Search

Your search keyword '"Nucleophilic reactions -- Research"' showing total 87 results

Search Constraints

Start Over You searched for: Descriptor "Nucleophilic reactions -- Research" Remove constraint Descriptor: "Nucleophilic reactions -- Research" Language english Remove constraint Language: english
87 results on '"Nucleophilic reactions -- Research"'

Search Results

1. Quaternary stereocentres via an enantioconvergent catalytic S.sub.N1 reaction

2. A theoretical model study on the cyclic reaction of 4-hydroxybutanal catalyzed by Bronsted acid

3. Vicarious nucleophilic amination of nitroquinolines with 4-amino-1,2,4-triazole

4. Correlation of the rates of solvolysis of acetyl chloride and α-substituted derivatives

6. Rearrangement, nucleophilic substitution, and halogen switch reactions of alkyl halides over NaY zeolite: formation of the bicyclobutonium cation inside the zeolite cavity

7. Imaging nucleophilic substitution dynamics

8. Perfluoroalkylated 4,13-diaza-18-crown-6 ethers: Synthesis, phase-transfer catalysis, and recycling studies

9. Nucleophilicites of primary and secondary amines in water

10. Nucleophilic substitution reactions of N-chloramines: Evidence for a change in mechanism with increasing nucleophile reactivity

11. Ugi multicomponent reaction followed by an intramolecular nucleophilic substitution: Convergent multicomponent synthesis of 1-sulfonyl 1,4-diazepan-5-ones and of their benzo-fused derivatives

12. Nucleophilic substitution at silicon ([S.sub.N]2@Si) via a central reaction barrier

13. Chemoselective nucleophilic fluorination induced by selective solvation of the [S.sub.N]2 transition state

14. Enolpyruvyl activation by enolpyruvylshikimate-3-phosphate synthase

15. Heterogeneous diazo-transfer reaction: A facile unmasking of azide groups on amine-functionalized insoluble supports for solid-phase synthesis

16. Mechanism of action of a flavin-containing monooxygenase

17. High nucleophilicity of cyclic amidocarbene toward aryl isocyanates, new approach to spiro[azetidinone-4,3'-indolinone] derivatives

18. Distinguishing the early and late transition states and exploring the validity of [sigma]->[sigma.sup.*#], [sigma.sup.#]->[sigma.sup.*], and [sigma]->[pi*.sub.C=O] concepts in diastereoselection from NBO analysis

19. Infrared and electronic spectroscopy of a model system for the nucleophilic substitution intermediate in the gas phase: The C-N valence bond formation in the benzene-ammonia cluster cation

20. Nucleophilic perfluoroalkylation of aldehydes, ketones, imines, disulfides, and diselenides

21. Synthesis of N,N-bis(3-butenyl)amines from 2-azaallyl dication synthetic equivalents and conversion to 2,3,6,7-tetrahydroazepines by ring-closing metathesis

22. Crystal structures of salinosporamides A (NPI-0052) and B (NPI-0047) in complex with the 20S proteasome reveal important consequences of beta-lactone ring opening and a mechanism for irreversible binding

23. Solution kinetics of CC-1065 A-ring opening: Substituent effects and general acid/base catalysis

24. Theoretical study on the lithium--halogen exchange reaction of 1,1-dihaloalkenes with methyllithium and the nucleophilic substitution reaction of the resulting alpha-halo alkethyllithium

25. Reactivities of mononuclear non-heme iron intermediates including evidence that iron(III) - hydroperoxo species is a sluggish oxidant

26. Rotating-top approximation in reduced-dimensionality quantum calculations of rate constants: Application to complex-forming nucleophilic substitution

27. Synthetic utilization of polynitroaromatic compounds. 3. Preparation of substituted dibenz[b,f][1,4]oxazepin-11(10H)-ones from 2,4,6-trinitrobenzoic acid via nucleophilic displacement of nitro group

28. Modeling S(sub N)2 reactions in methanol solution by ab initio calculation of nucleophile solvent-substrate clusters

29. Synthesis of 6,19-sulfamidate bridged pregnanes

30. Dialkylaminopyridine-functionalized mesoporous silica nanosphere as an efficient and highly stable heterogeneous nucleophilic catalyst

31. Theoretical study of nuecleophilic substitution at sulfur in sulfinyl derivatives

32. Mechanisms of NO release by N(super 1)-nitrosomelatonin: Nucleophilic attack versus reducing pathways

33. Synthetic tetstudies in the intramolecular carbocyclization of N-acyloxyiminium ions: Stereoelectronic and steric implications of nucleophilic alkene, alkyne, and allene hers

34. Nucleophilic trifluoromethylation of imines using the CF3I/TDAE reagent

35. m-CPBA/KOH: An efficient reagent for nucleophilic epoxidation of gem-deactivated olefins

36. Site-directed mutagenesis of active site residues of phosphite dehydrogenase

37. A stereoselective and atom-efficient approach to multifunctionalized five- and six-membered rings via a novel Michael-initiated intramolecular Diels-Alder furan reaction

38. Hydroxylamines as oxygen atom nucleophiles in transition-metal-catalyzed allylic substitution

39. Is the allylpalladium structure altered between solid and solutions?

40. Structural analysis of botulinum neurotoxin type E catalytic domain and its mutant Glu212 -> Gln reveals the pivotal role of the Glu212 carboxylate in the catalytic pathway

41. Nucleophilic substitution of hydrogen in heterocyclic chemistry

42. Gas -phase SN2 and bromine abstraction reactions of chloride ion with bromomethane: Reaction cross sections and energy disposal into products

43. Could ionic gamma-elimination be concerted: clocking the internal displacement across a cyclobutane ring

44. Nucleophilic or electrophilic phosphinidene complexes MLn=PH; what makes the difference?

45. Is the tert-butyl chloride solvolysis the most misunderstood reaction in organic chemistry? Evidence against nucleophilic solvent participation in the tert-butyl chloride transition state and for increased hydrogen bond donation to the 1-adamantyl chloride solvolysis transition state

46. Highly diastereoselective nucleophilic addition to myrtenal: straightforward synthesis of an enantiopure scorpionate ligand

47. Palladium-catalyzed asymmetric allylic alkylation of meso- and dl-1,2-divinylethylene carbonate

48. Copper(I)-catalyzed one-pot synthesis of 2H-1,4-benzoxazine-3-(4H)-ones from o-halophenols and 2-chloroacetamides

49. Absence of S(sub N)1 involvement in the solvolysis of secondary alkyl compounds

50. Synthesis and resolution of a multifunctional inherently chiral calix[4]arene with an ABCD substitution pattern at the wide rim: the effect of a multifunctional structure in the organocatalyst on enantioselectivity in asymmetric reactions

Catalog

Books, media, physical & digital resources