26 results on '"Silane -- Physiological aspects"'
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2. 1,2-silyl-migrative cyclization of vinylsilanes bearing a hydroxy group: stereoselective synthesis of multisubstituted tetrahydropyrans and tetrahydrofurans
3. Novel intramolecular [4+1] and [4+2] annulation reactions employing cascade radical cyclizations
4. Stereoselective synthesis of both syn- and anti-N-tert-alkylamines using highly stereospecific crotylation of ketone-derived acylhydrazones with crotyltrichlorosilanes
5. Reaction of allylsilanes and allylstannanes with alkynes catalyzed by electrophilic late transition metal chlorides
6. Ring-opening reactions of cyclic acetals and 1,3-oxazolidines with halosilane equivalents
7. A triruthenium carbonyl cluster bearing a bridging acenaphthylene ligand: an efficient catalyst for reduction of esters, carboxylic acids, and amides by trialkylsilanes
8. Mannich-type reactions in the gas-phase: the addition of enol silanes to cyclic N-acyliminium ions
9. The regioselective mono-deprotection of 1,3-dioxa-2,2-(di-tert-butyl)-2-silacyclohexanes with BF (sub)3 .SMe (sub)2
10. Stereoselective total syntheses of the racemic form and the natural enantiomer of the marine alkaloid lepadiformine via a novel N-acyliminium ion/allylsilane spirocyclization strategy
11. Electronic effects and the stereochemistries in rearrangement-displacement reactions of triaryl(halomethyl)silanes with fluoride and with alkoxide ions
12. Allylation of exocyclic N-acyliminium ions generated from chiral N-[1-(phenylsulfonyl)alkyl]oxazolidin-2-ones
13. Metal-catalyzed hydrosilylation of alkenes and alkynes using dimethyl(pyridyl)silane
14. The intriguing reactivity of functionalized beta-amino alcohols with glyoxal: application to a new expedient enantioselective synthesis of trans-6-alkylpipecolic acids
15. Beta-silylcarbenes from isolable diazosilanes
16. The application of intramolecular radical cyclizations of acylsilanes in the regiospecific formation of cyclic silyl enol ethers
17. Intramolecular cyclization of tert-butyldiphenylallylsilane units and carbonyl groups: allylsilane terminated cyclization versus the ene reaction
18. Palladium-catalyzed asymmetric diene cyclization/hydrosilylation employing functionalized silanes and disiloxanes
19. Reactivity of tris(trimethylsilyl)silane toward diarylaminyl radicals
20. Synthesis of (+)-juruenolide C: use of sequential 5-exo-digonal radical cyclization, 1,5-intramolecular hydrogen transfer, and 5-endo-trigonal cyclization
21. Bis(acylsilanes) and trifluoromethyltrimethylsilane: a useful system for the synthesis of cyclic 2,2-difluoro-3-trialkylsilyl-1,3-ketols and cyclic 2-fluoro-1,3-diketones
22. Palladium-catalyzed tandem reactions to form 1-vinyl-1H-isochromene derivatives
23. One-pot synthesis of difluoroaldols from acylsilanes and trifluoromethyltrimethylsilane. Application to the synthesis of a difluoro analogue of egomaketone
24. Norbornadiene as an efficient hydrogen scavenger for the palladium-catalyzed conversion of hydrosilanes to alkoxysilanes
25. Palladium complex catalyzed acylation of allylic esters with acylstannanes: complementary method to the acylation with acylsilanes
26. Stereoselective additions of chiral (E)-crotylsilanes to thionium ions: asymmetric synthesis of homoallylic thioethers
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