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Water insoluble calcium hydroxide Ca(OH)2 or calcium carbonate CaCO3 react with aqueous solution of (1-hydroxyethylidene)diphosphonic acid and nitrilotrimethylenephosphonic acid to form poorly soluble calcium (1-hydroxyethylidene)diphosphonate trihydrate and calcium nitrilotrimethylenephosphonate trihydrate, respectively. The reaction of calcium chloride CaCl2 with the disodium salt of ethylenediaminetetraacetic acid afforded poorly soluble calcium ethylenediaminetetraacetate hexahydrate. The reaction of suspensions of complexes of (1-hydroxyethylidene)calcium diphosphonate trihydrate, calcium ethylenediaminetetetraacetate hexahydrate and calcium nitrilotrimethylenephosphonate trihydrate with 2-aminoethanol led to the formation of water-soluble (1-hydroxyethylidene)bis(2-aminoethanol)calcium diphosphonate, tris(2-aminoethanol)calcium nitrilotrimethylenephosphonate, and bis(2-aminoethanol)calcium ethylenediaminetetraacetate, respectively. The molecular structure of calcium ethylenediaminetetraacetate hexahydrate was characterized by single-crystal X-ray diffraction method. [ABSTRACT FROM AUTHOR]

Poorly soluble zinc ethylenediaminetetraacetate zincate Zn[ZnL] reacts with sodium Na4L, potassium K4L, ammonium (NH4)4L, 2-ammonioethanol (H3NCH2CH2OH)4L, and hexamethylene-1,6-diammonium {H3N(CH2)6NH3}2L salts of ethylenediaminetetraacetic acid H4L to give readily soluble sodium Na2[ZnL], potassium K2[ZnL], ammonium (NH4)2[ZnL], 2-ammonioethanol (H3NCH2CH2OH)2[ZnL], and hexamethylene-1,6-diammonium {H3N(CH2)6NH3}[ZnL] ethylenediaminetetraacetate zincates. The reaction of tetrakis(triethylammonium) salt {(C2H5)3NH}4L with Zn[ZnL] does not give the expected bis(triethylammonium) ethylenediaminetetraacetate zincate {(C2H5)3NH}2[ZnL], but gives instead mono(triethylammonium) ethylenediaminetetraacetate zincate, {(C2H5)3NH}H[ZnL]; in aqueous solution, this product generates poorly soluble zinc ethylenediaminetetraacetate H2[ZnL(H2O)]·2H2O, which was studied by X-ray diffraction (CCDC no. 2172274). [ABSTRACT FROM AUTHOR]

Tetrabasic ethylenediaminetetraacetic acid H4L binds two molecules of monobasic amines to give the corresponding salts: ethylenediaminetetraacetates of bis(monoethanolaminium) H2L2–⋅2+H3NCH2CH2ОН, tris(hydroxymethyl)methylaminium H2L2–⋅2+H3NС(CH2ОН)3⋅3H2О, diethylaminium H2L2–⋅2+H2N(C2H5)2⋅H2О, tert-butylaminium H2L2–⋅2+H3NС(CH3)3⋅5H2О, and triethanolaminium H2L2–⋅2+HN(CH2CH2ОH)3. Dibasic hexamethylene-1,6-diamine, triethylenediamine, and tetramethylethylenediamine form the following 1 : 1 adducts: H2L2–⋅+NH3(CH2)6NH , H2L2–⋅+NH3CH2CH2(OCH2CH2)2NH , H2L2–⋅ +HN(CH2CH2)3NH+⋅H2О, and H2L2–⋅+H(CH3)2NCH2CH2N(CH3)2H+. The molecular structures of bis(monoethanolaminium) ethylenediaminetetraacetate and bis[tris(hydroxymethyl)methylaminium] ethylenediaminetetraacetate trihydrate were determined. [ABSTRACT FROM AUTHOR]