86 results on '"Rauchfuss, Thomas B."'
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2. Chelate control of diiron(I) dithiolates relevant to the [Fe-Fe]-hydrogenase active site
3. MS2(Me2PC2H4PMe2)2 (M = Mo, W): Acid-base properties, proton transfer, and reversible protonolysis of sulfido ligands
4. Organo-tricyanoborates as tectons: Illustrative coordination polymers based on copper(I) derivatives
5. Structural chemistry of 'Defect' cyanometalate boxes: {Cs subset [CpCo(CN)3] (sub 4) [Cp*Ru] (sub 3)} and {M subset [Cp*Rh(CN)3] (sub 4) [Cp*Ru] (sub 3)} (M = NH4, Cs)
6. Bimetallic carbonyl thiolates as functional models for Fe-only hydrogenases
7. Preparative and structural studies on the carbonyl cyanides of iron, manganese, and ruthenium: fundamentals relevant to the hydrogenases
8. Synthetic and structural studies on [Fe2(SR)(Sub 2)(CN)(Sub x)(CO)(Sub 6-x)](Super x-) as active site models for Fe-only hydrogenases
9. The N-H...S hydrogen bond in (TACN)2Fe2S6 and in model systems involving the Persulfido moiety: An ab initio and DFT study
10. Influence of H(sub 2)S and thiols on the binding of alkenes and alkynes to ReS(sub 4)(super -): The spectator sulfido effect
11. Binding of pi-acceptor ligands to (triamine)iron(II) complexes
12. Dehydrogenative route to metallo dithiolenes: the reaction of zinc polysulfides and alkenes
13. Binding of alkenes to ReS4-
14. Alkali metal-templated assembly of cyanometalate 'boxes' (NEt4)3(M(Cp*Rh(CN)3)4(Mo(CO)3)4) (M = K, Cs). Selective binding of Cs+
15. A polymeric binary titanium(IV) sulfide and its conversion to molecular Lewis base adducts
16. Effect of ancillary ligands on the reactivity and structure of zinc polysulfido complexes
17. Studies on the electroactive heterocycles C(sub6)S(sub8)(super0/2-) and C(sub6)S(sub6)O(sub2)(super0/2-) and related metal complexes
18. Functionalization of Cp4Fe4(CO)4: contrasts and comparisons with ferrocene
19. Sulfido-persulfido equilibria in sulfur-rich metal clusters: the case of (C5Me5)3RhRu2Ssub4sup2+
20. Iron sulfido derivatives of the fullerenes C60 and C70
21. Pairwise mobility of metal-metal bonds in (MeC5H4)4Ru4S3(SMe)(super n+)
22. One step closer to structural models of HDS catalysts: thienyl-oxo complexes of Re(V)
23. Binary carbon sulfides based on the alpha-C3S5 subunit and related C-S-O, C-S-Cl, and C-S-N compounds
24. Mobile metal-metal bonds: studies on mixed valence Ir3 and Ir4 clusters
25. Synthetic and structural studies on (RC5H4)4Ru4E(sub 4)(super 0/2+) (E = S, Se, Te): mobile metal-metal bonds within a mixed-valence Ru(IV)/Ru(III) cluster
26. Arene vs thiophene reduction in the system (C6R6)Ru(C4R4S)2+ and the protonation of eta4-thiophene ligands
27. Base hydrolysis of coordinated thiophene in (C5R5)Rh(C4Me4S)2+: nucleophilic attack at divalent sulfur and the reversible cleavage of C-S bonds
28. Electronic structure of metal chalcogen cubane clusters: photoelectron spectroscopic, electrochemical, and theoretical studies of (eta-C5H4Me TiS)4, (eta-C5H4Me VS)4, (eta-C5H5 CrO)4, (eta-C5H4Me CrO)4, (eta-C5H4Me CrS)4, (eta-C5H4Me CrSe)4, (eta-C5H4 super i Pr MoS)4, and (eta-C5H4 super i Pr MoSe)4
29. Synthetic studies on the CpRu-PPh3-(Se2) system: redox interconversions of Ru2(Se2)2 cores
30. Redistribution of reduced thiophene ligands in the conversion of (C5R5)Rh(eta4-C4Me4S) to ((C5R5)Rh)3(eta4,eta1-C4Me4S)2
31. New class of diiron dithiolates related to the Fe-only hydrogenase active site: synthesis and characterization of [Fe(sub)2(SR)(sub)2(CNMe)(sub)7](sup)2+
32. New class of ruthenium sulfide clusters: Ru (sub)4 S (sub)6 (PPh (sub)3) (sub)4, Ru (sub)5 S (sub)6 (PPh (sub)3) (sub)5, and Ru (sub)6 S (sub)8 (PPh (sub)3) (sub)6
33. A new synthesis of tetrathiooxalate and its conversion to C3S5(super 2-) and C4S6(super 2-)
34. Chalcogenospecific synthesis of 1,2-Se2S6 using ZnS6(TMEDA)
35. Role of the azadithiolate cofactor in models for [FeFe]-hydrogenase: novel structures and catalytic implications
36. Iron acyl thiolato carbonyls: structural models for the active site of the [Fe]-hydrogenase (Hmd)
37. Hydride-containing models for the active site of the nickel-iron hydrogenases
38. Hydrogen activation by biomimetic diiron dithiolates
39. Nickel-iron dithiolato hydrides relevant to the [NiFe]-hydrogenase active site
40. Coordination chemistry of [[HFe[(CN).sub.2][(CO).sub.3]].sup.-] and its derivatives: toward a model for the iron subsite of the [NiFe]-hydrogenases
41. Proton-assisted activation of dihydrogen: mechanistic aspects of proton-catalyzed addition of [H.sub.2] to Ru and Ir amido complexes
42. Redox activation of alkene ligands in platinum complexes with non-innocent ligands
43. Aza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases
44. New nitrosyl derivatives of diiron dithiolates related to the active site of the [FeFe]-hydrogenases
45. Redox and structural properties of mixed-valence models for the active site of the [FeFe]-hydrogenase: progress and challenges
46. Precursors to [FeFe]-hydrogenase models: syntheses of [Fe.sub.2][(SR).sub.2][(CO).sub.6] from CO-free iron sources
47. Characterization of the Fe site in iron-sulfur cluster-free hydrogenase (Hmd) and of a model compound via nuclear resonance vibrational spectroscopy (NRVS)
48. Terminal hydride in [FeFe]-hydrogenase model has lower potential for [H.sub.2] production than the isomeric bridging hydridE
49. Redox-switched oxidation of dihydrogen using a non-innocent ligand
50. Coordination chemistry of a model for the GP cofactor in the Hmd hydrogenase: hydrogen-bonding and hydrogen-transfer catalysis
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