51. A series of metal–organic frameworks constructed with 2,2′-bipyridine-3,3′-dicarboxylate: Syntheses, structures, and physical properties
- Author
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Chen, Xiao-Li, Yao, Yue-Juan, Hu, Huai-Ming, Chen, Shuan-Hu, Fu, Feng, Han, Zhong-Xi, Qin, Ting, Yang, Meng-Lin, and Xue, Gang-Lin
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ORGANOMETALLIC chemistry , *COMPLEX compounds synthesis , *METAL ions , *COORDINATION polymers , *LIGANDS (Chemistry) , *LUMINESCENCE , *MAGNETIC properties - Abstract
Abstract: To determine the influence of metal ion and the auxiliary ligand on the formation of metal–organic frameworks, six new coordination polymers, {[Mn2(bpdc)(bpy)3(H2O)2]·2ClO4 ·H2O} n (1), {[Mn(bpdc)(dpe)]·CH3OH·2H2O} n (2), {[Cu(bpdc)(H2O)2]} n (3), {[Zn(bpdc)(H2O)2]} n (4), {[Cd(bpdc)(H2O)3]·2H2O} n (5), and {[Co(bpdc)(H2O)3]·0.5dpe·H2O} n (6) (H2bpdc=2,2′-bipyridine-3,3′-dicarboxylic acid, bpy=2,2′-bipyridine, dpe=1,2-di(4-pyridyl) ethylene), have been synthesized and characterized. Compound 1 forms 1D helical chain structure containing two unique MnII ions. In 2, the bridging ligand dpe links Mn-bpdc double zigzag chains to generate a layer possesses rectangular cavities. In 3, bpdc2− ligand connects to three metal centers forming a 2D network. Different from the above compounds, 4 displays a 1D double-wavelike chain. Compound 5 features a helical chain. Compound 6 also displays a helical chain with guest molecule dpe existing in the structure. These diverse structures illustrate rational adjustment of metal ions and the second ligand is a good method for the further design of helical compounds with novel structures and properties. In addition, the magnetic properties of 2, 3 and 6, the thermal stabilities and photoluminescence properties of 4 and 5 were also studied. [Copyright &y& Elsevier]
- Published
- 2009
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