanthin) using SDR as the feedstock to achieve circular economy., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Microalgae have great potential in producing energy-dense and valuable products via thermochemical processes. Therefore, producing alternative bio-oil to fossil fuel from microalgae has rapidly gained popularity due to its environmentally friendly process and elevated productivity. This current work aims to review comprehensively the microalgae bio-oil production using pyrolysis and hydrothermal liquefaction. In addition, core mechanisms of pyrolysis and hydrothermal liquefaction process for microalgae were scrutinized, showing that the presence of lipids and proteins could contribute to forming a large amount of compounds containing O and N elements in bio-oil. However, applying proper catalysts and advanced technologies for the two aforementioned approaches could improve the quality, heating value, and yield of microalgae bio-oil. In general, microalgae bio-oil produced under optimal conditions could have 46 MJ/kg heating value and 60% yield, indicating that microalgae bio-oil could become a promising alternative fuel for transportation and power generation., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, sunflower seed husk biochar prepared by ZnCl 2 -activated and hydrothermal carbonization (HZSF) was studied for its effectiveness in removing tetracycline (TC) from an aqueous solution. The physical and chemical properties of materials were characterized by different methods of surface analysis. The specific surface area of HZSF is significantly enhanced over 1200 times compared with non-modified biochar (HZSF: 1578.3 m 2 ·g -1 , SF-700: 1.3 m 2 ·g -1 ), which has an enhancement effect on the TC adsorption capacity. The HZSF showed that the Langmuir isotherm and pseudo-second-order kinetic models could properly characterize the adsorption processes. In the Langmuir isotherm model, HZSF exhibited effective adsorption performance with q max of 673.0 mg·g -1 at 298 K for 24 h. The possible mechanisms for the adsorption process were the monolayer, chemical adsorption, and the participation of strong intermolecular forces. In general, HZSF has the potential to be a useful adsorbent for the elimination of antibiotics from water-based solutions., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Air gasification of the Wood-Plastic Composite (WPC) was performed over Ni-loaded HZSM-5 catalysts to generate H 2 -rich gas. Increasing SiO 2 /Al 2 O 3 ratio (SAR) of HZSM-5 adversely affected catalytic activity, where the highest gas yield (51.38 wt%) and H 2 selectivity (27.01 vol%) were acquired using 20 %Ni/HZSM-5(30) than those produced over 20 %Ni/HZSM-5(80) and 20 %Ni/HZSM-5(280). Reducing SAR was also favorably conducive to increasing the acyclic at the expense of cyclic compounds in oil products. These phenomena are attributed to enhanced acid strength and Ni dispersion of 20 %Ni/HZSM-5(30) catalyst. Moreover, catalytic activity in the terms of gas yield and H 2 selectivity enhanced with growing Ni loading to 20 %. Also, the addition of promoters (Cu and Ca) to 20 %Ni/HZSM-5(30) boosted the catalytic efficiency for H 2 -rich gas generation. Raising temperature indicated a positive relevance with the gas yield and H 2 selectivity. WPC valorization via gasification technology would be an outstanding outlook in the terms of a waste-to-energy platform., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In recent years, the unnecessary overuse of antibiotics has increased globally, resulting in antibiotic contamination of water, which has become a significant environmental concern. This study aims to examine the adsorption behavior of antibiotics (Tetracycline TC, Ciprofloxacin CIP, Ibuprofen IBP, and Sulfamethoxazole SMX) onto H 3 PO 4 -activated sunflower seed husk biochar (PSF). The results demonstrated that H 3 PO 4 could enhance the specific surface area (378.8 m 2 /g) and create a mesoporous structure of biochar. The adsorption mechanism was investigated using kinetic models, isotherms, and thermodynamics. The maximum adsorption capacities (q max ) of TC, CIP, SMX, and IBP are 429.3, 361.6, 251.3, and 251.1 mg g -1 , respectively. The adsorption mechanism of antibiotics on PSF was governed by complex mechanisms, including chemisorption, external diffusion, and intraparticle diffusion. This research provides an environmentally friendly method for utilizing one of the agricultural wastes for the removal of a variety of antibiotics from the aquatic environment., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Steam gasification of microalgae upon perovskite oxide-supported nickel (Ni) catalysts was carried out for H 2 -rich gas production. Ni-perovskite oxide catalysts with partial substitution of B in perovskite structures (Ni/CaZrO 3 , Ni/Ca(Zr 0.8 Ti 0.2 )O 3 , and Ni/Ca(Zr 0.6 Ti 0.4 )O 3 ) were synthesized and compared with those of the Ni/Al 2 O 3 catalyst. The perovskite oxide supports improved Ni dispersion by reducing the particle size and strengthening the Ni-support interaction. Higher gas yields and H 2 selectivity were obtained using Ni-perovskite oxide catalysts rather than Ni/Al 2 O 3 . In particular, Ni/Ca(Zr 0.8 Ti 0.2 )O 3 showed the highest activity and selectivity for H 2 production because of the synergetic effect of metallic Ni and elements present in the perovskite structures caused by high catalytic activity coupled with enhanced oxygen mobility. Moreover, increasing the temperature promoted the yield of gas and H 2 content. Overall, considering the outstanding advantages of perovskite oxides as supports for Ni catalysts is a promising prospect for H 2 production via gasification technology., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Many energy-intensive processes are employed to enhance biomass fuel properties to overcome the difficulties in utilizing biomass as fuel. Therefore, energy conservation during these processes is crucial for realizing a circular bioeconomy. This study develops a newly devised method to evaluate SCG biochars' higher heating value (HHV) and predict moisture content from power consumption. It is found that the increasing rates of HHV immediately follow decreases in power consumption, which could be used to determine the pretreatment time for energy conservation. The non-dominated sorting genetic algorithm II (NSGA-II) maximizes SCG biochar's HHV while minimizing energy consumption. The results show that producing SCG biochar with 23.98 MJ∙kg -1 HHV requires 20.042 MJ∙kg -1 , using a torrefaction temperature of 244 °C and torrefaction time of 27 min and 43 sec. Every kilogram of biochar with an energy yield of 85.93 % is estimated to cost NT$ 12.21., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Torrefaction is a remarkable technology in biomass-to-energy. However, biomass has several disadvantages, including hydrophilic properties, higher moisture, lower heating value, and heterogeneous properties. Many conventional approaches, such as kinetic analysis, process modeling, and computational fluid dynamics, have been used to explain torrefaction performance and characteristics. However, they may be insufficient in actual applications because of providing only some specific solutions. Machine learning (ML) and statistical approaches are powerful tools for analyzing and predicting torrefaction outcomes and even optimizing the thermal process for its utilization. This state-of-the-art review aims to present ML-assisted torrefaction. Artificial neural networks, multivariate adaptive regression splines, decision tree, support vector machine, and other methods in the literature are discussed. Statistical approaches (SAs) for torrefaction, including Taguchi, response surface methodology, and analysis of variance, are also reviewed. Overall, this review has provided valuable insights into torrefaction optimization, which is conducive to biomass upgrading for achieving net zero., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Capacitive deionization (CDI) has been considered as an efficient, energy-saving and environmental friendly technology for water treatment. For the practical application of CDI, high-performance electrode materials beyond standard activated carbon should be developed. In this study, biochar derived from brown algae Sargassum hemiphyllum prepared by pyrolysis at 300-700 °C and then used as the CDI electrode to remove Cu(II) from aqueous solutions. According to the findings, the optimal pyrolysis temperature was 700 °C, and the electrosorption capacity of BAB700 was 75-120 mg·g -1 at an applied voltage of 1.2 V across wide range of initial pH, temperatures and ion types. Moreover, BAB700 also exhibited outstanding ability to electrosorb other heavy metals (Zn(II), Ni(II), and Cd(II)). In addition, the BAB700 retained the Cu(II) removal efficiency of 70 % in 10 cycles. Cu(II) in actual water is completely eliminated with great reproducibility, resulting in a high degree of applicability for water treatment., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The increase in worldwide demand for energy is driven by the rapid increase in population and exponential economic development. This resulted in the fast depletion of fossil fuel supplies and unprecedented levels of greenhouse gas in the atmosphere. To valorize biomass into different bioproducts, one of the popular and carbon-neutral alternatives is biorefineries. This system is an appropriate technology in the circular economy model. Various research highlighted the role of biorefineries as a centerpiece in the carbon-neutral ecosystem of technologies of the circular economy model. To fully realize this, various improvements and challenges need to be addressed. This paper presents a critical and timely review of the challenges and future direction of biorefineries as an alternative carbon-neutral energy source., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Large-size woody biomass is a valuable renewable resource to replace fossil fuels in biorefinery processes. The preprocessing of wood chips and briquettes is challenging to manage, especially in an industrial setting, as it generates a significant amount of dust and noise and occasionally causes unexpected accidents. As a result, a substantial amount of resources, energy, labor, and space are needed. The thermochemical conversion behavior of large-size woody biomass was studied to reduce energy consumption for chipping. Large-size wood was 1.5 m in length, 0.1 m in breadth, and stacked 90 cm in height. This strategy has many benefits, including increased effectiveness and reduced CO 2 emissions. The target of this paper presents the thermochemical process, and large-size wood was chosen because it provides high-quality product gas while reducing the preprocessing fuel cost. This review examines the benefits of thermochemical conversion technologies for assessing the likelihood of carbon neutrality., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Carotenoids are naturally occurring pigments that are widely distributed in algae, fungi, bacteria, and plants. Carotenoids play a significant role in the food, feed, cosmetic, nutraceutical, and pharmaceutical industries. These pigments are effectively considered as a health-promoting compounds, which are widely used in our daily diet to reduce the risk of chronic diseases such as cardiovascular diseases, cancer, acute lung injury, cataracts, neural disorders, etc. In this context, this review paper demonstrates the synthesis of carotenoids and their potential application in the food and pharmaceutical industries. However, the demand for carotenoid production is increasing overtime, and the extraction and production are expensive and technically challenging. The recent developments in carotenoid biosynthesis, and key challenges, bottlenecks, and future perspectives were also discussed to enhance the circular bioeconomy., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Food waste conversion/valorization to produce bio-based chemicals plays a key role toward achieving carbon neutrality by 2050. Food waste valorization to renewable chemicals is thus an attractive and eco-friendly approach to handling food waste. The production of platform chemicals from food waste is crucial for making highly value-added renewable chemicals. However, earlier reviews dealing with food waste valorization to produce value-added chemicals have emphasized the enhancement of methane, hydrogen, and ethanol production. Along these lines, the existing methods of food waste to produce platform chemicals (e.g., volatile fatty acids, glucose, hydroxymethylfurfural, levulinic acid, lactic acid, and succinic acid) through physical, chemical, and enzymatic pretreatments, hydrolysis, fermentation, and hydrothermal conversion are extensively reviewed. Finally, the challenges faced under these methods are discussed, along with suggestions for future research on platform chemical production from food waste., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Hydrogen produced from biomass feedstocks is considered an effective solution in moving toward a decarbonized economy. Biohydrogen is a clean energy source that has gained global attention for adoption as it promises to mitigate climate change and human environmental damage. Through the circular economy framework, sustainable biohydrogen production with other bioproducts while addressing issues such as waste management is possible. This study presents a comprehensive review of the various biomass feedstocks and processing technologies associated with biohydrogen generation, as well as the possible integration of existing industries into a circular bioeconomy framework. The currently standing challenges and future perspectives are also discussed., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Green and sustainable hydrogen from biomass gasification processes is one of the promising ways to alternate fossil fuels-based hydrogen production. First off, an overview of green hydrogen generation from biomass gasification processes is presented and the corresponding possible gasification reactions and the effect of respective experimental criteria are explained in detail. In addition, a comprehensive explanation of the catalytic effect on tar reduction and hydrogen generation via catalytic gasification is presented regarding the functional mechanisms of various types of catalysts. Furthermore, the commercialization aspects, the associated technical challenges and barriers, and the prospects of a biomass gasification process for green hydrogen generation are discussed. Finally, this comprehensive review provides the related advancements, challenges, and great insight of biomass gasification for the green hydrogen generation to realize a sustainable hydrogen society via biomass valorization., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Household food waste (FW) was converted into biohydrogen-rich gas via steam gasification over Ni and bimetallic Ni (Cu-Ni and Co-Ni) catalysts supported on mesoporous SBA-15. The effect of catalyst method on steam gasification efficiency of each catalyst was investigated using incipient wetness impregnation, deposition precipitation, and ethylenediaminetetraacetic acid metal complex impregnation methods. H 2 -TPR confirmed the synergistic interaction of the dopants (Co and Cu) and Ni. Furthermore, XRD and HR-TEM revealed that the size of the Ni particle varied depending on the method of catalyst synthesis, confirming the formation of solid solutions in Co- or Cu-doped Ni/SBA-15 catalysts due to dopant insertion into the Ni. Notably, the exceptional activity of the Cu-Ni/SBA-15-EMC catalyst in FW steam gasification was attributed to the fine distribution of the concise Ni nanoparticles (9 nm), which resulted in the highest hydrogen selectivity (62 vol%), gas yield (73.6 wt%). Likewise, Cu-Ni solid solution decreased coke to 0.08 wt%., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Agricultural waste biomass has shown great potential to deliver green energy produced by biochemical and thermochemical conversion processes to mitigate future energy crises. Biohydrogen has become more interested in carbon-free and high-energy dense fuels among different biofuels. However, it is challenging to develop models based on experience or theory for precise predictions due to the complexity of biohydrogen production systems and the limitations of human perception. Recent advancements in machine learning (ML) may open up new possibilities. For this reason, this critical study offers a thorough understanding of ML's use in biohydrogen production. The most recent developments in ML-assisted biohydrogen technologies, including biochemical and thermochemical processes, are examined in depth. This review paper also discusses the prediction of biohydrogen production from agricultural waste. Finally, the techno-economic and scientific obstacles to ML application in agriculture waste biomass-based biohydrogen production are summarized., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Every day, a large amount of food waste (FW) is released into the environment, causing financial loss and unpredictable consequences in the world, highlighting the urgency of finding a suitable approach to treating FW. As moisture content makes up 75% of the FW, hydrothermal carbonization (HTC) is a beneficial process for the treatment of FW since it does not require extensive drying. Moreover, the process is considered favorable for carbon sequestration to mitigate climate change in comparison with other processes because the majority of the carbon in FW is integrated into hydrochar. In this work, the reaction mechanism and factors affecting the HTC of FW are scrutinized. Moreover, the physicochemical properties of products after the HTC of FW are critically presented. In general, HTC of FW is considered a promising approach aiming to attain simultaneously-two core benefits on economy and energy in the sustainable development strategy., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

In this study, the brown algae Sargassum Hemiphyllum was used as a carbon source for synthesis of magnetic porous biochar via pyrolyzing at high temperature and and doping iron oxide particles (Fe-BAB). Cu (II) species were removed from aqueous solutions using Fe-BAB under various conditions. Fe-BAB demonstrated superior Cu (II) adsorption (105.3 mg g -1 ) compared to other biochars. On the surface of Fe-BAB, there are several oxygen-containing functional groups, such as -COOH and -OH, which are likely responsible for the excellent heavy metal removal performance. By utilizing magnet, the Fe-BAB can be conveniently separated from the solution and ready for further usage. Multi-adsorption mechanisms were responsible for Cu adsorption on Fe-BAB. Using the magnetic algal biochar for heavy metal removal is feasible due to its high adsorption efficiency and simplicity of separation., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Microalgal biorefineries represent an opportunity to economically and environmentally justify the production of bioproducts. The generation of bioproducts within a biorefinery system must quantitatively demonstrate its viability in displacing traditional fossil-based refineries. To this end, several works have conducted life cycle analyses on microalgal biorefineries and have shown technological bottlenecks due to energy-intensive processes. This state-of-the-art review covers different studies that examined microalgal biorefineries through life cycle assessments and has identified strategic technologies for the sustainable production of microalgal biofuels through biorefineries. Different metrics were introduced to supplement life cycle assessment studies for the sustainable production of microalgal biofuel. Challenges in the comparison of various life cycle assessment studies were identified, and the future design choices for microalgal biorefineries were established., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The macroalgal industry is expanding, and the quest for novel ingredients to improve and develop innovative products is crucial. Consumers are increasingly looking for natural-derived ingredients in cosmetic products that have been proven to be effective and safe. Macroalgae-derived compounds have growing popularity in skincare products as they are natural, abundant, biocompatible, and renewable. Due to their high biomass yields, rapid growth rates, and cultivation process, they are gaining widespread recognition as potentially sustainable resources better suited for biorefinery processes. This review demonstrates macroalgae metabolites and their industrial applications in moisturizers, anti-aging, skin whitening, hair, and oral care products. These chemicals can be obtained in combination with energy products to increase the value of macroalgae from an industrial perspective with a zero-waste approach by linking multiple refineries. The key challenges, bottlenecks, and future perspectives in the operation and outlook of macroalgal biorefineries were also discussed., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Biochars derived from three species of algae was synthesized by impregnating the green algae Ulva Ohnoi, red algae Agardhiella subulata, and brown algae Sargassum hemiphyllum with ZnCl 2 chemical activator and employed as a long-term adsorbent for ciprofloxacin (CIP) removal from water. The results revealed that combination of brown algae and ZnCl 2 chemical activator (ZBAB) successfully produced mesoporous biochar with excellent physicochemical characteristics and gave the best CIP adsorption capacity. The ZBAB yielded a high CIP adsorption capacity (190-300 mg g -1 ) under various parameter effects (initial pH, temperature and major ions). Throughought the surface characterization techniques, the proposed adsorption mechanisms were electrostatic interaction, π-π EDA interaction, pore filling and hydrogen bonding. Moreover, not only algal biochars exhibited innovative and potential adsorbent for rapid and effective remediate pollution from water, but combination of algal biomass and ZnCl 2 activator also created renewable source of energy from biomass pyrolysis., (Copyright © 2022. Published by Elsevier Ltd.)

In this study, biochar derived from brown algal Ascophyllum nodosum was synthesized through hydrothermal carbonization (HTC) coupling with ZnCl 2 chemical activation and applied as a sustainable adsorbent for antibiotic removal from water exemplified by ciprofloxacin (CIP). Various surface analysis techniques such as Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and zeta potential were used to clarify the surface properties of prepared biochars. The adsorption performance of biochars was investigated using batch adsorption experiments with a variety of parameters (initial pH, ionic types, temperature and water matrixes). The application of prepared biochar in CIP removal showed a good result of adsorption capacity (150-400 mg g -1 ) in different conditions. Overall, algal biochars, as a product recycled from biowaste, demonstrated a novel and promising adsorbent for effective and sustainable method for removal of antibiotics from water., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Lignocellulosic biomass (LCB) is considered as a sustainable feedstock for a biorefinery to generate biofuels and other bio-chemicals. However, commercialization is one of the challenges that limits cost-effective operation of conventional LCB biorefinery. This article highlights some studies on the sustainability of LCB in terms of cost-competitiveness and environmental impact reduction. In addition, the development of computational intelligence methods such as Artificial Intelligence (AI) as a tool to aid the improvement of LCB biorefinery in terms of optimization, prediction, classification, and decision support systems. Lastly, this review examines the possible research gaps on the production and valorization in a smart sustainable biorefinery towards circular economy., (Copyright © 2021. Published by Elsevier Ltd.)

In recent years, lignocellulosic biomass has emerged as one of the most versatile energy sources among the research community for the production of biofuels and value-added chemicals. However, biomass pretreatment plays an important role in reducing the recalcitrant properties of lignocellulose, leading to superior quality of target products in bioenergy production. Among existing pretreatment techniques, liquid hot water (LHW) pretreatment has several outstanding advantages compared to others including minimum formation of monomeric sugars, significant removal of hemicellulose, and positive environmental impacts; however, several constraints of LHW pretreatment should be clarified. This contribution aims to provide a comprehensive analysis of reaction mechanism, reactor characteristics, influencing factors, techno-economic aspects, challenges, and prospects for LHW-based biomass pretreatment. Generally, LHW pretreatment could be widely employed in bioenergy processing from biomass, but circular economy-based advanced pretreatment techniques should be further studied in the future to achieve maximum efficiency, and minimum cost and drawbacks., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Lignocellulosic biomass is a highly renewable, economical, and carbon-neutral feedstock containing sugar-rich moieties that can be processed to produce second-generation biofuels and bio-sourced compounds. However, due to their heterogeneous multi-scale structure, the lignocellulosic materials have major limitations to valorization and exhibit recalcitrance to saccharification or hydrolysis by enzymes. In this context, this review focuses on the latest methods available and state-of-the-art technologies in the pretreatment of lignocellulosic biomass, which aids the disintegration of the complex materials into monomeric units. In addition, this review deals with the genetic engineering techniques to develop advanced strategies for fermentation processes or microbial cell factories to generate desired products in native or modified hosts. Further, it also intends to bridge the gap in developing various economically feasible lignocellulosic products and chemicals using biorefining technologies., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Rapid growth of aquatic weeds in treatment pond poses undesirable challenge to shellfish aquaculture, requiring the farmers to dispose these weeds on a regular basis. This article reviews the potential and application of various aquatic weeds for generation of biofuels using recent thermochemical technologies (torrefaction, hydrothermal carbonization/liquefaction, pyrolysis, gasification). The influence of key operational parameters for optimising the aquatic weed conversion efficiency was discussed, including the advantages, drawbacks and techno-economic aspects of the thermochemical technologies, and their viability for large-scale application. Via extensive study in small and large scale operation, and the economic benefits derived, pyrolysis is identified as a promising thermochemical technology for aquatic weed conversion. The perspectives, challenges and future directions in thermochemical conversion of aquatic weeds to biofuels were also reviewed. This review provides useful information to promote circular economy by integrating shellfish aquaculture with thermochemical biorefinery of aquatic weeds rather than disposing them in landfills., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Microalgae are the most prospective raw materials for the production of biofuels, pyrolysis is an effective method to convert biomass into bioenergy. However, biofuels derived from the pyrolysis of microalgae exhibit poor fuel properties due to high content of moisture and protein. Co-pyrolysis is a simple and efficient method to produce high-quality bio-oil from two or more materials. Tires, plastics, and bamboo waste are the optimal co-feedstocks based on the improvement of yield and quality of bio-oil. Moreover, adding catalysts, especially CaO and Cu/HZSM-5, can enhance the quality of bio-oil by increasing aromatics content and decreasing oxygenated and nitrogenous compounds. Consequently, this paper provides a critical review of the production of bio-oil from co-pyrolysis of microalgae with other biomass wastes. Meanwhile, the underlying mechanism of synergistic effects and the catalytic effect on co-pyrolysis are discussed. Finally, the economic viability and prospects of microalgae co-pyrolysis are summarized., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Artificial neural network (ANN) is one kind of artificial intelligence in the computing system that aims to process information as the way neurons in the human brain. In this study, the combination of the Taguchi method and ANN are used to maximize and predict biofuel yield from spent mushroom substrate torrefaction and pyrolysis via microwave irradiation. The Taguchi method is utilized to design the multiple factors (particle size, catalyst, power, and magnetic agent) and levels of experiment parameters. The highest total biofuel yield (biochar + bio-oil) is 99.42%, accomplished by a combination of 355 µm particle size, 300 mg·g-SMS -1 catalyst, 900 W power, and 300 mg·g-SMS -1 magnetic agent. ANN with one hidden layer shows the outstanding linear regression predictions for the highest biofuel yields (biochar 0.9999 and bio-oil 0.9998). This high linear regression indicates that ANN with a quick propagation algorithm is an appropriate approach for predicting biofuel conversion., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Biohydrogen (BioH 2 ) is considered as one of the most environmentally friendly fuels and a strong candidate to meet the future demand for a sustainable source of energy. Presently, the production of BioH 2 from photosynthetic organisms has raised a lot of hopes in the fuel industry. Moreover, microalgal-based BioH 2 synthesis not only helps to combat current global warming by capturing greenhouse gases but also plays a key role in wastewater treatment. Hence, this manuscript provides a state-of-the-art review of the upstream and downstream BioH 2 production processes. Different metabolic routes such as direct and indirect photolysis, dark fermentation, photofermentation, and microbial electrolysis are covered in detail. Upstream processes (e.g. growth techniques, growth media) also have a great impact on BioH 2 productivity and economics, which is also explored. Technical and scientific obstacles of microalgae BioH 2 systems are finally addressed, allowing the technology to become more innovative and commercial., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Present study provides biohydrogen production methods from waste furniture via catalytic steam gasification with bio-char catalysts (raw char, KOH-activated char and steam-activated char). Total gas yield for the prepared chars was in the order of KOH-activated char > steam-activated char > raw char, whereas, H 2 selectivity was in the sequence of raw char > steam-activated char > KOH-activated char. Though KOH-activated char showed the highest gas yield, highest H 2 selectivity was obtained at the gasification experiment with raw char due to the large amount of Ca and K and its reasonable surface area (146.89 m 2 /g). Although the activation of raw biochar results in the increase of gas yield, it has the negative effect on H 2 generation due to the removal of alkali and alkaline earth metals for the KOH activated char and steam-activated char. This study shows that raw bio-char could be a potential solution for eco-friendly hydrogen production., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Recent studies show that fast hydropyrolysis (i.e., pyrolysis under hydrogen atmosphere operating at a rapid heating rate) is a promising technology for the conversion of biomass into liquid fuels (e.g., bio-oil and C 4+ hydrocarbons). This pyrolysis approach is reported to be more effective than conventional fast pyrolysis in producing aromatic hydrocarbons and also lowering the oxygen content of the bio-oil obtained compared to hydrodeoxygenation (a common bio-oil upgrading method). Based on current literature, various non-catalytic and catalytic fast hydropyrolysis processes are reviewed and discussed. Efforts to combine fast hydropyrolysis and hydrotreatment process are also highlighted. Points to be considered for future research into fast hydropyrolysis and pending challenges are also discussed., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

To explore the catalytic effect of potassium on pyrolysis characteristics of biomass, the rubberwood is pyrolyzed by a thermogravimetric analyzer. The samples are impregnated by three concentrations of potassium carbonate (0.004 M, 0.008 M, and 0.012 M). The pyrolysis kinetics is analyzed by an independent parallel reaction (IPR) model to describe the catalytic effect on the four-pseudo components model in the rubberwood. The particle swarm optimization (PSO) is adopted to optimize the fit quality between the established kinetic models and experimental data. It is found that the pyrolysis of rubberwood impregnated with 0.012 M concentration of K 2 CO 3 can reduce the activation energy of cellulose from 223.86 to 204.14 kJ mol -1 , whereas there is no obvious effect on the activation energies of hemicelluloses and lignin. The starting temperature and ending temperature of cellulose thermodegradation also move toward lower temperatures, indicating that the addition of potassium enhances the degradation of cellulose., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

An innovative approach was developed by incorporating high-pressure CO 2 into the separate hydrolysis-fermentation of aspen leftover branches, aiming to enhance the bioethanol production efficiency. The high-pressure CO 2 significantly increased the 72-h enzymatic hydrolysis yield of converting aspen into glucose from 53.8% to 82.9%. The hydrolysis process was performed with low enzyme loading (10 FPU g -1 glucan) with the aim of reducing the cost of fuel bioethanol production. The ethanol yield from fermentation of the hydrolyzed glucose using yeast (Saccharomyces cerevisiae) was 8.7 g L -1 , showing increment of 10% compared with the glucose control. Techno-economic analysis indicated that the energy consumption of fuel bioethanol production from aspen branch chips was reduced by 35% and the production cost was cut 44% to 0.615 USD L -1 , when 68 atm CO 2 was introduced into the process. These results furtherly emphasized the low carbon footprint of this sustainable energy production approach., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Microwave vacuum pyrolysis of palm kernel shell was examined to produce engineered biochar for application as additive in agriculture application. The pyrolysis approach, performed at 750 W of microwave power, produced higher yield of porous biochar (28 wt%) with high surface area (270 cm 2 /g) compared to the yield obtained by conventional approach (<23 wt%). Addition of the porous biochar in mushroom substrate showed increased moisture content (99%) compared to the substrate without biochar (96%). The mushroom substrate added with biochar (150 g) was optimal in shortening formation, growth, and full colonization of the mycelium within one month. Using 2.5% of the biochar in mushroom substrate desirably maintained the optimum pH level (6.8-7) during the mycelium colonization period, leading to high mycelium growth (up to 91%) and mushroom yield (up to 280 g). The engineered biochar shows great potential as moisture retention and neutralizing agent in mushroom cultivation., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

The world energy system faces two major challenges: the requirement for more energy and less carbon. It is important to address biofuels production as an alternative to the usage of fossil fuel by utilizing microalgae as the potential feedstock. Yet, the commercialization of microalgae remains contentious caused by factors relating to the life cycle assessment and feasibility of microalgae-based biofuels. This present review starts with an introduction to the benefits of microalgae, followed by intensive elaboration on microalgae cultivation parameters. Subsequently, the fundamental principle along with the advantages and disadvantages of various pretreatment techniques of microalgae were reviewed. In addition, the conventional and recent advances in lipid extraction techniques from microalgae were comprehensively evaluated. Comparative analysis regard to the gaps from previous studies was discussed point-by-point in each section. The effort presented in this review will provide an insight for future researches dealing with microalgae-biofuel production on downstream processing., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

The thermal characteristics of Actinobacillus succinogenes (AS) from pyrolysis, torrefaction, and combustion are analyzed to evaluate the potential of this biomass as a renewable fuel. AS pyrolysis can be classified into four stages, and its main decomposition zone is at 200-500 °C. The solid yield of AS after 60 min torrefaction is over 60 wt%, and the torrefaction severity index map indicates that a high torrefaction temperature with a short duration has a more profound influence on its decomposition. The Py-GC/MS analysis of AS suggests that the volatile products from 500 °C pyrolysis are similar to microalgae-derived pyrolysis bio-oils. The combustibility index (S) of AS is 4.07 × 10 -7 which is much higher than that of lignite coal (0.39 × 10 -7 ) and bituminous coal (0.18 × 10 -7 ), and close to those of biochar and bio-oil. The obtained results are conducive to the development of microorganisms as fuel to achieve a circular bioeconomy., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Biorefinery is a sustainable means of generating multiple bioenergy products from various biomass feedstocks through the incorporation of relevant conversion technologies. With the increased attention of circular economy in the past half-decade with the emphasis of holistically addressing economic, environmental, and social aspects of the industrial-sector, biorefinery acts as a strategic mechanism for the realization of a circular bioeconomy. This study presents a comprehensive review of different biorefinery models used for various biomass feedstocks such as lignocelluloses, algae, and numerous waste-types. The review focuses on how biorefinery is instrumental in the transition of various biomass-based industries in a circular bioeconomy. The results reveal that the social-economic aspect of the industrial sector has a major influence on the full adoption of biorefineries in circular bioeconomy. Biomass wastes have played a major role in the implementation of biorefinery in circular bioeconomy. The current challenges are also presented along with future perspectives., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Microalgal and lignocellulosic biomass is the most sumptuous renewable bioresource raw material existing on earth. Recently, the bioconversion of biomass into biofuels have received significant attention replacing fossil fuels. Pretreatment of biomass is a critical process in the conversion due to the nature and structure of the biomass cell wall that is complex. Although green technologies for biofuel production are advancing, the productivity and yield from these techniques are low. Over the past years, various pretreatment techniques have been developed and successfully employed to improve the technology. This paper presents an in-depth review of the recent advancement of pretreatment methods focusing on microalgal and lignocellulosic biomass. The technological approaches involving physical, chemical, biological and other latest pretreatment methods are reviewed., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Microalgal biomass is a renewable energy source and is considered as a crucial solution in the increasing energy demand and greenhouse gas emissions. Through various thermochemical conversion processes such as torrefaction, pyrolysis, liquefaction, and gasification, biomass can be converted to different bioenergy products. However, the production of these bioenergy products through the aforesaid thermochemical processes entails raw material consumption, energy consumption, and environmental impact. A multitude of studies has been conducted to evaluate the environmental impact of bioenergy products for specific thermochemical processes on a specific biomass feedstock using life cycle assessment. This study aims to comprehensively review the life cycle assessment of bioenergy products from microalgal biomass together with lignocellulosic biomass and through different thermochemical processes. The study identifies the current challenges and potential future works of bioenergy production from different thermochemical processes in the perspective of a life cycle assessment framework., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Third generation biofuels, also known as microalgal biofuels, are promising alternatives to fossil fuels. One attractive option is microalgal biodiesel as a replacement for diesel fuel. Chlamydomonas sp. Tai-03 was previously optimized for maximal lipid production for biodiesel generation, achieving biomass growth and productivity of 3.48 ± 0.04 g/L and 0.43 ± 0.01 g/L/d, with lipid content and productivity of 28.6 ± 1.41% and 124.1 ± 7.57 mg/L/d. In this study, further optimization using 5% CO 2 concentration and semi-batch operation with 25% medium replacement ratio, enhanced the biomass growth and productivity to 4.15 ± 0.12 g/L and 1.23 ± 0.02 g/L/d, with lipid content and productivity of 19.4 ± 2.0% and 239.6 ± 24.8 mg/L/d. The major fatty acid methyl esters (FAMEs) were palmitic acid (C16:0), oleic acid (C18:1), and linoleic acid (C18:2). These short-chain FAMEs combined with high growth make Chlamydomonas sp. Tai-03 a suitable candidate for biodiesel synthesis., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

This study aimed to investigate the transport mechanisms of ions during forward-osmosis-driven (FO-driven) dewatering of microalgae using molecular dynamics (MD) simulations. The dynamical and structural properties of ions in FO systems of varying NaCl or MgCl 2 draw solution (DS) concentrations were calculated and correlated. Results indicate that FO systems with higher DS concentration caused ions to have lower hydration numbers and higher coordination numbers leading to lower diffusion coefficients. The higher hydration number of Mg 2+ ions resulted in significantly lower ionic permeability as compared to Na + ions at all concentrations (p = 0.002). The simulations also revealed that higher DS concentrations led to higher accumulation of ions in the membrane. This study provides insights on the proper selection of DS for FO systems., (Copyright © 2019 Elsevier Ltd. All rights reserved.)