386 results on '"Rauchfuss, Thomas B."'
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2. The binuclear cluster of [FeFe] hydrogenase is formed with sulfur donated by cysteine of an [Fe(Cys)(CO)₂(CN)] organometallic precursor
3. Final Stages in the Biosynthesis of the [FeFe]‐Hydrogenase Active Site.
4. [Ru3(CN)3(CO)9]3−:Building Block for Multimetallic Cages.
5. Systematic Assembly of the Double Molecular Boxes: $\lbrace Cs\!\subset\![CpCo(CN)_3]_4[Cp^\ast Ru]_3\rbrace$ as a Tridentate Ligand
6. Synthesis, Spectroscopy, and Structure of [FeRu(μ-dithiolate)(CN)2(CO)4]2–.
7. Fully Refined Semisynthesis of the [FeFe] Hydrogenase H‑Cluster.
8. Hybrids of [FeFe]- and [NiFe]‑H2ase Active Site Models.
9. Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(Ex)(CN)2(CO)2]2– (E = S, Se, or Te).
10. A Promising Mimic of Hydrogenase Activity
11. Nanoscale ensembles using building blocks inspired by the [FeFe]-hydrogenase active site
12. Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(Ex)(CN)2(CO)2]2– (E = S, Se, or Te).
13. Chelate control of diiron(I) dithiolates relevant to the [Fe-Fe]-hydrogenase active site
14. MS2(Me2PC2H4PMe2)2 (M = Mo, W): Acid-base properties, proton transfer, and reversible protonolysis of sulfido ligands
15. Organo-tricyanoborates as tectons: Illustrative coordination polymers based on copper(I) derivatives
16. Structural chemistry of 'Defect' cyanometalate boxes: {Cs subset [CpCo(CN)3] (sub 4) [Cp*Ru] (sub 3)} and {M subset [Cp*Rh(CN)3] (sub 4) [Cp*Ru] (sub 3)} (M = NH4, Cs)
17. Bimetallic carbonyl thiolates as functional models for Fe-only hydrogenases
18. Systematic assembly of the double molecular boxes: {Cs[subset][[CpCo[(CN).sub.3]].sub.4][[Cp*Ru].sub.3]} as a tridentate ligand
19. Preparative and structural studies on the carbonyl cyanides of iron, manganese, and ruthenium: fundamentals relevant to the hydrogenases
20. Synthetic and structural studies on [Fe2(SR)(Sub 2)(CN)(Sub x)(CO)(Sub 6-x)](Super x-) as active site models for Fe-only hydrogenases
21. The N-H...S hydrogen bond in (TACN)2Fe2S6 and in model systems involving the Persulfido moiety: An ab initio and DFT study
22. Influence of H(sub 2)S and thiols on the binding of alkenes and alkynes to ReS(sub 4)(super -): The spectator sulfido effect
23. Binding of pi-acceptor ligands to (triamine)iron(II) complexes
24. Third-order nonlinear optical properties of sulfur-rich compounds
25. Dehydrogenative route to metallo dithiolenes: the reaction of zinc polysulfides and alkenes
26. Binding of alkenes to ReS4-
27. Alkali metal-templated assembly of cyanometalate 'boxes' (NEt4)3(M(Cp*Rh(CN)3)4(Mo(CO)3)4) (M = K, Cs). Selective binding of Cs+
28. [Me 8Pt 4ReS 4] − and related PtMe 2-containing clusters derived from tetrathiorhenate
29. Inhibition of [FeFe]-hydrogenase by formaldehyde: proposed mechanism and reactivity of FeFe alkyl complexes.
30. Challenges in the Synthesis of Active Site Mimics for [NiFe]-Hydrogenases.
31. A polymeric binary titanium(IV) sulfide and its conversion to molecular Lewis base adducts
32. Effect of ancillary ligands on the reactivity and structure of zinc polysulfido complexes
33. Studies on the electroactive heterocycles C(sub6)S(sub8)(super0/2-) and C(sub6)S(sub6)O(sub2)(super0/2-) and related metal complexes
34. Functionalization of Cp4Fe4(CO)4: contrasts and comparisons with ferrocene
35. Sulfido-persulfido equilibria in sulfur-rich metal clusters: the case of (C5Me5)3RhRu2Ssub4sup2+
36. Iron sulfido derivatives of the fullerenes C60 and C70
37. Structural and mechanistic studies on ion insertion into the molecular box {[CpCo(CN) 3] 4[Cp*Ru] 4}
38. Biosynthesis of the [FeFe] hydrogenase H-cluster via a synthetic [Fe(II)(CN)(CO)2(cysteinate)]− complex.
39. Surprising Condensation Reactions of the Azadithiolate Cofactor.
40. Homoleptic Rhodium Pyridine Complexes for Catalytic Hydrogen Oxidation.
41. Pairwise mobility of metal-metal bonds in (MeC5H4)4Ru4S3(SMe)(super n+)
42. One step closer to structural models of HDS catalysts: thienyl-oxo complexes of Re(V)
43. Binary carbon sulfides based on the alpha-C3S5 subunit and related C-S-O, C-S-Cl, and C-S-N compounds
44. Mobile metal-metal bonds: studies on mixed valence Ir3 and Ir4 clusters
45. Synthetic and structural studies on (RC5H4)4Ru4E(sub 4)(super 0/2+) (E = S, Se, Te): mobile metal-metal bonds within a mixed-valence Ru(IV)/Ru(III) cluster
46. Arene vs thiophene reduction in the system (C6R6)Ru(C4R4S)2+ and the protonation of eta4-thiophene ligands
47. Base hydrolysis of coordinated thiophene in (C5R5)Rh(C4Me4S)2+: nucleophilic attack at divalent sulfur and the reversible cleavage of C-S bonds
48. Electronic structure of metal chalcogen cubane clusters: photoelectron spectroscopic, electrochemical, and theoretical studies of (eta-C5H4Me TiS)4, (eta-C5H4Me VS)4, (eta-C5H5 CrO)4, (eta-C5H4Me CrO)4, (eta-C5H4Me CrS)4, (eta-C5H4Me CrSe)4, (eta-C5H4 super i Pr MoS)4, and (eta-C5H4 super i Pr MoSe)4
49. Synthetic studies on the CpRu-PPh3-(Se2) system: redox interconversions of Ru2(Se2)2 cores
50. Redistribution of reduced thiophene ligands in the conversion of (C5R5)Rh(eta4-C4Me4S) to ((C5R5)Rh)3(eta4,eta1-C4Me4S)2
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