379 results on '"Rauchfuss, Thomas B."'
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2. Synthesis, Spectroscopy, and Structure of [FeRu(μ-dithiolate)(CN)2(CO)4]2–.
3. Fully Refined Semisynthesis of the [FeFe] Hydrogenase H‑Cluster.
4. Hybrids of [FeFe]- and [NiFe]‑H2ase Active Site Models.
5. Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(Ex)(CN)2(CO)2]2– (E = S, Se, or Te).
6. Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(Ex)(CN)2(CO)2]2– (E = S, Se, or Te).
7. Chelate control of diiron(I) dithiolates relevant to the [Fe-Fe]-hydrogenase active site
8. MS2(Me2PC2H4PMe2)2 (M = Mo, W): Acid-base properties, proton transfer, and reversible protonolysis of sulfido ligands
9. Organo-tricyanoborates as tectons: Illustrative coordination polymers based on copper(I) derivatives
10. Structural chemistry of 'Defect' cyanometalate boxes: {Cs subset [CpCo(CN)3] (sub 4) [Cp*Ru] (sub 3)} and {M subset [Cp*Rh(CN)3] (sub 4) [Cp*Ru] (sub 3)} (M = NH4, Cs)
11. Bimetallic carbonyl thiolates as functional models for Fe-only hydrogenases
12. Preparative and structural studies on the carbonyl cyanides of iron, manganese, and ruthenium: fundamentals relevant to the hydrogenases
13. Synthetic and structural studies on [Fe2(SR)(Sub 2)(CN)(Sub x)(CO)(Sub 6-x)](Super x-) as active site models for Fe-only hydrogenases
14. The N-H...S hydrogen bond in (TACN)2Fe2S6 and in model systems involving the Persulfido moiety: An ab initio and DFT study
15. Influence of H(sub 2)S and thiols on the binding of alkenes and alkynes to ReS(sub 4)(super -): The spectator sulfido effect
16. Binding of pi-acceptor ligands to (triamine)iron(II) complexes
17. Third-order nonlinear optical properties of sulfur-rich compounds
18. Dehydrogenative route to metallo dithiolenes: the reaction of zinc polysulfides and alkenes
19. Binding of alkenes to ReS4-
20. Alkali metal-templated assembly of cyanometalate 'boxes' (NEt4)3(M(Cp*Rh(CN)3)4(Mo(CO)3)4) (M = K, Cs). Selective binding of Cs+
21. Challenges in the Synthesis of Active Site Mimics for [NiFe]-Hydrogenases.
22. A polymeric binary titanium(IV) sulfide and its conversion to molecular Lewis base adducts
23. Effect of ancillary ligands on the reactivity and structure of zinc polysulfido complexes
24. Studies on the electroactive heterocycles C(sub6)S(sub8)(super0/2-) and C(sub6)S(sub6)O(sub2)(super0/2-) and related metal complexes
25. Functionalization of Cp4Fe4(CO)4: contrasts and comparisons with ferrocene
26. Sulfido-persulfido equilibria in sulfur-rich metal clusters: the case of (C5Me5)3RhRu2Ssub4sup2+
27. Iron sulfido derivatives of the fullerenes C60 and C70
28. Homoleptic Rhodium Pyridine Complexes for Catalytic Hydrogen Oxidation.
29. Pairwise mobility of metal-metal bonds in (MeC5H4)4Ru4S3(SMe)(super n+)
30. One step closer to structural models of HDS catalysts: thienyl-oxo complexes of Re(V)
31. Binary carbon sulfides based on the alpha-C3S5 subunit and related C-S-O, C-S-Cl, and C-S-N compounds
32. Mobile metal-metal bonds: studies on mixed valence Ir3 and Ir4 clusters
33. Synthetic and structural studies on (RC5H4)4Ru4E(sub 4)(super 0/2+) (E = S, Se, Te): mobile metal-metal bonds within a mixed-valence Ru(IV)/Ru(III) cluster
34. Arene vs thiophene reduction in the system (C6R6)Ru(C4R4S)2+ and the protonation of eta4-thiophene ligands
35. Base hydrolysis of coordinated thiophene in (C5R5)Rh(C4Me4S)2+: nucleophilic attack at divalent sulfur and the reversible cleavage of C-S bonds
36. Electronic structure of metal chalcogen cubane clusters: photoelectron spectroscopic, electrochemical, and theoretical studies of (eta-C5H4Me TiS)4, (eta-C5H4Me VS)4, (eta-C5H5 CrO)4, (eta-C5H4Me CrO)4, (eta-C5H4Me CrS)4, (eta-C5H4Me CrSe)4, (eta-C5H4 super i Pr MoS)4, and (eta-C5H4 super i Pr MoSe)4
37. Synthetic studies on the CpRu-PPh3-(Se2) system: redox interconversions of Ru2(Se2)2 cores
38. Redistribution of reduced thiophene ligands in the conversion of (C5R5)Rh(eta4-C4Me4S) to ((C5R5)Rh)3(eta4,eta1-C4Me4S)2
39. Acid—Base Chemistry of Transition-Metal—π-Thiophene Complexes
40. Crystal Structure of the [FeFe]-Hydrogenase Maturase HydE Bound to Complex‑B.
41. Vibrational Perturbation of the [FeFe] Hydrogenase H‑Cluster Revealed by 13C2H‑ADT Labeling.
42. Computational and Experimental Investigations of the Fe2(μ‑S2)/Fe2(μ-S)2 Equilibrium.
43. New class of diiron dithiolates related to the Fe-only hydrogenase active site: synthesis and characterization of [Fe(sub)2(SR)(sub)2(CNMe)(sub)7](sup)2+
44. New class of ruthenium sulfide clusters: Ru (sub)4 S (sub)6 (PPh (sub)3) (sub)4, Ru (sub)5 S (sub)6 (PPh (sub)3) (sub)5, and Ru (sub)6 S (sub)8 (PPh (sub)3) (sub)6
45. Application of Hemilabile Ligands to "At-Metal Switching" Hydrogenation Catalysis.
46. A new synthesis of tetrathiooxalate and its conversion to C3S5(super 2-) and C4S6(super 2-)
47. Asymmetry in the Ligand Coordination Sphere of the [FeFe] Hydrogenase Active Site Is Reflected in the Magnetic Spin Interactions of the Aza-propanedithiolate Ligand.
48. Chalcogenospecific synthesis of 1,2-Se2S6 using ZnS6(TMEDA)
49. Role of the azadithiolate cofactor in models for [FeFe]-hydrogenase: novel structures and catalytic implications
50. Iron acyl thiolato carbonyls: structural models for the active site of the [Fe]-hydrogenase (Hmd)
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